Browsing by Subject "Crystalline materials"

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Open Access
Analytic modeling of patterned high-Tc superconductive bolometers: film and substrate interface effects
(SPIE, 1998) Fardmanesh, Mehdi; Rothwarf, A.
Superconducting film and substrate interface effects on the response of superconductive edge-transition bolometers are modeled with a one dimensional thermal model in closed form, for samples with large area patterns compared to the substrate thickness. The results from the model agree with experimental results on samples made of meander line patterned granular YBCO films on crystalline substrates, in both the magnitude and phase of the response versus modulation frequency up to about 100 KHz, the limit of the characterization setup. Using the fit of the calculated frequency response curves obtained from the model to the measured ones, values of the film-substrate and substrate-holder thermal boundary resistance, heat capacity of the superconducting film, and the thermal parameters of the substrate materials could be investigated. While the calculated magnitude and phase of the response of the SrTiO3 substrate samples obtained from the model is in a very good agreement with the measured values, the calculated response of the LaAlO3 and MgO substrate samples deviate slightly from the measured values at very low frequencies, increasing with an increase in the thermal conductivity of the substrate material. Using the fit of the calculated response to the measured values, film-substrate thermal boundary resistances in the range of 4.4* 10-3 to 4.4* 10-2 K-cm2-w-1 are obtained for different substrate materials. The effect of substrate optical absorption in the response of the samples is also investigated.
Open Access
Analytic thermal modeling for dc-to-midrange modulation frequency responses of thin-film high-Tc superconductive edge-transition bolometers
(Optical Society of America, 2001) Fardmanesh, M.
Thin-film superconductive edge-transition bolometers are modeled with a one-dimensional analytic thermal model with joule heating, film and substrate materials, and the physical interface effects taken into consideration. The results from the model agree well with the experimental results of samples made of large-meander-line Yba2Cu3O7-x films on crystalline SrTiO3, LaAlO3, and MgO substrates up to 100 kHz, the limits of the experimental setup. Compared with the results of the SrTiO3 substrate samples, the results from the model of the LaAlO3 and the MgO substrate samples deviate slightly from the measured values at very low modulation frequencies (below ∼10 Hz). The deviation increases for higher thermal-conductive substrate materials. When the model was used, the substrate absorption and the thermal parameters of the devices could also be investigated. © 2001 Optical Society of America.
Open Access
Different behaviour of magnetic impurities in crystalline and amorphous states of superconductors
(Institute of Physics, 2002) Park, M.-A.; Savran, K.; Kim, Y.-J.
It has been observed that the effect of magnetic impurities in a superconductor is drastically different depending on whether the host superconductor is in the crystalline or the amorphous state. Based on the recent theory of Kim and Overhauser (KO), it is shown that as the system is getting disordered, the initial slope of the Tc depression is decreasing by a factor √ℓ/ξ0, when the mean free path ℓ becomes smaller than the BCS coherence length ξ0, which is in agreement with experimental findings. In addition, for a superconductor in a crystalline state in the presence of magnetic impurities the superconducting transition temperature Tc drops sharply from about 50% of Tc0 (for a pure system) to zero near the critical impurity concentration. This pure limit behaviour was indeed found by Roden and Zimmermeyer in crystalline Cd. Recently, Porto and Parpia have also found the same pure limit behaviour in superfluid He-3 in aerogel, which may be understood within the framework of the KO theory.
Open Access
Effect of the superconductivity transition on the response of YBCO edge transition bolometers
(2003) Bozbey, Ali; Fardmanesh, Mehdi; Askerzade, I. N.; Banzet, M.; Schubert, J.
Dependence of the phase and magnitude of the response of Y-Ba-Cu-O edge transition bolometers on the superconducting transition is studied. The responses of both large and small area devices were investigated and several anomalies are observed. The response of small area LaAlO3 devices considerably differed from that expected based on the dR/dT curve. This discrepancy is observed to be strongly dependent on the superconducting transition. Both the phase and magnitude/(dR/dT) of the response of the devices showed abrupt changes for below the Tc-onset when measured versus temperature, while the phase variation also showed strong dependence on the modulation frequency. We present the analysis and propose mechanisms responsible for the modulation frequency dependence of the response characteristics versus temperature, within the superconductivity transition region of the devices.
Open Access
Highly luminescent CB[7]-based conjugated polyrotaxanes embedded into crystalline matrices
(Wiley-VCH Verlag, 2017) Erdem, T.; Idris, M.; Demir, Hilmi Volkan; Tuncel, D.
π-Conjugated polymers suffer from low quantum yields (QYs) due to chain–chain interactions. Furthermore, their emission in solid films is significantly quenched due to aggregation leading further decrease in QY. These are the two main issues of these materials hampering their widespread use in optoelectronic devices. To address these issues, here the backbone of poly(9,9′-bis(6″-(N,N,N-trimethylammonium)hexyl)fluorene-alt-co-thiophenelene) is isolated by threading with cucurbit[7]uril (CB7). Subsequently, the conjugated polyrotaxanes are incorporated into organic crystalline matrices to obtain highly efficient color-converting solids suitable for solid-state lighting. Upon threading the polymer backbone with CB7s, although the QY of the resulting polyrotaxane in solution state increases, the quenching problem in their solid state is not completely tackled. To solve this problem, these conjugated polyrotaxanes are embedded into various crystalline matrices and their remarkably high QYs (>50%) in the solution are successfully maintained in the solid state. To demonstrate the suitability of these aforementioned materials for solid-state lighting, a proof-of-concept light-emitting diode is constructed by employing their powders as color converters.
Open Access
Lateral overgrowth of germanium for monolithic integration of germanium-on-insulator on silicon
(Elsevier, 2015) Hyung Nam J.; Alkis, S.; Nam, D.; Afshinmanesh F.; Shim J.; Park, J.; Brongersma, M.; Okyay, Ali Kemal; Kamins, T.I.; Saraswat, K.
A technique to locally grow germanium-on-insulator (GOI) structure on silicon (Si) platform is studied. On (001) Si wafer, silicon dioxide (SiO2) is thermally grown and patterned to define growth window for germanium (Ge). Crystalline Ge is grown via selective hetero-epitaxy, using SiO2 as growth mask. Lateral overgrowth of Ge crystal covers SiO2 surface and neighboring Ge crystals coalesce with each other. Therefore, single crystalline Ge sitting on insulator for GOI applications is achieved. Chemical mechanical polishing (CMP) is performed to planarize the GOI surface. Transmission electron microscopy (TEM) analysis, Raman spectroscopy, and time-resolved photoluminescence (TRPL) show high quality crystalline Ge sitting on SiO2. Optical response from metal-semiconductor-metal (MSM) photodetector shows good optical absorption at 850 nm and 1550 nm wavelength. © 2015 Elsevier B.V. All rights reserved.
Open Access
Lithium salt-nonionic surfactant lyotropic liquid crystalline gel-electrolytes with redox couple for dye sensitized solar cells
(Royal Society of Chemistry, 2016) Yılmaz, E.; Olutaş, E. B.; Barım, G.; Bandara, J.; Dag, Ö.
Lithium salt (LiCl, LiBr, LiI, or LiNO3) and a non-ionic surfactant (such as 10-lauryl ether, C12E10) form lyotropic liquid crystalline (LLC) mesophases in the presence of a small amount of water. The mesophases can be prepared as gels by mixing all the ingredients in one pot or in the solution phase that they can be prepared by coating over any substrate where the LLC phase is formed by evaporating excess solvent. The second method is easier and produces the same mesophase as the first method. A typical composition of the LLC phases consists of 2-3 water per salt species depending on the counter anion. The LiI-C12E10 mesophases can also be prepared by adding I2 to the media to introduce an I-/I3 - redox couple that may be used as a gel-electrolyte in a dye-sensitized solar cell. Even though the mesophases contain a large amount of water in the media, this does not affect the cell performance. The water molecules in the mesophase are in the hydration sphere of the ions and do not act like bulk water, which is harmful to the anode of the dye-sensitized solar cells (DSSC). There are two major drawbacks of the salt-surfactant LLC mesophases in the DSSCs; one is the diffusion of the gels into the pores of the anode electrode and the other is the low ionic conductivity. The first issue was partially overcome by introducing the gel content as a solution and the gelation was carried in/over the pores of the dye modified titania films. To increase the ionic conductivity of the gels, other salts (such as LiCl, LiBr, and LiNO3) with better ionic conductivity were added to the media, however, those gels behave less effectively than pure LiI/I2 systems. Overall, the DSSCs constructed using the LLC electrolyte display high short circuit current (Isc of around 10 mA), high open circuit voltage (Voc of 0.81 V) and good fill factor (0.69) and good efficiency (3.3%). There is still room for improvement in addressing the above issues in order to enhance the cell efficiency by developing new methods of introducing the gel-electrolytes into the mesopores of the anode electrode.
Open Access
Low-temperature self-limiting atomic layer deposition of wurtzite InN on Si(100)
(American Institute of Physics Inc., 2016) Haider, A.; Kizir, S.; Bıyıklı, Necmi
In this work, we report on self-limiting growth of InN thin films at substrate temperatures as low as 200 °C by hollow-cathode plasma-assisted atomic layer deposition (HCPA-ALD). The precursors used in growth experiments were trimethylindium (TMI) and N2 plasma. Process parameters including TMI pulse time, N2 plasma exposure time, purge time, and deposition temperature have been optimized for self-limiting growth of InN with in ALD window. With the increase in exposure time of N2 plasma from 40 s to 100 s at 200 °C, growth rate showed a significant decrease from 1.60 to 0.64 Å/cycle. At 200 °C, growth rate saturated as 0.64 Å/cycle for TMI dose starting from 0.07 s. Structural, optical, and morphological characterization of InN were carried out in detail. X-ray diffraction measurements revealed the hexagonal wurtzite crystalline structure of the grown InN films. Refractive index of the InN film deposited at 200 °C was found to be 2.66 at 650 nm. 48 nm-thick InN films exhibited relatively smooth surfaces with Rms surface roughness values of 0.98 nm, while the film density was extracted as 6.30 g/cm3. X-ray photoelectron spectroscopy (XPS) measurements depicted the peaks of indium, nitrogen, carbon, and oxygen on the film surface and quantitative information revealed that films are nearly stoichiometric with rather low impurity content. In3d and N1s high-resolution scans confirmed the presence of InN with peaks located at 443.5 and 396.8 eV, respectively. Transmission electron microscopy (TEM) and selected area electron diffraction (SAED) further confirmed the polycrystalline structure of InN thin films and elemental mapping revealed uniform distribution of indium and nitrogen along the scanned area of the InN film. Spectral absorption measurements exhibited an optical band edge around 1.9 eV. Our findings demonstrate that HCPA-ALD might be a promising technique to grow crystalline wurtzite InN thin films at low substrate temperatures.
Open Access
Lyotropic liquid-crystalline mesophase of lithium triflate-nonionic surfactant as gel electrolyte for graphene optical modulator
(American Chemical Society, 2023) Balci, F. M.; Balci, S.; Kocabas, C.; Dag, Ö.
Lithium salt (noncoordinating anions, such as lithium triflate (Ltf)) gel electrolytes may be key for the practical use of electrochemical devices. We introduce a new lyotropic liquid-crystalline (LLC) mesophase using Ltf, a small amount of water (as low as 1.3 water per Ltf), and nonionic surfactant (C18H37(OCH2CH2)10OH, C18E10). The LLC phase forms over a broad range of Ltf/C18E10 mole ratios, 2-18. The clear ethanol solution of the ingredients can be either directly spin-coated over a glass substrate to form a gel phase or it can be prepared as a gel by mixing Ltf, water, and C18E10. The mesophase leaches out surfactant molecules at low salt concentrations, but at a salt/surfactant mole ratio of above 8, the phase is homogeneous with a cubic mesostructure, fully transparent in the visible optical region, mechanically flexible, and an effective gel electrolyte. We have observed a large electrostatic doping on graphene with the Fermi energy level of ∼1.0 eV using Ltf-C18E10 gel electrolytes. The Ltf-based gels demonstrate better properties than commonly used ionic liquid electrolyte in graphene optical modulators. The stability of the new gel electrolytes and their superior performance make them suitable electrolytes for use in graphene-based optical modulators.
Open Access
Lyotropic liquid-crystalline mesophases of [Zn(H2O)6](NO3)2-C12EO10-CTAB-H2O and [Zn(H2O)6](NO3)2-C12EO10-SDS-H2O systems
(2008) Albayrak, C.; Soylu, A. M.; Dag, Ö.
The mixture of two surfactants (C12EO10-CTAB and C 12EO10-SDS) forms lyotropic liquid-crystalline (LLC) mesophases with [Zn(H2O)6](NO3)2 in the presence of a minimum concentration of 1.75 H2O per C 12EO10. The metal ion/C12EO10 mole ratio can be increased up to 8.0, which is a record high metal ion density in an LLC mesophase. The metal ion concentration can be increased in the medium by increasing the CTAB/C12EO10 or SDS/C12EO 10 mole ratio at the expense of the stability of the LLC mesophase. The structure and some thermal properties of the new mesophase have been investigated using XRD, POM, FTIR, and Raman techniques. © 2008 American Chemical Society.
Open Access
MaterialVis: material visualization tool using direct volume and surface rendering techniques
(Elsevier Inc., 2014) Okuyan, E.; Güdükbay, Uğur; Bulutay, C.; Heinig, Karl-Heinz
Visualization of the materials is an indispensable part of their structural analysis. We developed a visualization tool for amorphous as well as crystalline structures, called MaterialVis. Unlike the existing tools, MaterialVis represents material structures as a volume and a surface manifold, in addition to plain atomic coordinates. Both amorphous and crystalline structures exhibit topological features as well as various defects. MaterialVis provides a wide range of functionality to visualize such topological structures and crystal defects interactively. Direct volume rendering techniques are used to visualize the volumetric features of materials, such as crystal defects, which are responsible for the distinct fingerprints of a specific sample. In addition, the tool provides surface visualization to extract hidden topological features within the material. Together with the rich set of parameters and options to control the visualization, MaterialVis allows users to visualize various aspects of materials very efficiently as generated by modern analytical techniques such as the Atom Probe Tomography.
Open Access
One-dimensional peptide nanostructure templated growth of iron phosphate nanostructures for lithium-ion battery cathodes
(American Chemical Society, 2016-06) Susapto, H. H.; Kudu, O. U.; Garifullin, R.; Yllmaz, E.; Güler, Mustafa O.
Template-directed synthesis of nanomaterials can provide benefits such as small crystalline size, high surface area, large surface-to-volume ratio, and structural stability. These properties are important for shorter distance in ion/electron movement and better electrode surface/electrolyte contact for energy storage applications. Here nanostructured FePO4 cathode materials were synthesized by using peptide nanostructures as a template inspired by biomineralization process. The amorphous, high surface area FePO4 nanostructures were utilized as a cathode for lithium-ion batteries. Discharge capacity of 155 mAh/g was achieved at C/20 current rate. The superior properties of biotemplated and nanostructured amorphous FePO4 are shown compared to template-free crystalline FePO4.
Open Access
One-pot synthesis of CdS nanoparticles in the channels of mesosructured silica films and monoliths
(American Chemical Society, 2005) Tura, C.; Coombs, N.; Dag, Ö.
Cd(II)-modified mesoporous silica films and/or monoliths synthesized in one pot using a true liquid crystalline (TLC) approach have been reacted with H2S gas to produce CdS-modified mesostructured nanocomposite materials (Nano-CdS/meso-SiO2). During this process, both the TLC and the metallotropic liquid crystalline (MLC) mesophase of metal salt ([Cd(H 2O)4](NO3)2)-nonionic surfactant (CnH2n+1- (OCH2CH2)mOH, CnEOm) systems were collectively used to incorporate large quantities of metal ions into the mesoporous silica film and monoliths. The effect of the cadmium nitrate concentration on the formation and structure of the mesoporous silica has also been investigated. The results show that at low salt concentrations, the mesoporous silica is anisotropic (hexagonal); however, at high salt concentration, the structure is isotropic (cubic or disordered). The freshly prepared CdS nanoparticles are reactive toward the surface acids that form during the H2S treatment. These surface acids also promote the degradation of the CdS nanopaticles. However, the CdS particles in the mesopores can be stabilized by washing out the acid sides or aging the samples for a period of time before the H2S reaction. The optical absorption edge of the CdS nanoparticle in the pores is sensitive to the composition and structure of the host. In this context, the materials were characterized using FTIR, micro-Raman, UV-visible absorption spectroscopy, POM, TEM, and PXRD techniques.
Open Access
Physics and applications of photonic crystals
(Nanotechnology Research Center NANOTAM, 2004) Özbay, Ekmel; Bulu I.; Aydin, K.; Caglayan H.; Guven, K.
In this article, we investigate how the photonic band gaps and the variety of band dispersions of photonic crystals can be utilized for various applications and how they further give rise to completely novel optical phenomena. The enhancement of spontaneous emission through coupled cavity waveguides in a one-dimensional silicon nitride photonic microcrystal is investigated. We then present the highly directive radiation from sources embedded in two-dimensional photonic crystals. The manifestation of novel and intriguing optical properties of photonic crystals are exemplified experimentally by the negative refraction and the focusing of electromagnetic waves through a photonic crystal slab with subwavelength resolution. © 2004 Elsevier B.V. All rights reserved.
Open Access
Raman scattering from confined phonons in GaAs/AlGaAs quantum wires
(Academic Press, 1998) Bairamov, B. H.; Aydınlı, Atilla; Tanatar, Bilal; Güven, K.; Gurevich, S.; Mel'tser, B. Ya.; Ivanov, S. V.; Kop'ev, P. S.; Smirnitskii, V. B.; Timofeev, F. N.
We report on photoluminescence and Raman scattering performed at low temperature (T = 10 K) on GaAs/Al 0.3Ga 0.7As quantum-well wires with effective wire widths of L = 100.0 and 10.9 nm prepared by molecular beam epitaxial growth followed by holographic patterning, reactive ion etching, and anodic thinning. We find evidence for the existence of longitudinal optical phonon modes confined to the GaAs quantum wire. The observed frequency at ω L10 = 285.6 cm -1 for L = 11.0 nm is in good agreement with that calculated on the basis of the dispersive dielectric continuum theory of Enderlein† as applied to the GaAs/Al 0.3Ga 0.7As system. Our results indicate the high crystalline quality of the quantum-well wires fabricated using these techniques. © 1998 Academic Press.
Open Access
Raman studies of doped polycrystalline silicon from laser-annealed, doped a-Si:H
(Pergamon Press, 1994) Compaan, A.; Savage, M. E.; Aydınlı, Atilla; Azfar, T.
We have used Raman scattering to follow the progress of multiple-pulse (sub-melt-threshold) laser annealing in doped hydrogenated amorphous silicon films (a-Si:H) on glass. In phosphorous-doped a-Si:H the Raman signal shows that recrystallization begins with the first laser pulse but the multiple pulses are needed to generate the highest hole concentrations of ∼6×1020 cm-3. In boron-doped a-Si:H the electron concentration reaches ∼1×1021 cm-3 after laser anneal which produces a dip rather than a peak near the phonon line as a consequence of a negative Fano-interference parameter, q. The results show that Raman scattering can be used to obtain carrier concentrations in poly-silicon provided that wavelength-dependent Fano interference effects are properly included. © 1994.
Open Access
Room-temperature scanning Hall probe microscope (RT-SHPM) imaging of garnet films using new high-performance InSb sensors
(IEEE, 2002) Oral, Ahmet; Kaval, Murat; Dede, Münir; Masuda, H.; Okamoto, A.; Shibasaki, I.; Sandhu, A.
The room-temperature scanning Hall probe microscopy (RT-SHPM) imaging of garnet films using high-performance InSb sensors was discussed. The high-performance InSb micro-Hall sensors were fabricated by optical lithography. It was found that the room-temperature noise figure of the InSb sensors was 6-10 mG/√Hz, which was an order of magnitude better than GaAs-AlGaAs two-dimensional electron gas sensors.
Open Access
Strong acid-nonionic surfactant lyotropic liquid-crystalline mesophases as media for the synthesis of carbon quantum dots and highly proton conducting mesostructured silica thin films and monoliths
(American Chemical Society, 2015) Olutaş, E. B.; Balcı, F. M.; Dag, Ö.
Lyotropic liquid-crystalline (LLC) materials are important in designing porous materials, and acids are as important in chemical synthesis. Combining these two important concepts will be highly beneficial to chemistry and material science. In this work, we show that a strong acid can be used as a solvent for the assembly of nonionic surfactants into various mesophases. Sulfuric acid (SA), 10-lauryl ether (C12E10), and a small amount of water form bicontinuous cubic (V1), 2Dhexagonal (H1), and micelle cubic (I1) mesophases with increasing SA/ C12E10 mole ratio. A mixture of SA and C12E10 is fluidic but transforms to a highly ordered LLC mesophase by absorbing ambient water. The LLC mesophase displays high proton conductivity (1.5 to 19.0 mS/cm at room temperature) that increases with an increasing SA content up to 11 SA/ C12E10 mole ratio, where the absorbed water is constant with respect to the SA amount but gradually increases from a 2.3 to 4.3 H2O/C12E10 mole ratio with increasing SA/C12E10 from 2 to 11, respectively. The mixture of SA and C12E10 slowly undergoes carbonization to produce carbon quantum dots (c-dots). The carbonization process can be controlled by simply controlling the water content of the media, and it can be almost halted by leaving the samples under ambient conditions, where the mixture slowly absorbs water to form photoluminescent c-dot-embedded mesophases. Over time the c-dots grow in size and increase in number, and the photoluminescence frequency gradually shifts to a lower frequency. The SA/C12E10 mesophase can also be used as a template to produce highly proton conducting mesostructured silica films and monoliths, as high as 19.3 mS/cm under ambient conditions. Aging the silica samples enhances the conductivity that can be even larger than for the LLC mesophase with the same amount of SA. The presence of silica has a positive effect on the proton conductivity of SA/C12E10 systems.
Open Access
Structural and phase evolution in mechanically alloyed calcium copper titanate dielectrics
(2013) Alizadeh, M.; Ardakani H.A.; Amini, R.; Ghazanfari, M.R.; Ghaffari, M.
Nanocrystalline calcium-copper-titanate (CCTO) dielectric powders were prepared by mechanical alloying. Phase transformations and structural evolution of the mechanically activated powders were investigated through the Rietveld refinement of the X-ray diffraction results. The crystallite size, lattice strain, and weight fraction of individual phases were estimated based on crystal structure refinement. Furthermore, the microstructural properties and thermal behavior of the milled powders were investigated by Transmission Electron Microscopy (TEM) and Differential Thermal Analysis (DTA), respectively. It was found that CCTO nanocrystals can be successfully synthesized after the amorphization of the initial crystalline materials. Semi-spherical nano-size particles were developed after sufficient milling time. Formation of an amorphous phase during the milling cycle was confirmed by the presence of the glass transition and crystallization peaks in the thermal analysis profiles. © 2012 Elsevier Ltd and Techna Group S.r.l.
Open Access
Swollen liquid crystals (SLCs): A versatile template for the synthesis of nano structured materials
(Royal Society of Chemistry, 2017) Dutt, S.; Siril, P. F.; Remita, S.
Liquid crystal (LCs) is the state of matter that exhibits properties between a conventional liquid and solid crystals. Liquid crystals mainly can be classified into two types: thermotropic and lyotropic liquid crystals. A thermotropic liquid crystal shows properties that are dependent on temperature conditions. On the other hand in lyotropic liquid crystals (LLCs), the amphiphiles are dissolved in a solvent and exhibit liquid crystalline properties in certain concentration ranges. In the literature, lot of reviews have been presented on thermotropic and lyotropic liquid crystals (LLCs). But nowadays, swollen liquid crystals (SLCs) have become a much more important area of research because of their easily tunable properties, their stability and versatility of the system. Swollen liquid crystals (SLCs) consist of infinite liquid crystalline non polar cylinders organized on a hexagonal lattice in a polar medium and are prepared with the proper ratios of salted water and non polar solvents with cationic or anionic or non ionic surfactants and co surfactants i.e. water:oil:surfactant:cosurfactant. In this review article, we will briefly discuss the synthesis of swollen liquid crystals (SLCs), factors affecting their stability, different kinds of nanomaterials such as metallic, bimetallic, polymeric nanostructures synthesized inside swollen liquid crystals (SLCs) using different methods and the effect of swollen liquid crystal (SLC) confinement on the final morphology of nanomaterials with their potential applications.