Browsing by Subject "Surface plasmon resonance"

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Open Access
Asymmetric chiral metamaterial circular polarizer based on four U-shaped split ring resonators
(Optical Society of America, 2011-04-28) Mutlu, M.; Akosman, A. E.; Serebryannikov, A. E.; Özbay, Ekmel
An asymmetric chiral metamaterial structure is constructed by using four double-layered U-shaped split ring resonators, which are each rotated by 90° with respect to their neighbors. The peculiarity of the suggested design is that the sizes of the electrically and magnetically excited rings are different, which allows for equalizing the orthogonal components of the electric field at the output interface with a 90° phase difference when the periodic structure is illuminated by an x-polarized wave. As a result, left-hand circular polarization and right-hand circular polarization are obtained in transmission at 5:1 GHz and 6:4 GHz, respectively. The experiment results are in good agreement with the numerical results.
Open Access
Biocatalytic protein membranes fabricated by electrospinning
(Elsevier B.V., 2016) Kabay, G.; Kaleli, G.; Sultanova, Z.; Ölmez, T. T.; Şeker, U. Ö. Ş.; Mutlu, M.
In this study, a protein-based catalytic membrane was produced by electrospinning. Membrane activity was characterised in terms of response current for various glucose concentrations. We focused on the preparation of a scaffold by converting a globular protein to other structural forms using catastrophic solvents. A scaffolding protein, bovine serum albumin, and an enzyme, glucose oxidase (GOD), were selected as a model natural carrier matrix and a biologically active agent, respectively. Beta-mercaptoethanol (β-ME) was used to convert the globular protein to an amyloid-like form. A structural stabilising agent, 2,2,2-triflouroethanol (TFE), was used to maintain the final α-helical structure of the amyloid-like protein. The TFE:PBS (phosphate-buffered saline) ratio and various electrospinning parameters were analysed to minimise activity loss. Using this approach, we applied electrospinning to an active enzyme to obtain biocatalytic nanofibrous membranes. After optimising the protein electrospinning process, the activities of the protein nanofibrous membranes were monitored. GOD remained active in the new membrane structure. The highest enzyme activity was observed for the membranes prepared with a 1.5:1 (v:v) TFE:PBS solvent ratio. In that particular case, the immobilized enzyme created a current of 0.7 μA and the apparent activity was 2547 ± 132 U/m2.
Open Access
Compound Hertzian chain model for copper-carbon nanocomposites' absorption spectrum
(2011) Kokabi, A.; Hosseini, M.; Saeedi, S.; Moftakharzadeh, A.; Vesaghi, M.A.; Fardmanesh, M.
The infrared range optical absorption mechanism of carbon-copper composite thin layer coated on the diamond-like carbon buffer layer has been investigated. By consideration of weak interactions between copper nanoparticles in their network, optical absorption is modelled using their coherent dipole behaviour induced by the electromagnetic radiation. The copper nanoparticles in the bulk of carbon are assumed as a chain of plasmonic dipoles, which have coupling resonance. Considering nearest neighbour interactions for this metallic nanoparticles, surface plasmon resonance frequency (ω 0) and coupled plasmon resonance frequency (ω 1) have been computed. The damping rate against wavelength is derived, which leads to the derivation of the optical absorption spectrum in terms of ω 0 and ω 1. The dependency of the absorption peaks to the particle size and the particle mean spacing is also investigated. The absorption spectrum is measured for different Cu-C thin films with various Cu particle size and spacing. The experimental results of absorption are compared with the obtained analytical ones. © 2011 The Institution of Engineering and Technology.
Open Access
Developing a transducer based on localized surface plasmon resonance (LSPR) of gold nanostructures for nanobiosensor applications
(Trans Tech Publications, 2013) Turhan, Adil Burak; Ataman, D.; Çakmakyapan, S.; Mutlu, M.; Özbay, Ekmel; Vlachos, D. S.; Hristoforou, E.
In this work, we report the nanofabrication, optical characterization, and electromagnetic modeling of various nanostructure arrays for localized surface plasmon resonance (LSPR) based biosensing studies. Comparison of the experimental results and simulation outputs of various nanostructure arrays was made and a good correspondence was achieved.
Open Access
Dynamic tuning of plasmon resonance in the visible using graphene
(The Optical Society, 2016) Balci, S.; Balci, O.; Kakenov, N.; Atar, F. B.; Kocabas, C.
We report active electrical tuning of plasmon resonance of silver nanoprisms (Ag NPs) in the visible spectrum. Ag NPs are placed in close proximity to graphene which leads to additional tunable loss for the plasmon resonance. The ionic gating of graphene modifies its Fermi level from 0.2 to 1 eV, which then affects the absorption of graphene due to Pauli blocking. Plasmon resonance frequency and linewidth of Ag NPs can be reversibly shifted by 20 and 35 meV, respectively. The coupled graphene-Ag NPs system can be classically described by a damped harmonic oscillator model. Atomic layer deposition allows for controlling the graphene-Ag NP separation with atomic-level precision to optimize coupling between them.
Open Access
Effect of solvent refractive index on the surface plasmon resonance nanoparticle optical absorption
(2007) Ertas, G.; Süzer, Şefik
Optical properties of plasmon coupled silver and gold nanoparticles were studied as a function of the refractive index of the surrounding medium. Our studies confirmed that the effect of changes in the refractive index of the surrounding medium was more difficult to demonstrate from an experimental point of view, because of the very high susceptibility of nanoparticles to aggregate in aqueous and organic solvents. Whereas the position of the absorption bands of triiodide in these solvents shows a clear dependence on medium's refractive index, the surface plasmon band position of silver and gold nanoparticles do not exhibit the same dependence. This is attributed to a non-negligible interaction of these solvents with nanoparticle surfaces. Copyright © 2007 American Scientific Publishers All rights reserved.
Open Access
Enhanced transmission of microwave radiation in one-dimensional metallic gratings with subwavelength aperture
(American Institute of Physics, 2004) Akarca-Biyikli, S. S.; Bulu, I.; Özbay, Ekmel
We report a theoretical and experimental demonstration of enhanced microwave transmission through subwavelength apertures in metallic structures with double-sided gratings. Three different types of aluminum gratings (sinusoidal, symmetric rectangular, and asymmetric rectangular shaped) are designed and analyzed. Our samples have a periodicity of 16 mm, and a slit width of 2 mm. Transmission measurements are taken in the 10–37.5 GHz frequency spectrum, which corresponds to 8–30 mm wavelength region. All three structures display significantly enhanced transmission around surface plasmon resonance frequencies. The experimental results agree well with finite-difference-time-domain based theoretical simulations. Asymmetric rectangular grating structure exhibits the best results with ,50% transmission at 20.7 mm, enhancement factor of ,25, and ±4° angular divergence.
Open Access
Focusing of THz waves with a microsize parabolic reflector made of graphene in the free space
(Springer International Publishing, 2017) Oguzer T.; Altintas, A.; Nosich A.I.
Background: The scattering of H- and E-polarized plane waves by a two-dimensional (2-D) parabolic reflector made of graphene and placed in the free space is studied numerically. Methods: To obtain accurate results we use the Method of Analytical Regularization. Results: The total scattering cross-section and the absorption cross-section are computed, together with the field magnitude in the geometrical focus of reflector. The surface plasmon resonances are observed in the H-case. The focusing ability of the reflector is studied in dependence of graphene’s chemical potential, frequency, and reflector’s depth. Conclusions: It is found that there exists an optimal range of frequencies where the focusing ability reaches maximum values. The reason is the quick degradation of graphene’s surface conductivity with frequency. © 2017, The Author(s).
Open Access
Grating coupler integrated photodiodes for plasmon resonance based sensing in fluidic systems
(IEEE, 2011) Türker, Burak; Güner, Hasan; Ayaş, Sencer; Ekiz, Okan O.; Acar, Handan; Güler, Mustafa O.; Dâna, Aykutlu
We demonstrate an integrated sensor combining a grating-coupled plasmon resonance surface with a planar photodiode. Plasmon enhanced transmission is employed as a sensitive refractive index (RI) sensing mechanism and monitored via the integrated photodiode. © 2011 OSA.
Open Access
Highly asymmetric transmission of linearly polarized waves realized with a multilayered structure including chiral metamaterials
(IOP Publishing, 2014) Li, Z.; Mutlu, M.; Özbay, Ekmel
We numerically and experimentally demonstrate highly asymmetric transmission of linearly polarized waves with a multilayered metallic structure. The whole structure has a subwavelength thickness and consists of a thin slab of chiral metamaterial sandwiched between two 90° twisted linear polarizers. The chiral metamaterial is made of two sets of twisting cross wires that can rotate the polarization by 90° at resonance, and the two linear polarizers are simple metallic grating polarizers. The operation principle of the whole structure can be well interpreted by using the Jones matrix method. Our experimental results also verify that chiral metamaterials can be safely integrated into complex structures and treated as an effective medium as long as their resonant modes are not affected by the environment.
Open Access
Identification of novel neutralizing single-chain antibodies against vascular endothelial growth factor receptor 2
(2011) Erdag, B.; Koray Balcioglu, B.; Ozdemir Bahadir, A.; Serhatli, M.; Kacar O.; Bahar, A.; Seker, U.O.S.; Akgun, E.; Ozkan, A.; Kilic, T.; Tamerler, C.; Baysal, K.
Human vascular endothelial growth factor (VEGF) and its receptor (VEGFR-2/kinase domain receptor [KDR]) play a crucial role in angiogenesis, which makes the VEGFR-2 signaling pathway a major target for therapeutic applications. In this study, a single-chain antibody phage display library was constructed from spleen cells of mice immunized with recombinant human soluble extracellular VEGFR-2/KDR consisting of all seven extracellular domains (sKDR D1-7) to obtain antibodies that block VEGF binding to VEGFR-2. Two specific single-chain antibodies (KDR1.3 and KDR2.6) that recognized human VEGFR-2 were selected; diversity analysis of the clones was performed by BstNI fingerprinting and nucleotide sequencing. The single-chain variable fragments (scFvs) were expressed in soluble form and specificity of interactions between affinity purified scFvs and VEGFR-2 was confirmed by ELISA. Binding of the recombinant antibodies for VEGFR-2 receptors was investigated by surface plasmon resonance spectroscopy. In vitro cell culture assays showed that KDR1.3 and KDR2.6 scFvs significantly suppressed the mitogenic response of human umbilical vein endothelial cells to recombinant human VEGF 165 in a dose-dependent manner, and reduced VEGF-dependent cell proliferation by 60% and 40%, respectively. In vivo analysis of these recombinant antibodies in a rat cornea angiogenesis model revealed that both antibodies suppressed the development of new corneal vessels (p < 0.05). Overall, in vitro and in vivo results disclose strong interactions of KDR1.3 and KDR2.6 scFvs with VEGFR-2. These findings indicate that KDR1.3 and KDR2.6 scFvs are promising antiangiogenic therapeutic agents. © 2011 International Union of Biochemistry and Molecular Biology, Inc.
Open Access
Influence of gold-silica nanoparticles on the performance of small-molecule bulk heterojunction solar cells
(Elsevier BV * North-Holland, 2015) Xu, X.; Kyaw, A. K. K.; Peng, B.; Xiong, Q.; Demir, Hilmi Volkan; Wang Y.; Wong, T. K. S.; Sun, X. W.
Light trapping by gold (Au)-silica nanospheres and nanorods embedded in the active layer of small-molecule (SM) organic solar cell has been systematically compared. Nanorod significantly outperforms nanosphere because of more light scattering and higher quality factor for localized surface plasmon resonance (LSPR) triggered by nanorods. The optimum concentration of nanorod was characterized by charge carrier transport and morphology of the active layers. At optimum nanorod concentration, almost no change in the morphology of the active layer reveals that LSPR and scattering effects rather than the morphology are mainly responsible for the enhanced power conversion efficiency. In addition, the preliminary lifetime studies of the SM solar cells with and without Au-silica nanorods were conducted by measuring the current density-voltage characteristics over 20 days. The results show that plasmonic device with nanorods has no adverse impact on the device stability
Open Access
Lasing in a Slow Plasmon Moiré Cavity
(American Chemical Society, 2015) Karademir, E.; Balci, S.; Kocabas, C.; Aydınlı, Atilla
We report on lasing from dye-based excitons coupled to slow plasmon states inside metallic Moiré cavities. Surface plasmon polaritons (SPPs) inside the cavity were slowed down to a maximum group velocity of 0.3c. Varying the modulation of the Moiré cavity, we tune the output wavelength of the plasmonic laser by varying the fast modulation period of the Moiré cavity. This work opens a new way to study SPP-matter interaction dynamics and plasmonic lasing with Bragg cavity confined slow plasmons.
Open Access
LSPR enhanced MSM UV photodetectors
(IOP Publishing, 2012-10-18) Butun, S.; Cinel, N. A.; Özbay, Ekmel
We fabricated localized surface plasmon resonance enhanced UV photodetectors on MOCVD grown semi-insulating GaN. Plasmonic resonance in the UV region was attained using 36nm diameter Al nanoparticles. Extinction spectra of the nanoparticles were measured through spectral transmission measurements. A resonant extinction peak around 300nm was obtained with Al nanoparticles. These particles gave rise to enhanced absorption in GaN at 340nm. Spectral responsivity measurements revealed an enhancement factor of 1.5. These results provided experimental verification for obtaining field enhancement by using Al nanoparticles on GaN.
Open Access
Nanoantenna couplers for metal-insulator-metal waveguide interconnects
(SPIE, 2010) Onbasli, M.C.; Okyay, Ali Kemal
State-of-the-art copper interconnects suffer from increasing spatial power dissipation due to chip downscaling and RC delays reducing operation bandwidth. Wide bandwidth, minimized Ohmic loss, deep sub-wavelength confinement and high integration density are key features that make metal-insulator-metal waveguides (MIM) utilizing plasmonic modes attractive for applications in on-chip optical signal processing. Size-mismatch between two fundamental components (micron-size fibers and a few hundred nanometers wide waveguides) demands compact coupling methods for implementation of large scale on-chip optoelectronic device integration. Existing solutions use waveguide tapering, which requires more than 4λ-long taper distances. We demonstrate that nanoantennas can be integrated with MIM for enhancing coupling into MIM plasmonic modes. Two-dimensional finite-difference time domain simulations of antennawaveguide structures for TE and TM incident plane waves ranging from λ = 1300 to 1600 nm were done. The same MIM (100-nm-wide Ag/100-nm-wide SiO2/100-nm-wide Ag) was used for each case, while antenna dimensions were systematically varied. For nanoantennas disconnected from the MIM; field is strongly confined inside MIM-antenna gap region due to Fabry-Perot resonances. Major fraction of incident energy was not transferred into plasmonic modes. When the nanoantennas are connected to the MIM, stronger coupling is observed and E-field intensity at outer end of core is enhanced more than 70 times. © 2010 SPIE.
Open Access
Novel materials and techniques for energy conversion and sensing
(2015-12) Ekiz, Okan Öner
In the recent years, characterization of nanomaterials and using them in sensing applications gain considerable attention. Increased research on nanotechnology brings new materials and techniques that come with many unsought properties. Additionally, novel materials and concepts have created new demands for new characterization techniques. In this thesis, our main aim is to characterize novel materials and develop new techniques to use nanotechnology in sensing applications. Graphene is one of the most important material in nanotechnology found in the recent years. In this thesis, we have characterized and explain the electrochemical behavior of graphene oxide. During the experiments, novel properties of graphene oxide have been revealed. Foundings paved the way for new applications of graphene. Recent studies in plasmonic materials made SERS (Surface-Enhanced-Raman- Spectroscopy) an important characterization tool used in nanotechnology. SERS is a powerful technique for chemical speci c and label free analysis of low concentration materials. In this thesis, we have used SERS to build an arti cial nose for detection of VOCs. SERS substrates have been fabricated and used for the experiments. Experiments showed that our technique could detect many VOCs and could be used for several applications such as explosive and drug detection. There is a strong need for easy and cost e ective biosensors especially for homecare applications. Recent advances in nanotechnology help us to develop cost e ective techniques. Reducing costs could make biosensors more accessible for end user applications such. In this thesis, we have developed a biosensor platform by using SPR (Surface Plasmon Resonance) for pathogen detection. Experiments showed that our device could detect 102 pathogens without labeling. Our aim is to improve this platform for rapid food analysis and home-care applications.
Open Access
Oligonucleotide-based label-free detection with optical microresonators: strategies and challenges
(Royal Society of Chemistry, 2016) Toren, P.; Ozgur E.; Bayındır, Mehmet
This review targets diversified oligonucleotide-based biodetection techniques, focusing on the use of microresonators of whispering gallery mode (WGM) type as optical biosensors mostly integrated with lab-on-a-chip systems. On-chip and microfluidics combined devices along with optical microresonators provide rapid, robust, reproducible and multiplexed biodetection abilities in considerably small volumes. We present a detailed overview of the studies conducted so far, including biodetection of various oligonucleotide biomarkers as well as deoxyribonucleic acids (DNAs), ribonucleic acids (RNAs) and proteins. We particularly advert to chemical surface modifications for specific and selective biosensing.
Open Access
Optical response of Ag-Au bimetallic nanoparticles to electron storage in aqueous medium
(2008) Tunc, I.; Guvenc, H. O.; Sezen, H.; Süzer, Şefik; Correa-Duarte, M. A.; Liz-Marzán, L. M.
Composition and structure dependence of the shift in the position of the surface plasmon resonance band upon introduction of NaBH 4 to aqueous solutions of gold and silver nanoparticles are presented. Silver and gold nanoalloys in different compositions were prepared by co-reduction of the corresponding salt mixtures using sodium citrate as the reducing agent. After addition of NaBH 4 to the resultant nanoalloys, the maximum of their surface plasmon resonance band, ranging between that of pure silver (ca. 400 nm) and of pure gold (ca. 530 nm), is blue-shifted as a result of electron storage on the particles. The extent of this blue shift increases non-linearly with the mole fraction of silver in the nanoparticle, parallel to the trends reported previously for both the frequency and the extinction coefficient of the plasmon band shifts. Gold(core)@silver(shell) nanoparticles were prepared by sequential reduction of gold and silver, where addition of NaBH 4 results in relatively large spectral shift in the plasmon resonance band when compared with the nanoalloys having a similar overall composition. The origin of the large plasmon band shift in the core-shell is related with a higher silver surface concentration on these particles. Hence, the chemical nature of the nanoparticle emerges as the dominating factor contributing to the extent of the spectral shift as a result of electron storage in bimetallic systems. Copyright © 2008 American Scientific Publishers All rights reserved.
Open Access
Plasmonic band gap structures for surface-enhanced Raman scattering
(Optical Society of American (OSA), 2008) Kocabas, A.; Ertas G.; Senlik, S.S.; Aydınlı, Atilla
Surface-enhanced Raman Scattering (SERS) of rhodamine 6G (R6G) adsorbed on biharmonic metallic grating structures was studied. Biharmonic metallic gratings include two different grating components, one acting as a coupler to excite surface plasmon polaritons (SPP), and the other forming a plasmonic band gap for the propagating SPPs. In the vicinity of the band edges, localized surface plasmons are formed. These localized Plasmons strongly enhance the scattering efficiency of the Raman signal emitted on the metallic grating surfaces. It was shown that reproducible Raman scattering enhancement factors of over 10 5 can be achieved by fabricating biharmonic SERS templates using soft nano-imprint technique. We have shown that the SERS activities from these templates are tunable as a function of plasmonic resonance conditions. Similar enhancement factors were also measured for directional emission of photoluminescence. At the wavelengths of the plasmonic absorption peak, directional enhancement by a factor of 30 was deduced for photoluminescence measurements. © 2008 Optical Society of America.
Open Access
Plasmonic nano-bio sensors for detection of E-coli bacteria
(IEEE, 2009) Cinel, Neval A.; Bütün, Serkan; Çalışkan, Deniz; Özbay, Ekmel
Biological sensors, that rely on localized surface plasmon resonance exhibited by metallic nanocylinders fabricated using electron beam lithography and functionalized with the immobilization of biotin conjugated E-coli antibodies are investigated in this study.