Cucurbituril homologues and derivatives: syntheses and functionalization

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buir.contributor.authorKoҫ, Ahmet
buir.contributor.authorTuncel, Dönüş
dc.citation.epage39en_US
dc.citation.issueNumber1en_US
dc.citation.spage7en_US
dc.citation.volumeNumber36en_US
dc.contributor.authorKoç, Ahmeten_US
dc.contributor.authorTuncel, Dönüşen_US
dc.contributor.editorTuncel, Dönüş
dc.date.accessioned2020-02-25T10:46:43Z
dc.date.available2020-02-25T10:46:43Z
dc.date.issued2019-01
dc.departmentDepartment of Chemistryen_US
dc.departmentInstitute of Materials Science and Nanotechnology (UNAM)en_US
dc.descriptionChapter 2
dc.description.abstractIn this chapter, we discuss the syntheses and functionalization of cucurbituril (CB[n]) homologues and derivatives. We begin with a historical background on CB[n] chemistry, from the first known CB[n] homologue, CB[6], to the latest advances in functionalized CB[n] synthesis. Then we elaborate on unsubstituted CB[n] homologues regarding their synthesis, isolation, formation mechanisms, and structural and physical properties. We broadly discuss the synthesis of substituted CB[n] derivatives with various strategies. There are three known methods to synthesize substituted CB[n] from modified precursors: (1) use of substituted glycoluril, (2) use of substituted glycoluril oligomers and (3) use of aldehydes other than formaldehyde. In the last part of the chapter, we give detailed information on the direct functionalization of CB[n]. This part presents the synthesis of multi- and monohydroxylated derivatives via radical oxidation of CB[n] homologues and their further derivatization to reactive groups bearing multi- and monoalkylated CB[n].en_US
dc.description.provenanceSubmitted by Evrim Ergin (eergin@bilkent.edu.tr) on 2020-02-25T10:46:43Z No. of bitstreams: 1 Bilkent-research-paper (1).pdf: 268963 bytes, checksum: ad2e3a30c8172b573b9662390ed2d3cf (MD5)en
dc.description.provenanceMade available in DSpace on 2020-02-25T10:46:43Z (GMT). No. of bitstreams: 1 Bilkent-research-paper (1).pdf: 268963 bytes, checksum: ad2e3a30c8172b573b9662390ed2d3cf (MD5) Previous issue date: 2019-01en
dc.identifier.doi10.1039/9781788015950-00007en_US
dc.identifier.eisbn9781788015950
dc.identifier.isbn9781788014885
dc.identifier.urihttp://hdl.handle.net/11693/53489
dc.language.isoEnglishen_US
dc.publisherThe Royal Society of Chemistryen_US
dc.relation.ispartofCucurbituril-based functional materials
dc.relation.ispartofseriesSmart Materials Series
dc.relation.isversionofhttps://dx.doi.org/10.1039/9781788015950-00007en_US
dc.titleCucurbituril homologues and derivatives: syntheses and functionalizationen_US
dc.typeBook Chapteren_US

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