Browsing by Subject "Visible spectra"

Now showing 1 - 8 of 8

Open Access
Design strategies for ratiometric chemosensors: modulation of excitation energy transfer at the energy donor site
(2009) Guliyev, R.; Coskun, A.; Akkaya, E. U.
Excitation energy transfer, when coupled to an ion-modulated ICT chromophore, creates novel opportunities in sensing. The direction of energy transfer and the point of ICT modulation can be varied as desired. In our previous work, we have shown that energy transfer efficiency between two energetically coupled fluorophores will be altered by the metal ion binding to the ICT chromophore carrying a ligand. There are two beneficial results: increased pseudo-Stokes shift and expanded dynamic range. Here, we explored the consequences of the modulation of energy transfer efficiency at the energy donor site, in a molecular design which has an ICT type metal ion-sensitive chromophore placed as the energy donor in the dyad. Clear advantages emerge compared to the acceptor site modulation: unaltered emission wavelength in the red end of the visible spectrum, while keeping a large Stokes shift and the ratiometric character. © 2009 American Chemical Society.
Open Access
Dynamic tuning of plasmon resonance in the visible using graphene
(The Optical Society, 2016) Balci, S.; Balci, O.; Kakenov, N.; Atar, F. B.; Kocabas, C.
We report active electrical tuning of plasmon resonance of silver nanoprisms (Ag NPs) in the visible spectrum. Ag NPs are placed in close proximity to graphene which leads to additional tunable loss for the plasmon resonance. The ionic gating of graphene modifies its Fermi level from 0.2 to 1 eV, which then affects the absorption of graphene due to Pauli blocking. Plasmon resonance frequency and linewidth of Ag NPs can be reversibly shifted by 20 and 35 meV, respectively. The coupled graphene-Ag NPs system can be classically described by a damped harmonic oscillator model. Atomic layer deposition allows for controlling the graphene-Ag NP separation with atomic-level precision to optimize coupling between them.
Open Access
Flame detection for video-based early fire warning for the protection of cultural heritage
(2012-10-11) Dimitropoulos, K.; Günay, Osman; Köse, Kıvanç; Erden, Fatih; Chaabene, F.; Tsalakanidou, F.; Grammalidis, N.; Çetin, Enis
Cultural heritage and archaeological sites are exposed to the risk of fire and early warning is the only way to avoid losses and damages. The use of terrestrial systems, typically based on video cameras, is currently the most promising solution for advanced automatic wildfire surveillance and monitoring. Video cameras are sensitive in visible spectra and can be used either for flame or smoke detection. This paper presents and compares three video-based flame detection techniques, which were developed within the FIRESENSE EU research project. © 2012 Springer-Verlag Berlin Heidelberg.
Open Access
Graphene-based optical modulators
(World Scientific Publishing Co. Pte. Ltd., 2017) Balci S.; Kocabas, C.
In this chapter, we summarize the recent progress on graphene based optical modulators. Ability to control density of high mobility electrons on large area graphene surface enables realization of new type of electrooptical modulators in optoelectronics. Due to the low electronic density of states, accumulation of charges on graphene significantly shifts the Fermi energy up to 1 eV giving rise to profound optical effects in the infrared and visible spectra. On the other hand, graphene operates as a tunable Drude metal in long wavelengths such as THz and microwave. This unique broadband activity of graphene has stimulated a great deal of interest in graphene community due to its potential use in new optoelectronic devices. After discussing the electrically tunable optical properties of graphene, we highlight the key achievements in the field.
Open Access
Graphene-enabled optoelectronics on paper
(American Chemical Society, 2016-06) Polat, E. O.; Uzlu, H. B.; Balci, O.; Kakenov, N.; Kovalska, E.; Kocabas, C.
The realization of optoelectronic devices on paper has been an outstanding challenge due to the large surface roughness and incompatible nature of paper with optical materials. Here, we demonstrate a new class of optoelectronic devices on a piece of printing paper using graphene as an electrically reconfigurable optical medium. Our approach relies on electro-modulation of optical properties of multilayer graphene on paper via blocking the interband electronic transitions. The paper based devices yield high optical contrast in the visible spectrum with a fast response. Pattering graphene into multiple pixels, folding paper into three-dimensional shapes or printing colored ink on paper substrates enable us to demonstrate novel optoelectronic devices which cannot be realized with wafer-based techniques.
Open Access
Plasmonic absorbers for multispectral and broadband absorption
(SPIE, 2012) Ayaş, Sencer; Güner, Hasan; Türker, Burak; Ekiz, Öner; Dana, Aykutlu
We present polarization dependent multispectral and broadband plasmonic absorbers in the visible spectrum. The spectral characteristics of these structures are tunable over a broad spectrum. Experimental results are verified with the FDTD and RCWA analysis methods. These structures are used as surface enhanced raman spectroscopy(SERS) substrates. Designed structures have resonances that span the Raman Stokes and excitation wavelength. Such structures can be used for energy, LED and other spectroscopy applications. © 2012 Copyright Society of Photo-Optical Instrumentation Engineers (SPIE).
Open Access
A plasmonic enhanced photodetector based on silicon nanocrystals obtained through laser ablation
(Institute of Physics Publishing, 2012-10-18) Alkis, S.; Oruç, F. B.; Ortaç, B.; Koşger, A. C.; Okyay, Ali Kemal
We present a proof-of-concept photodetector which is sensitive in the visible spectrum. Silicon nanocrystals (Si-NCs) obtained by laser ablation are used as the active absorption region. Si-NC films are formed from a polymeric dispersion. The films are sandwiched between thin insulating films to reduce the electrical leakage current. Furthermore, Ag nanoparticles are integrated with the photodetector to enhance the visible response using plasmonic effects. The measured photocurrent is resonantly enhanced, which is explained in terms of enhanced local fields caused by localized plasmons. The UV-vis spectrum of Ag nanoparticles is also measured to verify the resonance.
Open Access
Plasmonically enhanced ZnO thin-film-photo-transistor with dynamic responsivity control
(IEEE, 2013) Özcan, Ayşe; Battal, Enes; Atar, Fatih Bilge; Okyay, Ali Kemal
We fabricated an ZnO based thin-film photo-transistor with electrically tunable photo-responsivity operating in the UV and visible spectra and designed plasmonic structures enhancing the device performance up to 6 folds below the band-gap of ZnO. © 2013 IEEE.