Browsing by Subject "Nanocrystalline materials"

Now showing 1 - 5 of 5

Open Access
Effect of milling time on the structure, micro-hardness, and thermal behavior of amorphous/nanocrystalline TiNiCu shape memory alloys developed by mechanical alloying
(Elsevier Ltd, 2014) Alijani F.; Amini, R.; Ghaffari, M.; Alizadeh, M.; Okyay, Ali Kemal
In the present paper, the effect of milling process on the chemical composition, structure, microhardness, and thermal behavior of Ti-41Ni-9Cu compounds developed by mechanical alloying was evaluated. The structural characteristic of the alloyed powders was evaluated by X-ray diffraction (XRD). The chemical composition homogeneity and the powder morphology and size were studied by scanning electron microscopy coupled with electron dispersive X-ray spectroscopy. Moreover, the Vickers micro-indentation hardness of the powders milled for different milling times was determined. Finally, the thermal behavior of the as-milled powders was studied by differential scanning calorimetery. According to the results, at the initial stages of milling (typically 0-12. h), the structure consisted of a Ni solid solution and amorphous phase, and by the milling evolution, nanocrystalline martensite (B19') and austenite (B2) phases were initially formed from the initial materials and then from the amorphous phase. It was found that by the milling development, the composition uniformity is increased, the inter-layer thickness is reduced, and the powders microhardness is initially increased, then reduced, and afterward re-increased. It was also realized that the thermal behavior of the alloyed powders and the structure of heat treated samples is considerably affected by the milling time.
Open Access
Effects of milling and annealing on formation and structural characterization of nanocrystalline intermetallic compounds from Ni-Ti elemental powders
(2012) Ghadimi, M.; Shokuhfar, A.; Rostami H.R.; Ghaffari, M.
Nickel and Titanium elemental powders with a nominal composition Ni-50 at.%Ti were mechanical alloyed in a planetary high-energy ball mill in different milling conditions (5, 10, 20, 40 and 60 h). The investigation revealed that increasing milling time leads to a reduction in crystallite size, and after 60 h of milling, the Ti dissolved in Ni lattice and NiTi (B2) phase was obtained. With milling time, morphology of pre-alloyed powders changed from lamella to globular. Annealing of as-milled powders at 1173 K for 900 s led to formation of nanocrystalline NiTi (B19′), grain growth and release of internal strain. The results indicated that this technique is a powerful and high productive process for preparing NiTi intermetallic compound with nanocrystalline structure and appropriate morphology. © 2012 Elsevier B.V. All rights reserved.
Open Access
Liquid-phase sintering of medical-grade P558 stainless steel using a new biocompatible eutectic additive
(Elsevier, 2012-02-02) Salahinejad, E.; Hadianfard, M. J.; Ghaffari, M.; Mashhadi, S. B.; Okyay, Ali Kemal
One of the effective approaches to reduce residual pores in powder metallurgy parts is activated liquid-phase sintering process using proper additives. In this work, for the first time, a new biocompatible additive (Mn-11.5 wt.% Si, a eutectic alloy) is experimented for liquid-phase sintering of nanocrystalline/amorphous P558 stainless steel powders. It is realized that by increasing the sintering aid content and temperature, the density is effectively increased: a sharp densification progress when the sintering temperature increases from 1000 °C to 1050 °C and a slower densification rate when it exceeds 1050 °C. This preliminary study opens up the development of high-density medical-grade stainless steels produced by powder metallurgy, where suitable additives can lower sintering temperature and time, which is promising for retarding grain growth and commercial applications.
Open Access
Multiexciton generation assisted highly photosensitive CdHgTe nanocrystal skins
(Elsevier Ltd, 2016) Akhavan S.; Cihan, A. F.; Yeltik A.; Bozok, B.; Lesnyak, V.; Gaponik N.; Eychmüller A.; Demir, Hilmi Volkan
Multiexciton Generation (MEG) enabled by the photogeneration of more than one electron-hole pairs upon the absorption of a single photon observed in colloidal semiconductor nanocrystals (NCs) is an essential key to high efficiency when operating in large enough photon energy regimes. Here, we report a newly designed class of solution-processed highly sensitive MEG-assisted photosensors of CdHgTe NCs, in which the charge accumulation is dramatically enhanced for photon energies greater than two times the bandgap of the employed NCs. We fabricated and comparatively studied five types of devices based on different NC monolayers of selected quantum-confined bandgaps resulting in different levels of photovoltage buildup readouts. Among these photosensitive platforms, MEG is distinctly observed for CdHgTe NCs, as the number of electrons trapped inside these NCs and the number of holes accumulating into the interfacing metal electrode were increased beyond a single exciton per absorbed photon. Furthermore, we conducted time-resolved fluorescence measurements and confirmed the occurrence of MEG in the CdHgTe NC monolayer of the photosensor. These findings pave the way for engineering of multiexciton kinetics in high-efficiency NC-based photosensors and photovoltaics.
Open Access
Photovoltaic nanocrystal scintillators hybridized on Si solar cells for enhanced conversion efficiency in UV
(Optical Society of American (OSA), 2008) Mutlugun, E.; Soganci I.M.; Demir, Hilmi Volkan
We propose and demonstrate semiconductor nanocrystal based photovoltaic scintillators integrated on solar cells to enhance photovoltaic device parameters including spectral responsivity, open circuit voltage, short circuit current, fill factor, and solar conversion efficiency in the ultraviolet. Hybridizing (CdSe)ZnS core-shell quantum dots of 2.4 nm in diameter on multi-crystalline Si solar cells for the first time, we show that the solar conversion efficiency is enhanced 2 folds under white light illumination similar to the solar spectrum. Such nanocrystal scintillators provide the ability to extend the photovoltaic activity towards UV. © 2008 Optical Society of America.