Browsing by Subject "Anisotropy"
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Item Open Access 2D anisotropic photonic crystals of hollow semiconductor nanorod with liquid crystals(2013) Karaomerlioglu F.; Şimsek, Şevket; Mamedov, Amirullah M.; Özbay, EkmelPhotonic crystals (PCs) have many applications in order to control light-wave propagation. A novel type of two-dimensional anisotropic PC is investigated band gap and optical properties as a hollow semiconductor nanorod with nematicliquid crystals (LC). The PC structure composed of an anisotropic nematicLC in semiconductor square hollow nanorod is designed using the plane wave expansion (PWE) method and finite-difference time-domain (FDTD) method. It has been used 5CB (4-pentyl-4'-cyanobiphenyl) as LC core, and Tellurium (Te) as square hollow nanorod material.The PC with hollow Tenanorod with nematicLC is compared with the PC with solid Tenanorodand the PC with hollow Tenanorod. © (2013) Trans Tech Publications, Switzerland.Item Open Access Angular dependence of upper critical field in two-band Ginzburg-Landau theory(Elsevier B.V., 2007) Askerzade, I. N.; Tanatar, BilalGeneralization of two-band Ginzburg-Landau (GL) theory to the case of anisotropic mass is presented. The temperature dependence of the anisotropy parameter of upper critical field γc 2 (T) = Hc 2∥ (T) / Hc 2⊥ (T) and angular dependence of Hc2(θ, T) are calculated using anisotropic mass two-band Ginzburg-Landau theory of superconductors. It is shown that, with decreasing temperature anisotropy parameter γc2(T) is increased. Results of our calculations are in agreement with experimental data for single crystal MgB2. © 2007.Item Open Access Anharmonic line shift and linewidth of the Raman modes in TlInS2 layered crystals(John Wiley & Sons Ltd., 2004) Yuksek, N. S.; Gasanly, N. M.; Aydınlı, AtillaThe temperature dependence of the unpolarized Raman spectra from TlInS 2 layered crystal was measured between 10 and 300 K. The analysis of the experimental data showed that the temperature dependences of wavenumbers and linewidths are well described by considering the contributions from thermal expansion and lattice anharmonicity. The purely anharmonic contribution (phonon-phonon coupling) was found to be due to three-phonon processes. This work demonstrates that the two Raman modes at 280.9 and 292.3 cm-1 exhibit changes toward high wavenumbers as the temperature is raised from 10 to 300 K.Item Open Access Anisotropic electronic, mechanical, and optical properties of monolayer WTe2(American Institute of Physics Inc., 2016) Torun, E.; Sahin, H.; Cahangirov, S.; Rubio, A.; Peeters, F. M.Using first-principles calculations, we investigate the electronic, mechanical, and optical properties of monolayer WTe2. Atomic structure and ground state properties of monolayer WTe2 (Td phase) are anisotropic which are in contrast to similar monolayer crystals of transition metal dichalcogenides, such as MoS2, WS2, MoSe2, WSe2, and MoTe2, which crystallize in the H-phase. We find that the Poisson ratio and the in-plane stiffness is direction dependent due to the symmetry breaking induced by the dimerization of the W atoms along one of the lattice directions of the compound. Since the semimetallic behavior of the Td phase originates from this W-W interaction (along the a crystallographic direction), tensile strain along the dimer direction leads to a semimetal to semiconductor transition after 1% strain. By solving the Bethe-Salpeter equation on top of single shot G0W0 calculations, we predict that the absorption spectrum of Td-WTe2 monolayer is strongly direction dependent and tunable by tensile strain.Item Open Access Anisotropic stimulated emission from aligned CdSe/CdS dot-in-rods(IEEE, 2014-10) Gao, Y.; Ta, V. D.; Zhao, X.; Wang, Y.; Chen, R.; Zhao, Y.; Dang, C.; Sun, X.; Sun, H.; Demir, Hilmi VolkanAnisotropic optical properties of CdSe/CdS dot-in-rods loaded in a capillary tube are demonstrated, suggesting nanorods' alignment with a microfluidic approach. Polarized emissions from photoluminescence and whispering gallery mode lasing show promising applications for lighting and displays. © 2014 IEEE.Item Open Access Anisotropy sensitivity of an acoustic lens with slit aperture(IEEE, 1993) Atalar, Abdullah; Ishikawa, I.; Ogura, Y.; Tomita, K.A conventional spherical acoustic lens is modified by restricting its aperture in the form of a slit to provide directional sensitivity. The spacing between the two parallel absorbing sheets forming the slit is adjustable to obtain varying slit widths. The resulting lens can be used in conjunction with V(Z) method to obtain leaky wave velocities of the sample under investigation as a function of direction. The theoretical V(Z) analysis of the lens involves a two-dimensional integral rather than one-dimensional integral of the conventional lens. Single crystal anisotropic materials are chosen as test samples. Reflection coefficients for anisotropic single crystals of given surface cut and orientation are calculated. Numerically evaluated V(Z) curves are used to deduce the surface wave velocity of the object for the given orientation. This is compared with the surface wave velocity directly calculated from the elastic parameters of the object. Results show the compromise between signal-to-noise ratio and angular resolution as the slit width is varied. V(Z) measurement results of a slitted lens are presented to be compared with calculated curves. The new lens is used to measure the acoustic velocity on the (001) surface of GaAs along varying directions with differing slit widths.Item Open Access Bio-inspired hierarchically structured polymer fibers for anisotropic non-wetting surfaces(Royal Society of Chemistry, 2017) Yunusa, M.; Ozturk, F. E.; Yildirim, A.; Tuvshindorj, U.; Kanik, M.; Bayındır, MehmetWe demonstrate a rice leaf-like hierarchically textured polymer fiber array for anisotropic non-wetting surfaces. To provide superhydrophobicity in addition to the anisotropic behavior, fiber surfaces are spray coated with organically modified silica nanoparticles. The resulting micro/nano hierarchically structured fiber surfaces demonstrate anisotropic non-wetting properties. We designed various fiber architectures for droplet transportation, mixing, and guiding exploiting the scalability of the fiber texture during thermal drawing; optional nanoparticle surface modification; and inherent flexibility of the fibers.Item Open Access Density profile of a Bose-Einstein condensate inside a pancake-shaped trap: Observational consequences of the dimensional cross-over in the scattering properties(Elsevier Science B.V., 2002) Tanatar, Bilal; Minguzzi, A.; Vignolo, P.; Tosi, M. P.It is theoretically well known that two-dimensionality of the scattering events in a Bose-Einstein condensate introduces a logarithmic dependence on density in the coupling constant entering a mean-field theory of the equilibrium density profile, which becomes dominant as the s-wave scattering length gets larger than the condensate thickness. We trace the regions of experimentally accessible system parameters for which the cross-over between different dimensionality behaviors in the scattering properties may become observable through in situ imaging of the condensed cloud with varying trap anisotropy and scattering length.Item Open Access Effects of anisotropy on the critical temperature in layered nonadiabatic superconductors(Elsevier Science B.V., 2003) Askerzade, I. N.; Tanatar, BilalThe generalized anisotropic Eliashberg theory is employed to study the critical temperature of layered nonadiabatic superconductors where the relevant phonon energy is comparable to the Fermi energy. We consider a two-dimensional model appropriate for cuprate compounds and recently discovered superconductor magnesium-diboride (MgB2) which also reveals layered structure. By using the McMillan approximation we present the result of calculations of critical temperature Tc. It is shown that the critical temperature is enhanced due to the influence of anisotropy and nonadiabaticity.Item Open Access Free expansion of two-dimensional condensates with a vortex(Institute of Physics Publishing, 2003) Hoşten, O.; Vignolo, P.; Minguzzi, A.; Tanatar, Bilal; Tosi, M. P.We study the free expansion of a pancake-shaped Bose-condensed gas, which is initially trapped under harmonic confinement and containing a vortex at its centre. In the case of a radial expansion holding the axial confinement fixed we consider various models for the interactions, depending on the thickness of the condensate relative to the value of the scattering length. We are thus able to evaluate different scattering regimes ranging from quasi-three-dimensional (Q3D) to strictly two-dimensional (2D). We find that as the system goes from Q3D to 2D the expansion rate of the condensate increases whereas that of the vortex core decreases. In the Q3D scattering regime we also examine a fully free expansion in 3D and find oscillatory behaviour for the vortex core radius: an initial fast expansion of the vortex core is followed by a slowing down. Such a nonuniform expansion rate of the vortex core implies that the timing of its observation should be chosen appropriately.Item Open Access Identification of materials with magnetic characteristics by neural networks(2012) Nazlibilek, S.; Ege, Y.; Kalender O.; Sensoy, M.G.; Karacor, D.; Sazli, M.H.In industry, there is a need for remote sensing and autonomous method for the identification of the ferromagnetic materials used. The system is desired to have the characteristics of improved accuracy and low power consumption. It must also autonomous and fast enough for the decision. In this work, the details of inaccurate and low power remote sensing mechanism and autonomous identification system are given. The remote sensing mechanism utilizes KMZ51 anisotropic magneto-resistive sensor with high sensitivity and low power consumption. The images and most appropriate mathematical curves and formulas for the magnetic anomalies created by the magnetic materials are obtained by 2-D motion of the sensor over the material. The contribution of the paper is the use of the images obtained by the measurement of the perpendicular component of the Earth magnetic field that is a new method for the purpose of identification of an unknown magnetic material. The identification system is based on two kinds of neural network structures. The MultiLayer Perceptron (MLP) and the Radial Basis Function (RBF) network types are used for training of the neural networks. In this work, 23 different materials such as SAE/AISI 1030, 1035, 1040, 1060, 4140 and 8260 are identified. Besides the ferromagnetic materials, three objects are also successfully identified. Two of them are anti-personal and anti-tank mines and one is an empty can box. It is shown that the identification system can also be used as a buried mine identification system. The neural networks are trained with images which are originally obtained by the remote sensing system and the system is operated by images with added Gaussian white noises. © 2012 Elsevier Ltd. All rights reserved.Item Open Access Investigation of new two-dimensional materials derived from stanene(Elsevier, 2017-09) Fadaie, M.; Shahtahmassebi, N.; Roknabad, M. R.; Gulseren, O.In this study, we have explored new structures which are derived from stanene. In these new proposed structures, half of the Sn atoms, every other Sn atom in two-dimensional (2D) buckled hexagonal stanene structure, are replaced with a group- IV atom, namely C, Si or Ge. So, we investigate the structural, electronic and optical properties of SnC, SnGe and SnSi by means of density functional theory based first-principles calculations. Based on our structure optimization calculations, we conclude that while SnC assumes almost flat structure, the other ones have buckled geometry like stanene. In terms of the cohesive energy, SnC is the most stable structure among them. The electronic properties of these structures strongly depend on the substituted atom. We found that SnC is a large indirect band gap semiconductor, but SnSi and SnGe are direct band gap ones. Optical properties are investigated for two different polarization of light. In all structures considered in this study, the optical properties are anisotropic with respect to the polarization of light. While optical properties exhibit features at low energies for parallel polarization, there is sort of broad band at higher energies after 5 eV for perpendicular polarization of the light. This anisotropy is due to the 2D nature of the structures. © 2017 Elsevier B.V.Item Open Access Labyrinth based left-handed metamaterials and sub-wavelength focusing of electromagnetic waves(SPIE, 2006) Özbay, Ekmel; Bulu, İrfan; Çağlayan, HümeyraWe propose and demonstrate a resonant structure that solves two major problems related to the split-ring resonator structure. These major problems may be stated as the bianisotropy and electric coupling to the magnetic resonance. These two problems introduce difficulties in obtaining isotropic left-handed metamaterial mediums. The resonant structure that we propose here solves both of these problems. We further show that in addition to the magnetic resonance, when combined with a suitable wire medium, the structure that we propose exhibits left-handed transmission band. We further demonstrate the sub-wavelength focusing of electromagnetic waves by use of a two dimensional labyrinth based metamaterial. Our experimental results showed that it is possible to focus the source field with half widths as small as λ/4 by using the labyrinth based metamaterial.Item Open Access Magnetic-field dependence of low-temperature mobility in quasi-one-dimensional electron systems(Institute of Physics Publishing Ltd., 1994) Tanatar, Bilal; Constantinou, N. C.We study the mobility of a quasi-one-dimensional (Q1D) electron system in the presence of an axial magnetic field at low temperatures. We consider the mobility limits for remote-impurity scattering, homogeneous-background scattering, interface-roughness scattering, and alloy-disorder scattering mechanisms. For a system in which all carriers are in the lowest subband, the electron-impurity interaction is modelled for the above cases, and analytic expressions are derived. Calculations appropriate for a GaAs Q1D structure are presented for typical wire radius R, electron density N, impurity density Ni, and applied magnetic field B.Item Open Access Microfluidic methods in janus particle synthesis(Dove Medical Press Ltd, 2022-09-19) Saqib, Muhammad; Tran, Phong A.; Ercan, Batur; Yegan Erdem, EmineJanus particles have been at the center of attention over the years due to their asymmetric nature that makes them superior in many ways to conventional monophase particles. Several techniques have been reported for the synthesis of Janus particles; however, microfluidic-based techniques are by far the most popular due to their versatility, rapid prototyping, low reagent consumption and superior control over reaction conditions. In this review, we will go through microfluidic-based Janus particle synthesis techniques and highlight how recent advances have led to complex functionalities being imparted to the Janus particles. © 2022 Saqib et al.Item Open Access Numerical analysis for remote identification of materials with magnetic characteristics(2011) Ege, Y.; Şensoy, M.G.; Kalender O.; Nazlibilek, S.There is a variety of methods used for remote sensing of objects such as acoustic, ground penetration radar detection, electromagnetic induction spectroscopy, infrared imaging, thermal neutron activation, core four-pole resonance, neutron backscattering, X-ray backscattering, and magnetic anomaly. The method that has to be used can be determined by the type of material, geographical location (underground or water), etc. Recent studies have been concentrated on the improvement of the criteria such as sensing distances, accuracy, and power consumption. In this paper, anomalies created by materials with magnetic characteristics at the perpendicular component of the Earth magnetic field have been detected by using a KMZ51 anisotropic magnetoresistive sensor with high sensitivity and low power consumption, and also, the effects of physical properties of materials on magnetic anomaly have been investigated. By analyzing the graphics obtained by 2-D motion of the sensor over the material, the most appropriate mathematical curves and formulas have been determined. Based on the physical properties of the magnetic material, the variations of the variables constituting the formulas of the curves have been analyzed. The contribution of this paper is the use of the results of these analyses for the purpose of identification of an unknown magnetic material. This is a new approach for the detection and determination of materials with magnetic characteristics by sensing the variation at the perpendicular component of the Earth magnetic field. The identification process has been explained in detail in this paper. © 2011 IEEE.Item Open Access One-pot synthesis of CdS nanoparticles in the channels of mesosructured silica films and monoliths(American Chemical Society, 2005) Tura, C.; Coombs, N.; Dag, Ö.Cd(II)-modified mesoporous silica films and/or monoliths synthesized in one pot using a true liquid crystalline (TLC) approach have been reacted with H2S gas to produce CdS-modified mesostructured nanocomposite materials (Nano-CdS/meso-SiO2). During this process, both the TLC and the metallotropic liquid crystalline (MLC) mesophase of metal salt ([Cd(H 2O)4](NO3)2)-nonionic surfactant (CnH2n+1- (OCH2CH2)mOH, CnEOm) systems were collectively used to incorporate large quantities of metal ions into the mesoporous silica film and monoliths. The effect of the cadmium nitrate concentration on the formation and structure of the mesoporous silica has also been investigated. The results show that at low salt concentrations, the mesoporous silica is anisotropic (hexagonal); however, at high salt concentration, the structure is isotropic (cubic or disordered). The freshly prepared CdS nanoparticles are reactive toward the surface acids that form during the H2S treatment. These surface acids also promote the degradation of the CdS nanopaticles. However, the CdS particles in the mesopores can be stabilized by washing out the acid sides or aging the samples for a period of time before the H2S reaction. The optical absorption edge of the CdS nanoparticle in the pores is sensitive to the composition and structure of the host. In this context, the materials were characterized using FTIR, micro-Raman, UV-visible absorption spectroscopy, POM, TEM, and PXRD techniques.Item Open Access Organization of bridging organics in periodic mesoporous organosilicas (PMOs)-polarization micro-raman spectroscopy(Wiley, 2001) Dag, Ö.; Ozin, G. A.The organization of bridging organics in oriented periodic mesoporous organosilica film (OPMOF) was demonstrated using the polarization micro-Raman spectroscopy (PMRS) in conjunction with powder x-ray diffraction (PXRD) and polarization optical microscopy (POM). The synthesis and the structural characterization of hexagonal symmetry OPMOF containing bridge-bonded ethane, ethene inside the silica channel walls were described. The mesoscale channels were found to run parallel to the surface of the underlying glass substrates as demonstrated by the PXRD measurements. A hexagonal array of channels with glassy silica organosilica walls was the best description of the structure shown by the PMRS measurements of OPMOF.Item Open Access Prism coupling technique investigation of elasto-optical properties of thin polymer films(American Institute of Physics, 2004) Ay, F.; Kocabas, A.; Kocabas, C.; Aydınlı, Atilla; Agan, S.The use of thin polymer films in optical planar integrated optical circuits is rapidly increasing. Much interest, therefore, has been devoted to characterizing the optical and mechanical properties of thin polymer films. This study focuses on measuring the elasto-optical properties of three different polymers; polystyrene, polymethyl-methacrylate, and benzocyclobutane. The out-of-plane elastic modulus, refractive index, film thickness, and birefringence of thin polymer films were determined by means of the prism coupling technique. The effect of the applied stress on the refractive index and birefringence of the films was investigated. Three-dimensional finite element method analysis was used so as to obtain the principal stresses for each polymer system, and combining them with the stress dependent refractive index measurements, the elasto-optic coefficients of the polymer films were determined. It was found that the applied stress in the out-of-plane direction of the thin films investigated leads to negative elasto-optic coefficients, as observed for all the three thin polymer films.Item Open Access Silver nitrate/oligo(ethylene oxide) surfactant/mesoporous silica nanocomposite films and monoliths(Academic Press, 2001) Samarskaya, O.; Dag, Ö.A lyotropic, liquid crystalline (LC) phase of a silver nitrate/oligo(ethylene oxide), water, and acid mixture was used for one-pot synthesis of mesoporous silica materials in which Ag+ ions are uniformly distributed. We established that the AgNO3-to-surfactant mole ratio is very important in a 50 wt% surfactant/water system to preserve the hexagonal LC phase before and after the addition of the silica source. Below a 0.6 AgNO3-to-surfactant mole ratio, the mixture is liquid crystalline and serves as a template for silica polymerization. However, between 0.6 and 0.8 AgNO3-to-surfactant mole ratios, one must control the composition of the mixture during the polymerization processes. Above a 0.8 mole ratio, Ag+ ions undergo phase separation from the reaction mixture by complexing with the surfactant molecules. The resulting silica materials obtained from AgNO3/surfactant ratio above 0.8 have anisotropy but without a hexagonal mesophase. Here, we establish a AgNO3 concentration range in which the LC phase is preserved to template the synthesis of mesoporous silica, and we discuss the structural behavior of the mixtures at AgNO3/surfactant mole ratios of 0.00-2.00, using POM, PXRD, FTIR, and UV-Vis absorption spectroscopy. © 2001 Academic Press.