Browsing by Author "Cakmakyapan, S."

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Open Access
An array of surface-enhanced Raman scattering substrates based on plasmonic lenses
(Wiley, 2012-10-01) Kahraman, M.; Cakmakyapan, S.; Özbay, Ekmel; Culha, M.
An array of ring-shaped holes is prepared from silver thin films using electron beam lithography. The optimal conditions for high performance as a surface-enhanced Raman scattering (SERS) substrate are investigated. Either the diameter of the hole (0.5, 1.0, 2.0, 3.0 and 4.0 μm) or the slit width (200, 300, 400, 500 and 600 nm) is varied. 4-Aminothiophenol (ATP) adsorbed on the structures as a self-assembled monolayer (SAM) is used as probe to evaluate the SERS performance of the generated structures. It is found that there is an optimal configuration for ring-shaped holes with a 3.0-μm diameter and 200-nm slit width. The SERS activity on this optimal lens configuration is found to be 13 times greater than that of the activity on the silver thin film. An array of these structures at this optimal configuration can easily be constructed and used in a range of SERS-based sensing applications. An array of ring-shaped holes is prepared from silver thin films using electron beam lithography. The optimal conditions for high performance as a surface-enhanced Raman scattering (SERS) substrate are investigated. It is found that there is an optimal configuration for ring-shaped holes with a 3.0-μm diameter and 200-nm slit with. The SERS activity on this optimal lens configuration is found to be 13 times greater than that of the activity on the silver thin film.
Open Access
Comparison of back and top gating schemes with tunable graphene fractal metasurfaces
(American Chemical Society, 2016) Aygar, A. M.; Balci, O.; Cakmakyapan, S.; Kocabas, C.; Caglayan, H.; Özbay, Ekmel
In this work, fractal metasurfaces that consist of periodic gold squares on graphene are used to increase light-graphene interaction. We show by simulations and experiments that higher level fractal structures result in higher spectral tunability of resonance wavelength. This is explained by higher field localization for higher level fractal structures. Furthermore, spectral tunability of fractal metasurfaces integrated with graphene is investigated comparing two different schemes for electrostatic gating. Experiment results show that a top-gated device yields more spectral tunability (8% of resonance wavelength) while requiring much smaller gate voltages compared to the back-gated device. © 2016 American Chemical Society.
Open Access
Concentric ring structures as efficient SERS substrates
(Institute of Electrical and Electronics Engineers, 2013) Cinel, N. A.; Cakmakyapan, S.; Ertas, G.; Özbay, Ekmel
Plasmonic nanopatterned structures that can work as highly efficient surface-enhanced Raman scattering (SERS) substrates are presented in this study. A 'coupled' concentric ring structure has been designed, fabricated, tuned, and compared to an 'etched' concentric ring structure and plain gold film via SERS experiments. The proposed design gives Raman signal intensity 630 times larger than plain gold film and 8 times larger than an 'etched' concentric ring structure. The surface plasmons were imaged with the fluorescence imaging technique and supporting numerical simulations were done.
Open Access
Coupling enhancement of split ring resonators on graphene
(Pergamon Press, 2014-12) Cakmakyapan, S.; Caglayan, H.; Özbay, Ekmel
Metallic split ring resonator (SRR) structures are used in nanophotonics applications in order to localize and enhance incident electromagnetic field. Electrically controllable sheet carrier concentration of graphene provides a platform where the resonance of the SRRs fabricated on graphene can be tuned. The reflectivity spectra of SRR arrays shift by applying gate voltage, which modulates the sheet carrier concentration, and thereby the optical conductivity of monolayer graphene. We experimentally and numerically demonstrated that the tuning range can be increased by tailoring the effective mode area of the SRR and enhancing the interaction with graphene. The tuning capability is one of the important features of graphene based tunable sensors, optical switches, and modulator applications. © 2014 Elsevier Ltd. All rights reserved.
Open Access
E-Beam lithography designed substrates for surface enhanced Raman spectroscopy
(Elsevier BV, 2015-06) Cinel, N. A.; Cakmakyapan, S.; Butun, S.; Ertas, G.; Özbay, Ekmel
Surface Enhanced Raman Spectroscopy (SERS) is a popular method that amplifies weak Raman signals from Raman-active analyte molecules making use of certain specially-prepared metallic surfaces. The main challenge in SERS is to design and fabricate highly repeatable, predictable, and sensitive substrates. There are many fabrication methods that strive to achieve this goal, which are briefly summarized in this paper. The E-beam lithography method is proposed to be superior to the mentioned techniques. In this paper, we review how EBL can be utilized in the preparation of SERS substrates and we discuss the contributions to the field by the Özbay group.
Open Access
Effective mass of electron in monolayer graphene: Electron-phonon interaction
(AIP Publishing LLC, 2013-01-25) Tiras, E.; Ardali, S.; Tiras, T.; Arslan, E.; Cakmakyapan, S.; Kazar, O.; Hassan, J.; Janzén, E.; Özbay, Ekmel
Shubnikov-de Haas (SdH) and Hall effect measurements performed in a temperature range between 1.8 and 275 K, at an electric field up to 35 kV m -1 and magnetic fields up to 11 T, have been used to investigate the electronic transport properties of monolayer graphene on SiC substrate. The number of layers was determined by the use of the Raman spectroscopy. The carrier density and in-plane effective mass of electrons have been obtained from the periods and temperature dependencies of the amplitude of the SdH oscillations, respectively. The effective mass is in good agreement with the current results in the literature. The two-dimensional (2D) electron energy relaxations in monolayer graphene were also investigated experimentally. The electron temperature (Te) of hot electrons was obtained from the lattice temperature (TL) and the applied electric field dependencies of the amplitude of SdH oscillations. The experimental results for the electron temperature dependence of power loss indicate that the energy relaxation of electrons is due to acoustic phonon emission via mixed unscreened piezoelectric interaction and deformation-potential scattering.
Open Access
Experimental validation of strong directional selectivity in nonsymmetric metallic gratings with a subwavelength slit
(American Institute of Physics, 2011-02-02) Cakmakyapan, S.; Caglayan, H.; Serebryannikov, A. E.; Özbay, Ekmel
Strong directional selectivity is theoretically predicted and experimentally validated at the microwave frequencies in the beaming regime for a single subwavelength slit in nonsymmetric metallic gratings with double-side corrugations. The operation regime can be realized at a fixed angle of incidence when the surface-plasmon assisted transmission is significant within a narrow range of observation angles, if illuminating one of the grating interfaces, and tends to vanish for all observation angles, if illuminating the opposite interface. The studied effect is connected with asymmetry (nonreciprocity) in the beaming that occurs if the surface plasmon properties are substantially different for the two interfaces being well isolated from each other.
Open Access
Fano resonances in THz metamaterials composed of continuous metallic wires and split ring resonators
(Optical Society of America, 2014) Li, Z.; Cakmakyapan, S.; Butun, B.; Daskalaki, C.; Tzortzakis, S.; Yang, X.; Özbay, Ekmel
We demonstrate theoretically and experimentally that Fano resonances can be obtained in terahertz metamaterials that are composed of periodic continuous metallic wires dressed with periodic split ring resonators. An asymmetric Fano lineshape has been found in a narrow frequency range of the transmission curve. By using a transmission line combined with lumped element model, we are able to not only fit the transmission spectra of Fano resonance which is attributed to the coupling and interference between the transmission continuum of continuous metallic wires and the bright resonant mode of split ring resonators, but also reveal the capacitance change of the split ring resonators induced frequency shift of the Fano resonance. Therefore, the proposed theoretical model shows more capabilities than conventional coupled oscillator model in the design of Fano structures. The effective parameters of group refractive index of the Fano structure are retrieved, and a large group index more than 800 is obtained at the Fano resonance, which could be used for slow light devices. (C) 2014 Optical Society of America
Open Access
One-way reciprocal spoof surface plasmons and relevant reversible diodelike beaming
(American Physical Society, 2013-05-15) Mutlu, M.; Cakmakyapan, S.; Serebryannikov, A. E.; Özbay, Ekmel
One - way excitation of spoof surface plasmons (SPs) and strongly pronounced diodelike extraordinary transmission of linearly polarized waves in the beaming regime can be obtained by combining spoof SPs and cross-polarization conversion resonances. The reciprocal composite structure that is suggested to realize this mechanism consists of a symmetric metallic grating with a subwavelength slit and a metamaterial based ultrathin 90 degrees polarization rotator and, therefore, shows the broken spatial inversion symmetry. In contrast to the earlier studies of SP inspired transmission through subwavelength slits, asymmetric (one-way) beaming is demonstrated at normal incidence and for both s- and p-polarized incident waves. Furthermore, as an implication of Lorentz reciprocity, the studied diodelike mechanism is reversible, which manifests itself in that transmission is significant for one of the two opposite illumination directions at s polarization and for the other direction at p polarization. The obtained numerical and experimental results verify the general idea and enable us to select the optimal operation regimes.
Open Access
One-way transmission through the subwavelength slit in nonsymmetric metallic gratings
(Optical Society of America, 2010-07-27) Cakmakyapan, S.; Serebryannikov, A. E.; Caglayan, H.; Özbay, Ekmel
An approach for obtaining one-way transmission in the beaming regime is suggested that is based on the directional radiation of surface plasmons in nonsymmetric metallic gratings with a single slit. In contrast to the various nonsymmetric one-way diffraction gratings that have recently been proposed, the possibility of obtaining of narrow beams is demonstrated. Strong directional selectivity can appear a wide range of the observation angles, while the angle of incidence is retained.
Open Access
Rapid and sensitive colorimetric ELISA using silver nanoparticles, microwaves and split ring resonator structures
(2010) Addae, S.A.; Pinard, M.A.; Caglayan H.; Cakmakyapan, S.; Caliskan, D.; Özbay, Ekmel; Aslan, K.
We report a new approach to colorimetric Enzyme-Linked Immunosorbent Assay (ELISA) that reduces the total assay time to < 2 min and the lower-detection-limit by 100-fold based on absorbance readout. The new approach combines the use of silver nanoparticles, microwaves and split ring resonators (SRR). The SRR structure is comprised of a square frame of copper thin film (30 μm thick, 1 mm wide, overall length of ~9.4 mm on each side) with a single split on one side, which was deposited onto a circuit board (2×2 cm 2). A single micro-cuvette (10 μl volume capacity) was placed in the split of the SRR structures. Theoretical simulations predict that electric fields are focused in and above the micro-cuvette without the accumulation of electrical charge that breaks down the copper film. Subsequently, the walls and the bottom of the micro-cuvette were coated with silver nanoparticles using a modified Tollen's reaction scheme. The silver nanoparticles served as a mediator for the creation of thermal gradient between the bioassay medium and the silver surface, where the bioassay is constructed. Upon exposure to low power microwave heating, the bioassay medium in the micro-cuvette was rapidly and uniformly heated by the focused electric fields. In addition, the creation of thermal gradient resulted in the rapid assembly of the proteins on the surface of silver nanoparticles without denaturing the proteins. The proof-of-principle of the new approach to ELISA was demonstrated for the detection of a model protein (biotinylated-bovine serum albumin, b-BSA). In this regard, the detection of b-BSA with bulk concentrations (1 μM to 1 pM) was carried out on commercially available 96-well high throughput screening (HTS) plates and silver nanoparticle-deposited SRR structures at room temperature and with microwave heating, respectively. While the room temperature bioassay (without microwave heating) took 70 min to complete, the identical bioassay took < 2 min to complete using the SRR structures (with microwave heating). A lower detection limit of 0.01 nM for b-BSA (100-fold lower than room temperature ELISA) was observed using the SRR structures. © 2010 S.A. Addae et al.
Open Access
Resonance broadening and tuning of split ring resonators by top-gated epitaxial graphene on SiC substrate
(AIP Publishing LLC, 2013) Cakmakyapan, S.; Sahin, L.; Pierini, F.; Strupinski, W.; Özbay, Ekmel
Split ring resonators (SRRs) are subwavelength structures that are able to localize and enhance the electromagnetic wave. Controlling the plasmonic resonance behavior of metallic nanostructures, such as SRRs, plays an important role in optoelectronics and nanophotonics applications. Electrically tunable carrier concentration of graphene provides hybrid devices, where the plasmonic structures and graphene are combined. In this paper, we report the design, fabrication, and measurement of a device comprising a SRR array on epitaxial graphene. We obtained resonance broadening and tuning of split ring resonators by utilizing an epitaxial graphene transistor with transparent top-gate.
Open Access
Resonance tuning and broadening of bowtie nanoantennas on graphene
(Elsevier BV, 2014-04) Cakmakyapan, S.; Sahin, L.; Pierini, F.; Özbay, Ekmel
Metallic bowtie antennas are used in nanophotonics applications in order to confine the electromagnetic field into volumes much smaller than that of the incident wavelength. Electrically controllable carrier concentration of graphene opens the door to the use of plasmonic nanoantenna structures with graphene so that the resonant nature of nanoantennas can be tuned. In this study, we demonstrated with the Fourier transform infrared (FTIR) spectroscopy and the Finite Difference Time Domain (FDTD) method that the intensity and resonance peak of bowtie nanoantennas on monolayer graphene can be tuned at mid-infrared (MIR) wavelength regime by applying a gate voltage, since the optical properties of graphene change by changing the carrier concentration. (C) 2014 Elsevier B.V. All rights reserved.
Open Access
Step-edge-induced resistance anisotropy in quasi-free-standing bilayer chemical vapor deposition graphene on SiC
(AIP Publishing, 2014) Ciuk, T.; Cakmakyapan, S.; Özbay, Ekmel; Caban, P.; Grodecki, K.; Krajewska, A.; Pasternak, I.; Szmidt, J.; Strupinski, W.
The transport properties of quasi-free-standing (QFS) bilayer graphene on SiC depend on a range of scattering mechanisms. Most of them are isotropic in nature. However, the SiC substrate morphology marked by a distinctive pattern of the terraces gives rise to an anisotropy in graphene's sheet resistance, which may be considered an additional scattering mechanism. At a technological level, the growth-preceding in situ etching of the SiC surface promotes step bunching which results in macro steps similar to 10 nm in height. In this report, we study the qualitative and quantitative effects of SiC steps edges on the resistance of epitaxial graphene grown by chemical vapor deposition. We experimentally determine the value of step edge resistivity in hydrogen-intercalated QFS-bilayer graphene to be similar to 190 Omega mu m for step height h(S) = 10 nm and provide proof that it cannot originate from mechanical deformation of graphene but is likely to arise from lowered carrier concentration in the step area. Our results are confronted with the previously reported values of the step edge resistivity in monolayer graphene over SiC atomic steps. In our analysis, we focus on large-scale, statistical properties to foster the scalable technology of industrial graphene for electronics and sensor applications. (C) 2014 AIP Publishing LLC.
Open Access
Ultrafast and sensitive bioassay using split ring resonator structures and microwave heating
(American Institute of Physics, 2010-08-30) Caglayan, H.; Cakmakyapan, S.; Addae, S. A.; Pinard, M. A.; Caliskan, D.; Aslan, K.; Özbay, Ekmel
In this paper, we have reported that split ring resonators (SRRs) structures can be used for bioassay applications in order to further improve the assay time and sensitivity. The proof-of-principle demonstration of the ultrafast bioassays was accomplished by using a model biotin-avidin bioassay. While the identical room temperature bioassay (without microwave heating) took 70 min to complete, the identical bioassay took less than 2 min to complete by using SRR structures (with microwave heating). A lower detection limit of 0.01 nM for biotinylated-bovine serum albumin (100-fold lower than the room temperature bioassay) was observed by using SRR structures.
Open Access
Validation of electromagnetic field enhancement in near-infrared through Sierpinski fractal nanoantennas
(Optical Society of American (OSA), 2014) Cakmakyapan, S.; Cinel, N.A.; Cakmak, A.O.; Özbay, Ekmel
We introduced fractal geometry to the conventional bowtie antennas. We experimentally and numerically showed that the resonance of the bowtie antennas goes to longer wavelengths, after each fractalization step, which is considered a tool to miniaturize the main bowtie structure. We also showed that the fractal geometry provides multiple hot spots on the surface, and it can be used as an efficient SERS substrate. © 2014 Optical Society of America.
Open Access
Voltage contrast X-ray photoelectron spectroscopy reveals graphene-substrate interaction in graphene devices fabricated on the C-and Si-faces of SiC
(American Institute of Physics Inc., 2015) Aydogan, P.; Arslan, E.; Cakmakyapan, S.; Özbay, Ekmel; Strupinski, W.; Süzer, Şefik
We report on an X-ray photoelectron spectroscopy (XPS) study of two graphene based devices that were analyzed by imposing a significant current under +3 V bias. The devices were fabricated as graphene layers(s) on hexagonal SiC substrates, either on the C- or Si-terminated faces. Position dependent potential distributions (IR-drop), as measured by variations in the binding energy of a C1s peak are observed to be sporadic for the C-face graphene sample, but very smooth for the Si-face one, although the latter is less conductive. We attribute these sporadic variations in the C-face device to the incomplete electrical decoupling between the graphene layer(s) with the underlying buffer and/or substrate layers. Variations in the Si2p and O1s peaks of the underlayer(s) shed further light into the electrical interaction between graphene and other layers. Since the potential variations are amplified only under applied bias (voltage-contrast), our methodology gives unique, chemically specific electrical information that is difficult to obtain by other techniques.