Electrospinning of uniform nanofibers of polymers of intrinsic microporosity (PIM-1): the influence of solution conductivity and relative humidity

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buir.contributor.authorTopuz, Fuat
buir.contributor.authorSatılmış, Bekir
buir.contributor.authorUyar, Tamer
buir.contributor.orcidUyar, Tamer|0000-0002-3989-4481
dc.citation.spage121610en_US
dc.citation.volumeNumber178en_US
dc.contributor.authorTopuz, Fuaten_US
dc.contributor.authorSatılmış, Bekiren_US
dc.contributor.authorUyar, Tameren_US
dc.date.accessioned2020-02-06T10:57:18Z
dc.date.available2020-02-06T10:57:18Z
dc.date.issued2019
dc.departmentInstitute of Materials Science and Nanotechnology (UNAM)en_US
dc.description.abstractPolymers of Intrinsic Microporosity (PIMs) are ultra-permeable macromolecules, which can be cast as a dense membrane and exploited in a wide spectrum of applications, particularly for gas separation owing to their extremely large inner surface area, free volume and high gas permeability. While they are mostly intended to serve as membranes for gas separation, in recent years, they have been also employed in water treatment applications owing to their solution processability, which enables the production of fibrous membranes by electrospinning. The fibrous form provides an increase in sorption performance, water permeability and flux for their application in water treatment. However, owing to the low conductivity of PIM-1 solutions in 1,1,2,2-tetrachloroethane (TeCA) that is the ideal solvent for the electrospinning of PIM-1 solutions, a higher polymer concentration is required to produce bead-free fibers. Furthermore, the electrospinning of highly concentrated PIM-1 solutions leads to the formation of microfibers. To tackle these problems, we herein incorporated an ammonium salt (i.e., tetraethylammonium bromide, TEAB) to increase the conductivity of PIM-1 solutions and study the impact of solution conductivity on the electrospinning of PIM-1 solutions. In parallel to the conductivity study, the influence of relative humidity on the electrospinning and morphology of PIM-1 fibers was explored. The addition of TEAB significantly increased the solution conductivity and drastically enhanced the electrospinnability of PIM-1. The electrospinning of PIM-1 solutions (10% (w/v)) in the presence 7.5 wt% TEAB (with respect to PIM-1) led to bead-free fibers, while at the same concentration, electrosprayed beads and droplet splashing were observed in the absence of TEAB. On the other hand, increasing humidity did not influence the electrospinnability of PIM-1 and the fiber texture, however, less fibers were formed in a given time at very high humidity conditions (~80%). Overall, the experimental findings revealed that the addition of the salt drastically enhanced the electrospinnability of PIM-1 solutions owing to the enhanced conductivity and could lead to the formation of very thin PIM-1 fibers with 160 nm in diameter while no significant effect of relative humidity on the electrospinnability of PIM-1 solutions was observed.en_US
dc.embargo.release2021-09-12
dc.identifier.doi10.1016/j.polymer.2019.121610en_US
dc.identifier.issn0032-3861
dc.identifier.urihttp://hdl.handle.net/11693/53135
dc.language.isoEnglishen_US
dc.publisherElsevieren_US
dc.relation.isversionofhttps://doi.org/10.1016/j.polymer.2019.121610en_US
dc.source.titlePolymeren_US
dc.subjectPolymers of Intrinsic Microporosity (PIMs)en_US
dc.subjectElectrospinningen_US
dc.subjectFibersen_US
dc.subjectConductivityen_US
dc.subjectViscosityen_US
dc.titleElectrospinning of uniform nanofibers of polymers of intrinsic microporosity (PIM-1): the influence of solution conductivity and relative humidityen_US
dc.typeArticleen_US

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Institute of Materials Science and Nanotechnology (UNAM)