In situ preparation of thermoset/clay nanocomposites via thiol-epoxy click chemistry

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buir.contributor.authorUyar, Tamer
buir.contributor.orcidUyar, Tamer|0000-0002-3989-4481
dc.citation.epage4911en_US
dc.citation.issueNumber11en_US
dc.citation.spage4901en_US
dc.citation.volumeNumber75en_US
dc.contributor.authorPurut, Koc, O.en_US
dc.contributor.authorBekin, Acar, S.en_US
dc.contributor.authorUyar, Tameren_US
dc.contributor.authorTasdelen, M. A.en_US
dc.date.accessioned2019-02-21T16:05:58Zen_US
dc.date.available2019-02-21T16:05:58Zen_US
dc.date.issued2018en_US
dc.departmentInstitute of Materials Science and Nanotechnology (UNAM)en_US
dc.description.abstractA series of thermoset/clay nanocomposites are prepared by thiol-epoxy click reaction using commercially available starting compounds at ambient conditions in very good yields. The incorporation and exfoliation of clay nanolayers in the thermoset matrix are confirmed by FT-IR, XRD and TEM analyses. The influence of clay loadings on the thermal and mechanical analyses is investigated and all nanocomposites exhibit improved properties than that of the pristine thermoset. The nanocomposite containing 1% montmorillonite by weight has the most improved mechanical properties due to its highly exfoliated structure resulting in efficient interactions between clay and polymer matrix. A further increase of the clay loading results in the aggregation of clay plates to form intercalated structures leading to deteriorated thermal and mechanical properties of nanocomposites.en_US
dc.description.sponsorshipAcknowledgements The authors would like to thank Yalova University Research Fund (Project no: 2015/YL/055) for financial supports.en_US
dc.identifier.doi10.1007/s00289-018-2306-1en_US
dc.identifier.eissn1436-2449en_US
dc.identifier.issn0170-0839en_US
dc.identifier.urihttp://hdl.handle.net/11693/50284en_US
dc.language.isoEnglishen_US
dc.publisherSpringer Verlagen_US
dc.relation.isversionofhttps://doi.org/10.1007/s00289-018-2306-1en_US
dc.relation.project2015/YL/055en_US
dc.source.titlePolymer Bulletinen_US
dc.subjectClick chemistryen_US
dc.subjectNanoclayen_US
dc.subjectNanocompositesen_US
dc.subjectThermoseten_US
dc.subjectThiol-epoxy reactionen_US
dc.titleIn situ preparation of thermoset/clay nanocomposites via thiol-epoxy click chemistryen_US
dc.typeArticleen_US

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