A metal dicyanamide cluster with high CO2/N2 selectivity

Simple item page
dc.citation.epage157en_US
dc.citation.spage153en_US
dc.citation.volumeNumber228en_US
dc.contributor.authorTekin, A.en_US
dc.contributor.authorKaralti, O.en_US
dc.contributor.authorKaradas, F.en_US
dc.date.accessioned2018-04-12T10:54:17Z
dc.date.available2018-04-12T10:54:17Z
dc.date.issued2016en_US
dc.departmentDepartment of Chemistryen_US
dc.departmentInstitute of Materials Science and Nanotechnology (UNAM)en_US
dc.description.abstractA new microporous metal dicyanamide cluster, Co(hmt)(dca)2 (hmt: hexamethylenetetramine, dca: dicyanamide), with accessible N-donor sites exhibits high CO2/N2 selectivity, 83 at 295 K and 1 bar, for a mixture with a 15:85 CO2 to N2 ratio. Adsorption studies show that the use of hmt and dca moieties as building blocks for solid adsorbents can enhance the CO2:surface interactions due to N atoms available inside the pores, which is confirmed by X-ray single crystal studies.en_US
dc.identifier.doi10.1016/j.micromeso.2016.03.035en_US
dc.identifier.eissn1873-3093
dc.identifier.issn1387-1811
dc.identifier.urihttp://hdl.handle.net/11693/36810
dc.language.isoEnglishen_US
dc.publisherElsevier B.V.en_US
dc.relation.isversionofhttp://dx.doi.org/10.1016/j.micromeso.2016.03.035en_US
dc.source.titleMicroporous and Mesoporous Materialsen_US
dc.subjectAdsorptionen_US
dc.subjectCO2 adsorptionen_US
dc.subjectCO2/N2 selectivityen_US
dc.subjectCrystal structureen_US
dc.subjectDicyanamideen_US
dc.titleA metal dicyanamide cluster with high CO2/N2 selectivityen_US
dc.typeArticleen_US

Files

Original bundle
Now showing 1 - 1 of 1
Thumbnail Image
Name:
A metal dicyanamide cluster with high CO2N2 selectivity.pdf
Size:
1.41 MB
Format:
Adobe Portable Document Format
Description:
Full Printable Version
Download

Collections

Department of Chemistry
Institute of Materials Science and Nanotechnology (UNAM)