A metal dicyanamide cluster with high CO2/N2 selectivity
| dc.citation.epage | 157 | en_US |
| dc.citation.spage | 153 | en_US |
| dc.citation.volumeNumber | 228 | en_US |
| dc.contributor.author | Tekin, A. | en_US |
| dc.contributor.author | Karalti, O. | en_US |
| dc.contributor.author | Karadas, F. | en_US |
| dc.date.accessioned | 2018-04-12T10:54:17Z | |
| dc.date.available | 2018-04-12T10:54:17Z | |
| dc.date.issued | 2016 | en_US |
| dc.department | Department of Chemistry | en_US |
| dc.department | Institute of Materials Science and Nanotechnology (UNAM) | en_US |
| dc.description.abstract | A new microporous metal dicyanamide cluster, Co(hmt)(dca)2 (hmt: hexamethylenetetramine, dca: dicyanamide), with accessible N-donor sites exhibits high CO2/N2 selectivity, 83 at 295 K and 1 bar, for a mixture with a 15:85 CO2 to N2 ratio. Adsorption studies show that the use of hmt and dca moieties as building blocks for solid adsorbents can enhance the CO2:surface interactions due to N atoms available inside the pores, which is confirmed by X-ray single crystal studies. | en_US |
| dc.description.provenance | Made available in DSpace on 2018-04-12T10:54:17Z (GMT). No. of bitstreams: 1 bilkent-research-paper.pdf: 179475 bytes, checksum: ea0bedeb05ac9ccfb983c327e155f0c2 (MD5) Previous issue date: 2016 | en |
| dc.identifier.doi | 10.1016/j.micromeso.2016.03.035 | en_US |
| dc.identifier.eissn | 1873-3093 | |
| dc.identifier.issn | 1387-1811 | |
| dc.identifier.uri | http://hdl.handle.net/11693/36810 | |
| dc.language.iso | English | en_US |
| dc.publisher | Elsevier B.V. | en_US |
| dc.relation.isversionof | http://dx.doi.org/10.1016/j.micromeso.2016.03.035 | en_US |
| dc.source.title | Microporous and Mesoporous Materials | en_US |
| dc.subject | Adsorption | en_US |
| dc.subject | CO2 adsorption | en_US |
| dc.subject | CO2/N2 selectivity | en_US |
| dc.subject | Crystal structure | en_US |
| dc.subject | Dicyanamide | en_US |
| dc.title | A metal dicyanamide cluster with high CO2/N2 selectivity | en_US |
| dc.type | Article | en_US |
Files
Original bundle
1 - 1 of 1
Loading...
- Name:
- A metal dicyanamide cluster with high CO2N2 selectivity.pdf
- Size:
- 1.41 MB
- Format:
- Adobe Portable Document Format
- Description:
- Full Printable Version