Rational design and synthesis of bodipy dyes for molecular sensing, light harvesting and photodynamic applications

buir.advisorAkkaya, Engin U.
dc.contributor.authorKütük, Tuğba Özdemir
dc.date.accessioned2016-01-08T20:20:50Z
dc.date.available2016-01-08T20:20:50Z
dc.date.issued2014
dc.descriptionAnkara : The Materials Science and Nanotechnology Program of the Graduate School of Engineering and Science of Bilkent University, 2014.en_US
dc.descriptionThesis (Ph.D.) -- Bilkent University, 2014.en_US
dc.descriptionIncludes bibliographical references leaves 172-192.en_US
dc.description.abstractBODIPY dyes have been addressed in many applications due to highly important features. These unique properties can be summarized as high photostability, high extinction coefficient, easy functionality, etc. Thus, tremendous studies have been published and, ion sensing, photodynamic therapy, dye-sensitized solar cells and light harvesting are some of the areas that BODIPY dyes have been utilized. In this thesis, BODIPY dyes were functionalized to be used for different concepts. In the first study, the main purpose was to seek for ion signaling differences of two isomeric tetra-styryl BODIPY dyes with charge donor ligand located at 1,7 versus 3,5 positions. Second work focuses on the light harvesting concept with the use of tetra-styryl BODIPY derivatives. Third study describes the coupling of energy transfer with internal charge transfer to monitor the alterations in intensity ratios, so, dynamic range of the fluorescent probe is improved. Design and synthesis of BODIPY dyes for detection of biological thiols in aqueous solution both chromogenically and fluorogenically was given in fourth study. Another biologically important molecule, hydrogen sulfide is selectively detected via BODIPY-based probe and depicted in the fifth study. In the sixth work, persistent luminescent nanoparticles are attached to BODIPY-based photosensitizer to activate the photodynamic action.en_US
dc.description.provenanceMade available in DSpace on 2016-01-08T20:20:50Z (GMT). No. of bitstreams: 1 1.pdf: 78510 bytes, checksum: d85492f20c2362aa2bcf4aad49380397 (MD5)en
dc.description.statementofresponsibilityKütük, Tuğba Özdemiren_US
dc.embargo.release2016-10-21
dc.format.extentxxiii, 243 leaves, illustrations, chartsen_US
dc.identifier.urihttp://hdl.handle.net/11693/18608
dc.language.isoEnglishen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subjection sensingen_US
dc.subjectexcitation energy transferen_US
dc.subjectlight harvestingen_US
dc.subjectbiological thiolsen_US
dc.subjecthydrogen sulfideen_US
dc.subjectphotodynamic therapyen_US
dc.subjectBODIPYen_US
dc.subject.lccQK882 .K88 2014en_US
dc.subject.lcshThiols.en_US
dc.subject.lcshSenses and sensation.en_US
dc.subject.lcshPhotosynthesis.en_US
dc.subject.lcshEnergy transfer.en_US
dc.titleRational design and synthesis of bodipy dyes for molecular sensing, light harvesting and photodynamic applicationsen_US
dc.typeThesisen_US
thesis.degree.disciplineMaterials Science and Nanotechnology
thesis.degree.grantorBilkent University
thesis.degree.levelDoctoral
thesis.degree.namePh.D. (Doctor of Philosophy)

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