Near-IR-triggered, remote-controlled release of metal ions: A novel strategy for caged ions

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dc.citation.epage10681en_US
dc.citation.issueNumber40en_US
dc.citation.spage10678en_US
dc.citation.volumeNumber53en_US
dc.contributor.authorAtilgan, A.en_US
dc.contributor.authorEçik, E. T.en_US
dc.contributor.authorGuliyev, R.en_US
dc.contributor.authorUyar, T. B.en_US
dc.contributor.authorErbas-Cakmak, S.en_US
dc.contributor.authorAkkaya, E. U.en_US
dc.date.accessioned2016-02-08T10:43:05Z
dc.date.available2016-02-08T10:43:05Z
dc.date.issued2014en_US
dc.departmentDepartment of Chemistryen_US
dc.description.abstractA ligand incorporating a dithioethenyl moiety is cleaved into fragments which have a lower metal-ion affinity upon irradiation with low-energy red/near-IR light. The cleavage is a result of singlet oxygen generation which occurs on excitation of the photosensitizer modules. The method has many tunable factors that could make it a satisfactory caging strategy for metal ions.en_US
dc.description.provenanceMade available in DSpace on 2016-02-08T10:43:05Z (GMT). No. of bitstreams: 1 bilkent-research-paper.pdf: 70227 bytes, checksum: 26e812c6f5156f83f0e77b261a471b5a (MD5) Previous issue date: 2014en
dc.identifier.doi10.1002/anie.201405462en_US
dc.identifier.eissn1521-3773
dc.identifier.issn1433-7851
dc.identifier.urihttp://hdl.handle.net/11693/25336
dc.language.isoEnglishen_US
dc.publisherWiley-VCH Verlagen_US
dc.relation.isversionofhttp://dx.doi.org/10.1002/anie.201405462en_US
dc.source.titleAngewandte Chemie (International Edition)en_US
dc.subjectGas generatorsen_US
dc.subjectIrradiationen_US
dc.subjectLigandsen_US
dc.subjectMetalsen_US
dc.subjectOxygenen_US
dc.subjectPhotochemical reactionsen_US
dc.subjectPhotosensitizersen_US
dc.subjectRemote controlen_US
dc.subjectZincen_US
dc.subjectCaged compoundsen_US
dc.subjectMetal ion affinitiesen_US
dc.subjectNear-IRen_US
dc.subjectNovel strategiesen_US
dc.subjectOn demandsen_US
dc.subjectRemote controlled releaseen_US
dc.subjectSinglet oxygenen_US
dc.subjectSinglet oxygen generationen_US
dc.subjectMetal ionsen_US
dc.titleNear-IR-triggered, remote-controlled release of metal ions: A novel strategy for caged ionsen_US
dc.typeArticleen_US

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