Near-IR-triggered, remote-controlled release of metal ions: A novel strategy for caged ions

Date

2014

Authors

Atilgan, A.
Eçik, E. T.
Guliyev, R.
Uyar, T. B.
Erbas-Cakmak, S.
Akkaya, E. U.

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Abstract

A ligand incorporating a dithioethenyl moiety is cleaved into fragments which have a lower metal-ion affinity upon irradiation with low-energy red/near-IR light. The cleavage is a result of singlet oxygen generation which occurs on excitation of the photosensitizer modules. The method has many tunable factors that could make it a satisfactory caging strategy for metal ions.

Source Title

Angewandte Chemie (International Edition)

Publisher

Wiley-VCH Verlag

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Citation

Published Version (Please cite this version)

Language

English