In situ synthesis of polymer / clay nanocomposites by type II photoinitiated free radical polymerization

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10.1002-pola.26957.pdf (647.43 KB)

Date

2011-08-15

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Source Title

Journal of Polymer Science Part A: Polymer Chemistry

Print ISSN

0887-624X

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Publisher

Wiley

Volume

51

Issue

16

Pages

5257 - 5262

Language

English

Type

Article

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Abstract

A new synthetic route for the preparation of poly(methyl methacrylate)/montmorillonite (PMMA/MMT) nanocomposites was reported. In this method, first 4-(dimethylamino)benzoate group was incorporated into silicate layers of clay by esterification reaction and used to produce PMMA/MMT nanocomposites by in situ Type II photoinitiated free radical polymerization. In situ photopolymerization of methyl methacrylate through into the silicate layers by either visible or UV light irradiation leads to PMMA/MMT nanocomposites. Copyright © 2011 Wiley Periodicals, Inc.

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Keywords

Montmorillonite, Polymer / clay nanocomposite, Poly (methyl methacrylate), Radical polymerization, Type II photopolymerization, visible light initiation

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http://hdl.handle.net/11693/12333

Published Version (Please cite this version)

http://dx.doi.org/10.1002/pola.24788

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Scholarly Publications - UNAM