Type-II colloidal quantum wells: CdSe/CdTe core/crown heteronanoplatelets

Date
2015
Advisor
Instructor
Source Title
Journal of Physical Chemistry C
Print ISSN
1932-7447
Electronic ISSN
Publisher
American Chemical Society
Volume
119
Issue
4
Pages
2177 - 2185
Language
English
Type
Article
Journal Title
Journal ISSN
Volume Title
Abstract

Solution-processed quantum wells, also known as colloidal nanoplatelets (NPLs), are emerging as promising materials for colloidal optoelectronics. In this work, we report the synthesis and characterization of CdSe/CdTe core/crown NPLs exhibiting a Type-II electronic structure and Type-II speci fic optical properties. Here, based on a core-seeded approach, the CdSe/CdTe core/crown NPLs were synthesized with well-controlled CdTe crown coatings. Uniform and epitaxial growth of CdTe crown region was verified by using structural characterization techniques including transmission electron microscopy (TEM) with quantitative EDX analysis and X-ray diffraction (XRD). Also the optical properties were systematically studied in these Type-II NPLs that reveal strongly red-shifted photoluminescence (up to ∼150 nm) along with 2 orders of magnitude longer fluorescence lifetimes (up to 190 ns) compared to the Type-I NPLs owing to spatially indirect excitons at the Type-II interface between the CdSe core and the CdTe crown regions. Photoluminescence excitation spectroscopy confirms that this strongly red-shifted emission actually arises from the CdSe/CdTe NPLs. In addition, temperature-dependent time-resolved fluorescence spectroscopy was performed to reveal the temperature-dependent fluorescence decay kinetics of the Type-II NPLs exhibiting interesting behavior. Also, water-soluble Type-II NPLs were achieved via ligand exchange of the CdSe/CdTe core/crown NPLs by using 3-mercaptopropionic acid (MPA), which allows for enhanced charge extraction efficiency owing to their shorter chain length and enables high quality film formation by layer-by-layer (LBL) assembly. With all of these appealing properties, the CdSe/CdTe core/crown heterostructures having Type-II electronic structure presented here are highly promising for light-harvesting applications. (Graph Presented). © 2015 American Chemical Society.

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Keywords
Cadmium telluride, Electronic structure, Fluorescence, Fluorescence spectroscopy, Optical properties, Photoluminescence, Transmission electron microscopy, X ray diffraction, 3 - mercaptopropionic acid, Colloidal quantum wells, Layer - by - layer assemblies, Photoluminescence excitation spectroscopy, Structural characterization, Synthesis and characterizations, Temperature dependent fluorescence, Time - resolved fluorescence spectroscopy, Semiconductor quantum wells
Citation
Published Version (Please cite this version)