Synthesis of the bioactive fungal natural product daldiquinone

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buir.contributor.authorTürkmen, Yunus Emre
buir.contributor.orcidTürkmen, Yunus Emre|0000-0002-9797-2820
dc.citation.epage153877- 3en_US
dc.citation.spage153877- 1en_US
dc.citation.volumeNumber100en_US
dc.contributor.authorAhmadli, D.
dc.date.accessioned2023-02-16T10:28:58Z
dc.date.available2023-02-16T10:28:58Z
dc.date.issued2022-05-19
dc.departmentInstitute of Materials Science and Nanotechnology (UNAM)en_US
dc.description.abstractWe report the first total synthesis of the biologically active fungal natural product daldiquinone (5), which was accomplished with a longest linear sequence of 8 steps in 41% overall yield. The construction of the unsymmetrical binaphthalene core was realized by a Suzuki-Miyaura cross-coupling in 88% yield on gram scale. Oxidation of naphthol 17 with IBX afforded the key naphthoquinone intermediate 18 in high yield (92%).en_US
dc.description.provenanceSubmitted by Ezgi Uğurlu (ezgi.ugurlu@bilkent.edu.tr) on 2023-02-16T10:28:58Z No. of bitstreams: 1 Synthesis_of_the_bioactive_fungal_natural_product_daldiquinone.pdf: 537314 bytes, checksum: 4bca78279cca9bab01fa4e420cba1d9b (MD5)en
dc.description.provenanceMade available in DSpace on 2023-02-16T10:28:58Z (GMT). No. of bitstreams: 1 Synthesis_of_the_bioactive_fungal_natural_product_daldiquinone.pdf: 537314 bytes, checksum: 4bca78279cca9bab01fa4e420cba1d9b (MD5) Previous issue date: 2022-05-19en
dc.embargo.release2024-05-19
dc.identifier.doi10.1016/j.tetlet.2022.153877en_US
dc.identifier.eissn1873-3581
dc.identifier.issn0040-4039
dc.identifier.urihttp://hdl.handle.net/11693/111427
dc.language.isoEnglishen_US
dc.publisherElsevier Ltden_US
dc.relation.isversionofhttps://doi.org/10.1016/j.tetlet.2022.153877en_US
dc.source.titleTetrahedron Lettersen_US
dc.subjectDaldiquinoneen_US
dc.subjectNaphthoquinonesen_US
dc.subjectNatural productsen_US
dc.subjectSuzuki-Miyaura couplingen_US
dc.subjectTotal synthesisen_US
dc.titleSynthesis of the bioactive fungal natural product daldiquinoneen_US
dc.typeArticleen_US

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