Highly selective surface adsorption-induced efficient photodegradation of cationic dyes on hierarchical ZnO nanorod-decorated hydrolyzed PIM-1 nanofibrous webs

buir.contributor.authorRanjith, Kugalur Shanmugam
buir.contributor.authorSatılmış, Bekir
buir.contributor.authorUyar, Tamer
buir.contributor.orcidUyar, Tamer|0000-0002-3989-4481
dc.citation.epage41en_US
dc.citation.spage29en_US
dc.citation.volumeNumber562en_US
dc.contributor.authorRanjith, Kugalur Shanmugam
dc.contributor.authorSatılmış, Bekir
dc.contributor.authorHuh, Y. S.
dc.contributor.authorHan, Y. -K.
dc.contributor.authorUyar, Tamer
dc.date.accessioned2021-02-24T11:54:28Z
dc.date.available2021-02-24T11:54:28Z
dc.date.issued2020
dc.departmentInstitute of Materials Science and Nanotechnology (UNAM)en_US
dc.description.abstractSelectivity of catalysts toward harmful cationic pollutants in industrial wastewater remains challenging but is of crucial importance in environmental remediation processes. Here, we present a complex network of a hydrolyzed polymer of intrinsic microporosity (HPIM)-based electrospun nanofibrous web with surface functional decoration of ZnO nanorods (NRs) as a hierarchical platform for selective and rapid degradation of cationic dyes. Over a single species or binary mixtures, cationic dyes were selectively adsorbed by the HPIM surface, which then rapidly degraded under simultaneous photoirradiation through the ZnO NRs. Both HPIM and ZnO exhibited high electronegative surfaces, which induced the selectivity towards the cationic dyes and rapidly degraded the pollutants with the production of reactive oxygen species under photoirradiation. Further, as a free-standing web, the catalytic network could be easily separated and reused without any significant loss of catalytic activity after multiple cycles of use. The hierarchical platform of ZnO/HPIM-based heterostructures could be a promising catalytic template for selective degradation of synthetic dyes in mixed wastewater samples.en_US
dc.description.provenanceSubmitted by Onur Emek (onur.emek@bilkent.edu.tr) on 2021-02-24T11:54:28Z No. of bitstreams: 1 Highly_selective_surface_adsorption-induced_efficient_photodegradation_of_cationic_dyes_on_hierarchical_ZnO_nanorod-decorated_hydrolyzed_PIM-1_nanofibrous_webs.pdf: 3796472 bytes, checksum: b4995cb7036e18ba5e8decad979225d5 (MD5)en
dc.description.provenanceMade available in DSpace on 2021-02-24T11:54:28Z (GMT). No. of bitstreams: 1 Highly_selective_surface_adsorption-induced_efficient_photodegradation_of_cationic_dyes_on_hierarchical_ZnO_nanorod-decorated_hydrolyzed_PIM-1_nanofibrous_webs.pdf: 3796472 bytes, checksum: b4995cb7036e18ba5e8decad979225d5 (MD5) Previous issue date: 2020en
dc.embargo.release2022-03-07
dc.identifier.doi10.1016/j.jcis.2019.11.096en_US
dc.identifier.issn0021-9797
dc.identifier.urihttp://hdl.handle.net/11693/75558
dc.language.isoEnglishen_US
dc.publisherElsevieren_US
dc.relation.isversionofhttps://dx.doi.org/10.1016/j.jcis.2019.11.096en_US
dc.source.titleJournal of Colloid and Interface Scienceen_US
dc.subjectElectrospinningen_US
dc.subjectPolymers of intrinsic microporosity (PIMs)en_US
dc.subjectHPIM-ZnO nanofibersen_US
dc.subjectHierarchical fibrous weben_US
dc.subjectCationic dye adsorptionen_US
dc.subjectPhotodegradationen_US
dc.titleHighly selective surface adsorption-induced efficient photodegradation of cationic dyes on hierarchical ZnO nanorod-decorated hydrolyzed PIM-1 nanofibrous websen_US
dc.typeArticleen_US

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