Chemiluminescence sensing of fluoride ions using a self-immolative amplifier
| dc.citation.epage | 1683 | en_US |
| dc.citation.issueNumber | 6 | en_US |
| dc.citation.spage | 1680 | en_US |
| dc.citation.volumeNumber | 16 | en_US |
| dc.contributor.author | Turan, I. S. | en_US |
| dc.contributor.author | Akkaya, E. U. | en_US |
| dc.date.accessioned | 2016-02-08T10:57:57Z | |
| dc.date.available | 2016-02-08T10:57:57Z | |
| dc.date.issued | 2014 | en_US |
| dc.department | Department of Chemistry | en_US |
| dc.department | Institute of Materials Science and Nanotechnology (UNAM) | en_US |
| dc.description.abstract | An enhanced chemiluminescence signal is obtained when electronically triggered dioxetane cleavage is initiated by fluoride-mediated deprotection of the silyl-protecting group, followed by self-immolation via 1,4-quinone−methide rearrangement. The reaction takes place even when the probe is trapped within a PMMA layer on top of a glass plate. In that arrangement, fluoride in aqueous solutions can be detected selectively at low micromolar concentrations. | en_US |
| dc.identifier.doi | 10.1021/ol5003412 | en_US |
| dc.identifier.eissn | 1523-7052 | |
| dc.identifier.issn | 1523-7060 | |
| dc.identifier.uri | http://hdl.handle.net/11693/26300 | |
| dc.language.iso | English | en_US |
| dc.publisher | American Chemical Society | en_US |
| dc.relation.isversionof | http://dx.doi.org/10.1021/ol5003412 | en_US |
| dc.source.title | Organic Letters | en_US |
| dc.title | Chemiluminescence sensing of fluoride ions using a self-immolative amplifier | en_US |
| dc.type | Article | en_US |
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