Cyclodextrin-grafted electrospun cellulose acetate nanofibers via "Click" reaction for removal of phenanthrene

Abstract

Beta-cyclodextrin (p-CD) functionalized cellulose acetate (CA) nanofibers have been successfully prepared by combining electrospinning and "click" reaction. Initially, p-CD and electrospun CA nanofibers were modified so as to be azide-p-CD and propargyl-terminated CA nanofibers, respectively. Then, "click" reaction was performed between modified CD molecules and CA nanofibers to obtain permanent grafting of CDs onto nanofibers surface. It was observed from the SEM image that, while CA nanofibers have smooth surface, there were some irregularities and roughness at nanofibers morphology after the modification. Yet, the fibrous structure was still protected. ATR-FTIR and XPS revealed that, CD molecules were successfully grafted onto surface of CA nanofibers. The adsorption capacity of p-CD-functionalized CA (CA-CD) nanofibers was also determined by removing phenanthrene (polycyclic aromatic hydrocarbons, PAH) from its aqueous solution. Our results indicate that CA-CD nanofibers have potential to be used as molecular filters for the purpose of water purification and waste water treatment by integrating the high surface area of nanofibers with inclusion complexation property of CD molecules.