Poly(epsilon caprolactone)/clay nanocomposites via host-guest chemistry

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buir.contributor.authorUyar, Tamer
buir.contributor.orcidUyar, Tamer|0000-0002-3989-4481
dc.citation.epage267en_US
dc.citation.spage259en_US
dc.citation.volumeNumber71en_US
dc.contributor.authorArslan, M.en_US
dc.contributor.authorTasdelen, M. A.en_US
dc.contributor.authorUyar, Tameren_US
dc.contributor.authorYagci, Y.en_US
dc.date.accessioned2016-02-08T09:43:58Z
dc.date.available2016-02-08T09:43:58Z
dc.date.issued2015en_US
dc.departmentInstitute of Materials Science and Nanotechnology (UNAM)en_US
dc.description.abstractCyclodextrin-modified montmorillonite (MMT-CD) has been prepared from commercial montmorillonite clay (Closite 30B) containing two hydroxyl groups by reacting succinic anhydride through esterification. Poly(epsilon caprolactone) (PCL)/clay nanocomposites are prepared by host-guest chemistry between MMT-CD as host and PCL, hydrophobic polymer as guest. The structures of the intermediates and final nanocomposite are investigated in detail by FT-IR XRD, TEM, DSC and TGA measurements. The intercalated/exfoliated morphologies are determined by combined XRD and TEM analyses. Thermal stabilities of all nanocomposites are improved by the addition of MMT-CD compared to the neat polymer. The DSC data confirm that the crystallinity of PCL is slightly increased by increasing clay loading. © 2015 Elsevier Ltd. All rights reserved.en_US
dc.identifier.doi10.1016/j.eurpolymj.2015.08.006en_US
dc.identifier.issn0014-3057
dc.identifier.urihttp://hdl.handle.net/11693/21270
dc.language.isoEnglishen_US
dc.publisherElsevier Ltden_US
dc.relation.isversionofhttp://dx.doi.org/10.1016/j.eurpolymj.2015.08.006en_US
dc.source.titleEuropean Polymer Journalen_US
dc.subjectCyclodextrinen_US
dc.subjectHost-guest chemistryen_US
dc.subjectNanocompositesen_US
dc.subjectOrganoclayen_US
dc.subjectRing-opening polymerizationen_US
dc.subjectSelf-assemblyen_US
dc.subjectClay mineralsen_US
dc.subjectCyclodextrinsen_US
dc.subjectIntercalationen_US
dc.titlePoly(epsilon caprolactone)/clay nanocomposites via host-guest chemistryen_US
dc.typeArticleen_US

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