Reaction-based sensing of fluoride ions using built-in triggers for intramolecular charge transfer and photoinduced electron transfer

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dc.citation.epage1403en_US
dc.citation.issueNumber7en_US
dc.citation.spage1400en_US
dc.citation.volumeNumber12en_US
dc.contributor.authorBozdemir, O. A.en_US
dc.contributor.authorSozmen, F.en_US
dc.contributor.authorBuyukcakir, O.en_US
dc.contributor.authorGuliyev, R.en_US
dc.contributor.authorCakmak, Y.en_US
dc.contributor.authorAkkaya, E. U.en_US
dc.date.accessioned2016-02-08T09:59:05Z
dc.date.available2016-02-08T09:59:05Z
dc.date.issued2010en_US
dc.departmentInstitute of Materials Science and Nanotechnology (UNAM)en_US
dc.departmentDepartment of Chemistryen_US
dc.description.abstractTwo Bodipy derivatives with silyl-protected phenolic functionalities signal fluoride concentrations both In solution and in a poly(methyl methacrylate) matrix. The exact location of the "nascent" phenolate group is Important. If it Is at the meso position, photoinduced electron transfer is triggered; however, if It is In full conjugation via a styryl moiety to the Bodipy core, strong intramolecular charge transfer Is triggered, resulting In a large red shift in the absorbance peak. In either case, a selective methodology for fluoride sensing is the Invariable result.en_US
dc.identifier.doi10.1021/ol100172wen_US
dc.identifier.eissn1523-7052
dc.identifier.issn1523-7060
dc.identifier.urihttp://hdl.handle.net/11693/22360
dc.language.isoEnglishen_US
dc.publisherAmerican Chemical Societyen_US
dc.relation.isversionofhttp://dx.doi.org/10.1021/ol100172wen_US
dc.source.titleOrganic Lettersen_US
dc.subjectFluoridesen_US
dc.subjectIonsen_US
dc.subjectPrecipitating factorsen_US
dc.subjectRespiratory electron transport chain processen_US
dc.subjectPolymethyl methacrylateen_US
dc.subjectPhenolicsen_US
dc.subjectPhenolateen_US
dc.subjectMethacrylatesen_US
dc.titleReaction-based sensing of fluoride ions using built-in triggers for intramolecular charge transfer and photoinduced electron transferen_US
dc.typeArticleen_US

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Institute of Materials Science and Nanotechnology (UNAM)
Department of Chemistry