Autonomous shuttling driven by an oscillating reaction: proof of principle in a cucurbit [7] uril-Bodipy pseudorotaxane

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dc.citation.epage1015en_US
dc.citation.issueNumber5en_US
dc.citation.spage1012en_US
dc.citation.volumeNumber15en_US
dc.contributor.authorBuyukcakir, O.en_US
dc.contributor.authorYasar, F. T.en_US
dc.contributor.authorBozdemir, O. A.en_US
dc.contributor.authorIcli, B.en_US
dc.contributor.authorAkkaya, E. U.en_US
dc.date.accessioned2016-02-08T09:40:07Z
dc.date.available2016-02-08T09:40:07Z
dc.date.issued2013en_US
dc.departmentInstitute of Materials Science and Nanotechnology (UNAM)en_US
dc.departmentDepartment of Chemistryen_US
dc.description.abstractA bipyridinium dication-substituted Bodipy fluorophore, with a terminal carboxylic acid function, provides two alternative stations for cucurbit[7]uril. Changing pH from basic to acidic results in shuttling of the cucurbit[7]uril from one station to another. In addition, this shuttling is accompanied by a change in the emissive properties of the Bodipy dye, which is only observed in the presence of cucurbit[7]uril. More striking, is a demonstration of autonomous shuttling of the pseudorotaxane system in an oscillating pH system.en_US
dc.description.provenanceMade available in DSpace on 2016-02-08T09:40:07Z (GMT). No. of bitstreams: 1 bilkent-research-paper.pdf: 70227 bytes, checksum: 26e812c6f5156f83f0e77b261a471b5a (MD5) Previous issue date: 2013en
dc.identifier.doi10.1021/ol303495nen_US
dc.identifier.eissn1523-7052
dc.identifier.issn1523-7060
dc.identifier.urihttp://hdl.handle.net/11693/21040
dc.language.isoEnglishen_US
dc.publisherAmerican Chemical Societyen_US
dc.relation.isversionofhttp://dx.doi.org/10.1021/ol303495nen_US
dc.source.titleOrganic Lettersen_US
dc.titleAutonomous shuttling driven by an oscillating reaction: proof of principle in a cucurbit [7] uril-Bodipy pseudorotaxaneen_US
dc.typeArticleen_US

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Institute of Materials Science and Nanotechnology (UNAM)
Department of Chemistry