Autonomous shuttling driven by an oscillating reaction: proof of principle in a cucurbit [7] uril-Bodipy pseudorotaxane
dc.citation.epage | 1015 | en_US |
dc.citation.issueNumber | 5 | en_US |
dc.citation.spage | 1012 | en_US |
dc.citation.volumeNumber | 15 | en_US |
dc.contributor.author | Buyukcakir, O. | en_US |
dc.contributor.author | Yasar, F. T. | en_US |
dc.contributor.author | Bozdemir, O. A. | en_US |
dc.contributor.author | Icli, B. | en_US |
dc.contributor.author | Akkaya, E. U. | en_US |
dc.date.accessioned | 2016-02-08T09:40:07Z | |
dc.date.available | 2016-02-08T09:40:07Z | |
dc.date.issued | 2013 | en_US |
dc.department | Institute of Materials Science and Nanotechnology (UNAM) | en_US |
dc.department | Department of Chemistry | en_US |
dc.description.abstract | A bipyridinium dication-substituted Bodipy fluorophore, with a terminal carboxylic acid function, provides two alternative stations for cucurbit[7]uril. Changing pH from basic to acidic results in shuttling of the cucurbit[7]uril from one station to another. In addition, this shuttling is accompanied by a change in the emissive properties of the Bodipy dye, which is only observed in the presence of cucurbit[7]uril. More striking, is a demonstration of autonomous shuttling of the pseudorotaxane system in an oscillating pH system. | en_US |
dc.description.provenance | Made available in DSpace on 2016-02-08T09:40:07Z (GMT). No. of bitstreams: 1 bilkent-research-paper.pdf: 70227 bytes, checksum: 26e812c6f5156f83f0e77b261a471b5a (MD5) Previous issue date: 2013 | en |
dc.identifier.doi | 10.1021/ol303495n | en_US |
dc.identifier.eissn | 1523-7052 | |
dc.identifier.issn | 1523-7060 | |
dc.identifier.uri | http://hdl.handle.net/11693/21040 | |
dc.language.iso | English | en_US |
dc.publisher | American Chemical Society | en_US |
dc.relation.isversionof | http://dx.doi.org/10.1021/ol303495n | en_US |
dc.source.title | Organic Letters | en_US |
dc.title | Autonomous shuttling driven by an oscillating reaction: proof of principle in a cucurbit [7] uril-Bodipy pseudorotaxane | en_US |
dc.type | Article | en_US |
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