Browsing by Subject "Oligothiophenes"

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Open Access
Construction of light emitting nanostructures through self-assembly of oligothiophene-based macromolecules for biomedical applications
(2016-08) Al Bahra, Obadah
This work discusses the synthesis and characterizations of oligothiophene-based macromolecules and the construction of nanostructures through self-assembly of these macromolecules in water. In order to prepare the macromolecules, first bi-functional oligothiophenes are synthesized, characterized and then, the properly functionalized polyethylene glycol is linked to oligothiophene through nucleophilic substitution reactions to obtain an amphiphilic macromolecule. Self-assembly of amphiphilic macromolecules in water are investigated; the size and the morphology of the resulting nanostructures are determined by various techniques including dynamic light scattering, SEM and TEM. Their optical properties are studied using UV-vis and fluorescent spectroscopies. Polyethylene oxide has been considered highly biocompatible and biodegradable material which make it candidate for the biological applications as carrier for bioactive materials and controlled releasing of the drugs.
Open Access
Nature of charge carriers in long doped oligothiophenes: the effect of counterions
(2008) Zamoshchik, N.; Salzner, U.; Bendikov, M.
A series of oligothiophene dications doped with Cl3 - ions were studied using density functional theory (DFT) at the B3LYP/6-31G(d) level. The balance between the bipolaron and polaron pair states was addressed by studying the closed-shell singlet, open-shell singlet, and triplet states of oligothiophene divalent salts using the relative energies of the different isomers, differences between the singlet and triplet states, bond length alternation analysis, charge distribution analysis, and isodesmic reactions. We found that contribution of polaron pair state to the electronic structure of the oligothiophene divalent salts is not observed in 8T2+(Cl3́ -)2 (short oligothiophene salts), appears in 12T 2+(Cl3 -)2 (medium-sized oligothiophene salts), and becomes the dominant in 20T2+(Cl 3 -)2 (long oligothiophene salts). Bipolarons are intrinsically unstable with respect to dissociation into polaron pairs regardless of the presence of counterions. Thus, even in the presence of counterions, we did not observe any bipolaron stabilization energy, however, doping ions localize polarons. The singlet and triplet states are energetically degenerate for long oligothiophene divalent salts, such as 20T 2+(Cl3 -)2. © 2008 American Chemical Society.