Browsing by Subject "Mixtures"

Now showing 1 - 15 of 15

Open Access
AC-modulated XPS enables to externally control the electrical field distributions on metal electrode/Ionic Liquid devices
(American Chemical Society, 2024-04-20) Kutbay, Ezgi; İnce, Süleyman; Süzer, Şefik
X-Ray Photoelectron Spectroscopy (XPS) has been utilized to extract local electrical potential profiles by recording core-level binding energy shifts upon application of the AC [square-wave (SQW)] bias with different frequencies. An electrochemical system consisting of a coplanar capacitor with a polyethylene membrane (PEM) coated with the Ionic Liquid (IL) N,N-diethyl-N-methyl-N-(2-methoxyethyl) ammonium bis(trifluoromethanesulfonyl)imide (DEME-TFSI) as the electrolyte is investigated. Analyses are carried out in operando, such that XPS measurements are recorded simultaneously with current measurements. ILs have complex charging/discharging processes, in addition to the formation of Electrical Double Layers (EDL) at the interfaces, and certain properties of these processes can be captured using AC modulation within appropriate time windows of observation. Herein, we select two frequencies, namely, 10 kHz and 0.1 Hz, to separate effects of the fast polarization and slow migratory motions, respectively. Moreover, the local potential developments after adding two equivalent series resistors at three different physical positions of the device have been carefully evaluated from the binding energy shifts in the F 1s peak representing the anion of the IL. This circuit modification allows us to quantify the AC currents passing through the device, as well as the system's impedance, in addition to revealing the potential variations due the IR drops. The complex AC-modulated local XPS data recorded can also be faithfully reproduced using the unmodulated F 1s spectrum and by convoluting it with electrical circuit output provided by the LT-Spice software. The outcome of these efforts is a more realistic equivalent circuit model, which can be related to chemical/physical makeup of the electrochemical system. An important finding of this methodology emerges as the possibility to induce additional local electrical field developments within the device, the directions of which can be reversed controllably.
Open Access
Adaptive mixture methods based on Bregman divergences
(Elsevier, 2013) Donmez, M. A.; Inan, H. A.; Kozat, S. S.
We investigate adaptive mixture methods that linearly combine outputs of m constituent filters running in parallel to model a desired signal. We use Bregman divergences and obtain certain multiplicative updates to train the linear combination weights under an affine constraint or without any constraints. We use unnormalized relative entropy and relative entropy to define two different Bregman divergences that produce an unnormalized exponentiated gradient update and a normalized exponentiated gradient update on the mixture weights, respectively. We then carry out the mean and the mean-square transient analysis of these adaptive algorithms when they are used to combine outputs of m constituent filters. We illustrate the accuracy of our results and demonstrate the effectiveness of these updates for sparse mixture systems.
Open Access
Dimensional crossover in two-dimensional Bose-Fermi mixtures
(Institute of Physics Publishing, 2010) Subaşi, A. L.; Sevinçli, S.; Vignolo, P.; Tanatar, Bilal
We investigate the equilibrium properties of boson-fermion mixtures consisting of a Bose condensate and spin-polarized Fermi gas confined in a harmonic two-dimensional (2D) trap using mean-field theory. Boson-boson and boson-fermion coupling constants have a logarithmic dependence on the density because of the two-dimensional scattering events when the s-wave scattering lengths are on the order of mixture thickness. We show that this modifies the density profiles significantly. It is also shown that the dimensional crossover stabilizes the mixture against collapse and spatial demixing is observed for the case of a negative boson-fermion scattering length.
Open Access
Experimental investigation of critical Casimir forces in binary liquid mixtures by blinking optical tweezers
(OSA, 2017) Magazzu, Alessandro; Schmidt, F.; Callegari, Agnese; Gambassi, A.; Dietrich, S.; Volpe, Giovanni
We investigate, for the first time and by blinking optical tweezers, the effects of critical Casimir forces (CCFs) on the free dynamics of a pair of spherical colloidal particles, immersed in binary liquid mixtures upon approaching their critical points.
Open Access
High-voltage optical emission in binary gaseous mixtures of N2
(Elsevier, 1995) Zengin, V.; Gökmen, A.; Dinçer, S.; Süzer, Ş.
Optical emission in 1:1 binary gaseous mixtures under high voltage displays a varying character depending on pressure, applied voltage polarity, and chemical nature of the mixture. Under negative polarity, in pure N2 and 50% mixture of Ar, O2 and CO2, emission stemming from N2 + is enhanced relative to emission from neutral N2. In mixtures of N2 with gases containing halogens (CCl4, CHCl3, CH2Cl2, CF3H, CF2Cl2 and SF6) a reversal is observed, i.e. the N2 + emission is suppressed. An enhancement factor is defined as the ratio of the emission under negative polarity to positive polarity to quatify this polarity dependence. This enhancement factor varies between 0.01 and 50 depending on the second component in the mixture © 1995 Elsevier Science B.V.
Open Access
Image histogram thresholding using Gaussian kernel density estimation (English)
(IEEE, 2013) Suhre, Alexander; Çetin, A. Enis
In this article, image histogram thresholding is carried out using the likelihood of a mixture of Gaussians. In the proposed approach, a prob ability density function (PDF) of the histogram is computed using Gaussian kernel density estimation in an iterative manner. The threshold is found by iteratively computing a mixture of Gaussians for the two clusters. This process is aborted when the current bin is assigned to a different cluster than its predecessor. The method does not envolve an exhaustive search. Visual examples of our segmentation versus Otsu's thresholding method are presented. © 2013 IEEE.
Open Access
One-step codoping of reduced graphene oxide using boric and nitric acid mixture and its use in metal-free electrocatalyst
(Elsevier, 2015) Tien H.N.; Kocabas, C.; Hur, S.H.
In this study, the preparation of a highly efficient metal-free electrocatalyst, boron and nitrogen codoped reduced graphene oxide (BN-rGO), with an excellent durability is reported. The BN-rGO were prepared in one step using boric and nitric acid mixture, exhibiting highly improved oxygen reduction reaction (ORR) activity than those of the pristine GO and single doped rGOs. The electrocatalyst also showed the excellent long-term durability and CO tolerance than those of the commercial Pt/C catalysts. © 2014 Elsevier B.V.All rights reserved.
Open Access
Phytoremediation of Cu, Cr and Pb mixtures by lemna minor
(2013) Üçüncü, E.; Tunca, E.; Fikirdeşici, S.; Özkan, A.D.; Altindaǧ, A.
The present study reports the capacity of the aquatic macrophyte Lemna minor to remediate combinations of Cu(II), Pb(II) and Cr(III) from a simulated natural environment. The effect of these metal mixtures on the growth of L. minor was also investigated using growth rate and biomass inhibition calculations. L. minor was successful in removing Cr and Pb from the water, and it remained an effective remediation agent when both metals were present in the environment. However, a relatively low absorption capacity was observed for Cu, increasing concentrations of which were associated with significant decreases in growth rate. No statistically significant difference was found between the 24 h and 7 days absorption rates of Cu, Pb and Cr, suggesting that, at the concentrations tested, equilibrium occurs within 24 h of metal exposure. © 2013 Springer Science+Business Media New York.
Open Access
Sound absorption coefficient changes of acoustical plates made of expanded perlite in moist environment
(WITPress, 2003) Yılmazer, Semiha
Expanded perlite is a porous, lightweight, fire resistant and moisture retaining material with sound and thermal insulation properties. In this research, acoustical behaviour of plates made of expanded perlite was studied experimentally. Since these plates are used for sound absorption the acoustical parameter selected for this study is "sound absorption coefficient". Preliminary experiments indicated that moisture reduced the sound absorption coefficient on plates and there is not much significant difference between the dry and 50% humid conditions. However, there is a significant difference in acoustical properties for the 50% - 95% humid conditions. Thus, this interval was studied in detail. A number of expanded perlite plates having different mixtures were prepared and tested. It was observed that coating of expanded perlite particles with sodium silicate increased moisture resistance, and that the addition of mineral fibre into the mixtures increased the strength and sound absorption coefficient of the plates.
Open Access
Strong acid-nonionic surfactant lyotropic liquid-crystalline mesophases as media for the synthesis of carbon quantum dots and highly proton conducting mesostructured silica thin films and monoliths
(American Chemical Society, 2015) Olutaş, E. B.; Balcı, F. M.; Dag, Ö.
Lyotropic liquid-crystalline (LLC) materials are important in designing porous materials, and acids are as important in chemical synthesis. Combining these two important concepts will be highly beneficial to chemistry and material science. In this work, we show that a strong acid can be used as a solvent for the assembly of nonionic surfactants into various mesophases. Sulfuric acid (SA), 10-lauryl ether (C12E10), and a small amount of water form bicontinuous cubic (V1), 2Dhexagonal (H1), and micelle cubic (I1) mesophases with increasing SA/ C12E10 mole ratio. A mixture of SA and C12E10 is fluidic but transforms to a highly ordered LLC mesophase by absorbing ambient water. The LLC mesophase displays high proton conductivity (1.5 to 19.0 mS/cm at room temperature) that increases with an increasing SA content up to 11 SA/ C12E10 mole ratio, where the absorbed water is constant with respect to the SA amount but gradually increases from a 2.3 to 4.3 H2O/C12E10 mole ratio with increasing SA/C12E10 from 2 to 11, respectively. The mixture of SA and C12E10 slowly undergoes carbonization to produce carbon quantum dots (c-dots). The carbonization process can be controlled by simply controlling the water content of the media, and it can be almost halted by leaving the samples under ambient conditions, where the mixture slowly absorbs water to form photoluminescent c-dot-embedded mesophases. Over time the c-dots grow in size and increase in number, and the photoluminescence frequency gradually shifts to a lower frequency. The SA/C12E10 mesophase can also be used as a template to produce highly proton conducting mesostructured silica films and monoliths, as high as 19.3 mS/cm under ambient conditions. Aging the silica samples enhances the conductivity that can be even larger than for the LLC mesophase with the same amount of SA. The presence of silica has a positive effect on the proton conductivity of SA/C12E10 systems.
Open Access
Template-directed photochemical homodimerization and heterodimerization reactions of cinnamic acids
(American Chemical Society, 2021-09-01) Yağcı, Bilge Banu; Zorlu, Y.; Türkmen, Yunus Emre
We developed a general method for the selective photochemical homo- and heterodimerization of cinnamic acid derivatives with the use of commercially available 1,8-dihydroxynaphthalene as a covalent template. A variety of symmetrical and unsymmetrical β-truxinic acids were obtained in high yields and as single diastereomers. The use of a template not only provides the alignment of the two olefins with suitable proximity (<4.2 Å) but also allows the heterodimerization of two different cinnamic acids, leading to unsymmetrical β-truxinic acid products.
Open Access
Two-dimensional boson-fermion mixtures
(2009) Subaşi, A.L.; Sevinçli, S.; Vignolo P.; Tanatar, Bilal
Using mean-field theory, we study the equilibrium properties of boson-fermion mixtures confined in a harmonic pancake-shaped trap at zero temperature. When the modulus of the s -wave scattering lengths are comparable to the mixture thickness, two-dimensional scattering events introduce a logarithmic dependence on density in the coupling constants, greatly modifying the density profiles themselves. We show that, for the case of a negative boson-fermion three-dimensional s -wave scattering length, the dimensional crossover stabilizes the mixture against collapse and drives it toward spatial demixing. © 2009 The American Physical Society.
Open Access
Two-dimensional boson-fermion mixtures in harmonic traps
(Elsevier Science B.V., 2003) Tanatar, Bilal; Erdemir, E.
The density profiles of bosonic and fermionic components in a system of trapped two-dimensional (2D) boson-fermion (BF) mixture are studied. We employ the variational approach to minimize the total energy functional of the BF mixture subject to the conservation of particle numbers of the species. We consider repulsive interactions between bosons and investigate the repulsive and attractive interactions between bosons and fermions. Our results are qualitatively similar to those in 3D, despite the fact that the structure of equations in 2D are different.
Open Access
Vortices in trapped boson-fermion mixtures
(Springer, 2005) Taşgin, M. E.; Subaşi, A. L.; Oktel, M. Ö.; Tanatar, Bilal
We consider a trapped system of atomic boson-fermion mixture with a quantized vortex. We investigate the density profiles of bosonic and fermionic components as functions of the boson-boson and boson-fermion short-range interaction strengths within the mean-filed approach. Stability of a vortex and conditions for the phase segregation are studied. We compare and contrast our results with the related system of droplets of 3He-4He mixtures.
Unknown
X-ray photoelectron spectroscopic investigation of conducting polymer blends
(Springer, 1996) Süzer, Ş.; Toppare, L.; Hallam, K. R.; Allen, G. C.
Electrochemically prepared films of conducting polymers of polypyrrole and polythiophene and their blends with polyamide have been investigated by X-ray photoelectron spectroscopy. In the N1s region of the spectra of films containing polypyrrole the peak corresponding to N+ at 402.0 eV is separated from that of neutral N. The intensity of the N+ peak can be correlated with the electrical conductivity of the films and the spectroscopically derived ratio of F/N+ is close to 4 indicating that one BF4 - dopant ion is incorporated for every oxidized nitrogen center. In the spectra of films of polythiophene and its blends peaks corresponding to S and S+ can not be resolved but again the F/C ratio correlates with the electrical conductivity. © Springer-Verlag 1996.