Browsing by Subject "Microstructure"

Now showing 1 - 18 of 18

Open Access
Dependence of the substrate structure and the film growth at the junction of YBCO SEJ rf-SQUIDs on the IBE process and effects on the SQUID's characteristics
(Elsevier, 2002) Fardmanesh, Mehdi; Schubert, J.; Akram, Rizwan; Banzet, M.; Zander, W.; Zhang, Y.; Schilling, M.; Krause, H-J.
Step edge junction (SEJ) rf-SQUIDs were made of 200 nm thick YBCO films on LaAlO3(100) substrates using pulsed laser deposition technique. The steps on the substrates were developed using a combination of stationary and rotating angled argon ion beams with different beam energies and intensities. While sharp clean steps with heights up to 300 nm were obtained on the substrates using the combinatorial ion beam etching (IBE) process, very shallow ramp-type surfaces were found developing on the bottom of the trench, close to the steps. The ramp-type surfaces were found to be a source of hole-type defects in the films grown at the step edges. High quality films could be obtained on the flat regions away from the steps. Higher defect densities in the films close to the SEJs resulted in devices with higher 1/f noise and wider spread of the junction parameters. The 1/f noise of such devices increased with decreasing temperature. High quality films on sharp clean steps with flat substrate surfaces, developed using optimized combinatorial IBE process, resulted in higher yield of low 1/f noise SQUIDs. The Ic of the junctions and hence the working temperature of the SQUID could also be controlled by the junction width and the step height.
Open Access
Effect of milling time on the structure, micro-hardness, and thermal behavior of amorphous/nanocrystalline TiNiCu shape memory alloys developed by mechanical alloying
(Elsevier Ltd, 2014) Alijani F.; Amini, R.; Ghaffari, M.; Alizadeh, M.; Okyay, Ali Kemal
In the present paper, the effect of milling process on the chemical composition, structure, microhardness, and thermal behavior of Ti-41Ni-9Cu compounds developed by mechanical alloying was evaluated. The structural characteristic of the alloyed powders was evaluated by X-ray diffraction (XRD). The chemical composition homogeneity and the powder morphology and size were studied by scanning electron microscopy coupled with electron dispersive X-ray spectroscopy. Moreover, the Vickers micro-indentation hardness of the powders milled for different milling times was determined. Finally, the thermal behavior of the as-milled powders was studied by differential scanning calorimetery. According to the results, at the initial stages of milling (typically 0-12. h), the structure consisted of a Ni solid solution and amorphous phase, and by the milling evolution, nanocrystalline martensite (B19') and austenite (B2) phases were initially formed from the initial materials and then from the amorphous phase. It was found that by the milling development, the composition uniformity is increased, the inter-layer thickness is reduced, and the powders microhardness is initially increased, then reduced, and afterward re-increased. It was also realized that the thermal behavior of the alloyed powders and the structure of heat treated samples is considerably affected by the milling time.
Open Access
Electrical characteristics of β-Ga2O3 thin films grown by PEALD
(Elsevier, 2014) Altuntas, H.; Donmez, I.; Ozgit Akgun, C.; Bıyıklı, Necmi
In this work, 7.5 nm Ga2O3 dielectric thin films have been deposited on p-type (1 1 1) silicon wafer using plasma enhanced atomic layer deposition (PEALD) technique. After the deposition, Ga2O 3 thin films were annealed under N2 ambient at 600, 700, and 800 C to obtain β-phase. The structure and microstructure of the β-Ga2O3 thin films was carried out by using grazing-incidence X-ray diffraction (GIXRD). To show effect of annealing temperature on the microstructure of β-Ga2O3 thin films, average crystallite size was obtained from the full width at half maximum (FWHM) of Bragg lines using the Scherrer formula. It was found that crystallite size increased with increasing annealing temperature and changed from 0.8 nm to 9.1 nm with annealing. In order to perform electrical characterization on the deposited films, Al/β-Ga2O3/p-Si metal-oxide- semiconductor (MOS) type Schottky barrier diodes (SBDs) were fabricated using the β-Ga2O3 thin films were annealed at 800 C. The main electrical parameters such as leakage current level, reverse breakdown voltage, series resistance (RS), ideality factor (n), zero-bias barrier height (Bo), and interface states (NSS) were obtained from the current-voltage (I-V) and capacitance-voltage (C-V) measurements at room temperature. The RS values were calculated by using Cheung methods. The energy density distribution profile of the interface states as a function of (ESS-EV) was obtained from the forward bias I-V measurements by taking bias dependence of ideality factor, effective barrier height (e), and RS into account. Also using the Norde function and C-V technique, e values were calculated and cross-checked. Results show that β-Ga2O3 thin films deposited by PEALD technique at low temperatures can be used as oxide layer for MOS devices and electrical properties of these devices are influenced by some important parameters such as NSS, RS, and β-Ga2O3 oxide layer.
Open Access
Evaluate of braze joint strength and microstructure characterize of titanium-CP with Ag-based filler alloy
(2012) Ganjeh, E.; Sarkhosh H.; Khorsand H.; Sabet H.; Dehkordi, E.H.; Ghaffari, M.
This research investigates the influences of brazing parameters (temperature and time) on microstructures and the mechanical properties of commercially pure (CP) titanium sheet when it is brazed with CBS34 (Ag-20Cu-22Zn-24Cd) braze filler foil. Brazing was performed in a conventional atmosphere control furnace. The brazing temperatures and holding times employed in this study were 800-870°C and 10-20min, respectively. The qualities of the brazed joints were evaluated by ultrasonic test and the microstructure and phase constitution of the bonded joints were analyzed by means of metallography, scanning electron microscope (SEM) and X-ray diffraction (XRD). The mechanical properties of brazed joints were evaluated by microhardness and shear tests. The diffusion between Ti, Ag, Cu, Zn and Cd from substrate and braze alloy, developed a strong reaction between each other. A number of intermetallic phases, such as TiCu and Ti2Cu in the Ag-Zn solid solution matrix have been identified especially at 870°C - 20min. Both the brazing temperature and the holding time are critical factors for controlling the microstructure and hence the mechanical properties of the brazed joints. The optimum brazing parameters was achieved at 870°C - 20min. Based on the shear test result, all cracks propagate along the brittle intermetallic compounds like Ti2Cu in the reaction layer which typically are composed of quasi-cleavage (Ag-Zn matrix) and brittle appearance. © 2012 Elsevier Ltd.
Open Access
In-chip microstructures and photonic devices fabricated by nonlinear laser lithography deep inside silicon
(Nature Publishing Group, 2017) Tokel, O.; Turnalı, A.; Makey, G.; Elahi, P.; Çolakoǧlu, T.; Ergeçen E.; Yavuz, Ö.; Hübner R.; Borra, M. Z.; Pavlov, I.; Bek, A.; Turan, R.; Kesim, D. K.; Tozburun, S.; Ilday, S.; Ilday, F. Ö.
Silicon is an excellent material for microelectronics and integrated photonics 1-3, with untapped potential for mid-infrared optics 4 . Despite broad recognition of the importance of the third dimension 5,6, current lithography methods do not allow the fabrication of photonic devices and functional microelements directly inside silicon chips. Even relatively simple curved geometries cannot be realized with techniques like reactive ion etching. Embedded optical elements 7, electronic devices and better electronic-photonic integration are lacking 8 . Here, we demonstrate laser-based fabrication of complex 3D structures deep inside silicon using 1-μm-sized dots and rod-like structures of adjustable length as basic building blocks. The laser-modified Si has an optical index different to that in unmodified parts, enabling the creation of numerous photonic devices. Optionally, these parts can be chemically etched to produce desired 3D shapes. We exemplify a plethora of subsurface - that is, 'in-chip' - microstructures for microfluidic cooling of chips, vias, micro-electro-mechanical systems, photovoltaic applications and photonic devices that match or surpass corresponding state-of-the-art device performances.
Open Access
Increasing Ti-6Al-4V brazed joint strength equal to the base metal by Ti and Zr amorphous filler alloys
(2012) Ganjeh, E.; Sarkhosh H.; Bajgholi, M.E.; Khorsand H.; Ghaffari, M.
Microstructural features developed along with mechanical properties in furnace brazing of Ti-6Al-4V alloy using STEMET 1228 (Ti-26.8Zr-13Ni-13.9Cu, wt.%) and STEMET 1406 (Zr-9.7Ti-12.4Ni-11.2Cu, wt.%) amorphous filler alloys. Brazing temperatures employed were 900-950 °C for the titanium-based filler and 900-990 °C for the zirconium-based filler alloys, respectively. The brazing time durations were 600, 1200 and 1800 s. The brazed joints were evaluated by ultrasonic test, and their microstructures and phase constitutions analyzed by metallography, scanning electron microscopy and X-ray diffraction analysis. Since microstructural evolution across the furnace brazed joints primarily depends on their alloying elements such as Cu, Ni and Zr along the joint. Accordingly, existence of Zr 2Cu, Ti 2Cu and (Ti,Zr) 2Ni intermetallic compounds was identified in the brazed joints. The chemical composition of segregation region in the center of brazed joints was identical to virgin filler alloy content which greatly deteriorated the shear strength of the joints. Adequate brazing time (1800 s) and/or temperature (950 °C for Ti-based and 990 °C for Zr-based) resulted in an acicular Widmanstätten microstructure throughout the entire joint section due to eutectoid reaction. This microstructure increased the shear strength of the brazed joints up to the Ti-6Al-4V tensile strength level. Consequently, Ti-6Al-4V can be furnace brazed by Ti and Zr base foils produced excellent joint strengths. © 2012 Elsevier Inc. All rights reserved.
Open Access
Investigating the effect of CP titanium microstructure on the mechanics of microscale machining
(2019-09) Aksın, Alp
Metal cutting in microscale brings along many challenges and unanswered questions. Mechanical response of the material to the micro-cutting process is one of them, since feed values and the edge radius of the tool can be in the magnitude of order of the material's grain size. In addition, the grain morphology of the material may affect process outputs. This study investigates microstructure effects of the commercially pure titanium (CP Ti) based on analytical and mechanistic modeling approaches. A slip line field model was studied considering fracture toughness and edge radius effects. Orthogonal micro-cutting tests were performed on different morphologies at feed levels ranging from 0.25 to 6 µm per revolution and cutting force data were collected. Cut chip thickness values were measured by using SEM and used as in-process output in the model. The model outputs were fit to force data and unknown model parameters were identified. Those determined parameters were compared with measurements. The study show that the rake angle and tool edge radius parameters have a consistent disparity between measured and identified values. Evidence of possible wear and material build up at the tool have been observed. Using Bayesian inference, possible range of rake angle values have been further investigated and probability distributions of the rake value were identified for different feed levels. Micromilling of CP titanium has also been considered and a relationship between microscale orthogonal cutting and micromilling has been sought. CP titanium was tested by conducting full immersion micromilling experiments based on mechanistic modeling. In uence of the grain morphology on model coefficients, surface texture and hardness have been discussed.
Open Access
Investigation of TI6AL4V microstructure effects on process material interaction during micro milling
(2017-12) Ahmadi, Masoud
The interrelationship between material microstructure and process parameters must be well understood in order to improve the machinability. In micro milling, the process parameters including depth of cut, feed and cutting edge radius are comparable to grain size of the material which significantly affects the mechanics of machining. This thesis investigates the contribution of microstructural characteristics including grain size, grain morphology and phase fractions/distributions of dual phase Ti6Al4V titanium alloy in micro scale milling. Various heat treatments were performed on the Ti6Al4V samples obtaining five different microstructures including fine equiaxed plus elongated, two size enlarged equiaxed, lamellar and martensitic microstructures. The influences of microstructures on built upedge (BUE) formation, cutting forces, surface quality and burr formation were studied. It was observed that smaller grain size leads to larger BUE and burr formation and higher cutting forces. However, when feed is set properly it also yields better surface roughness. The crystallographic texture and microstructure of the machined surface of selected samples were investigated using electron backscatter diffraction (EBSD) analysis which revealed that at low feed rates can result in occurrence of dynamic recrystallization (DRX) on the microstructure of the machined surfaces. It was observed that up and down milling stages led to different crystallographic texture of the machined samples during micro scale milling. The findings of this study are important in terms of developing predictive modeling of machining based on material microstructure.
Open Access
Investigation on braze joint strength and microstructure of Ti-CP with Ag and Ti base filler alloys
(American Welding Society, 2012) Ganjeh, E.; Khorsand H.; Sarkhosh H.; Ghaffari, M.; Sabet H.; Dehkordi, E.H.
This research investigates influences of brazing parameters (brazing alloy, temperature and time) on microstructures and mechanical properties of a commercially pure (CP) titanium sheet which is brazed with CBS 34 (Ag-based) and STEMET 1228 (Ti-based) braze-filler foils. Brazing was performed in a conventional inert furnace at temperature ranges of 800-870°C and 10-30 minutes for holding times. Qualities of the brazed joints were evaluated by ultrasonic testing, and then, microstructure and phase constitution of the bonded joints were analyzed by means of metallography, scanning electron microscope (SEM), and X-ray diffraction (XRD). Mechanical properties of brazed joints were evaluated by shear testing. Diffusion of titanium from substrate to filler alloy developed a strong reaction between them. A number of phases such as TiCu, Ti 2Cu, TiAg, Ag-Zn solid solution matrix (for Ag-based brazed samples) and Ti 2Cu, (Ti,Zr) 2Ni, Zr 2Cu (for Ti-based brazed samples) have been identified. The optimum brazing parameters were achieved at a temperature of 870 °C-20 min for CBS 34 and 870 °C-30 min for STEMET 1228. The specimen using STEMET 1228 braze alloy demonstrates best bonding strength (equal to Ti-CP tensile strength). Copyright 2012 ASM International® All rights reserved.
Open Access
Liquid-phase sintering of medical-grade P558 stainless steel using a new biocompatible eutectic additive
(Elsevier, 2012-02-02) Salahinejad, E.; Hadianfard, M. J.; Ghaffari, M.; Mashhadi, S. B.; Okyay, Ali Kemal
One of the effective approaches to reduce residual pores in powder metallurgy parts is activated liquid-phase sintering process using proper additives. In this work, for the first time, a new biocompatible additive (Mn-11.5 wt.% Si, a eutectic alloy) is experimented for liquid-phase sintering of nanocrystalline/amorphous P558 stainless steel powders. It is realized that by increasing the sintering aid content and temperature, the density is effectively increased: a sharp densification progress when the sintering temperature increases from 1000 °C to 1050 °C and a slower densification rate when it exceeds 1050 °C. This preliminary study opens up the development of high-density medical-grade stainless steels produced by powder metallurgy, where suitable additives can lower sintering temperature and time, which is promising for retarding grain growth and commercial applications.
Open Access
Microstructural association between mechanical behavior with bending fracture surfaces in Astaloy CrA sintered parts alloyed by Cu and C
(Elsevier Ltd, 2014) Khorsand H.; Ghaffari, M.; Ganjeh, E.
Application of powder metallurgy technique, a method presenting both economic and technical concepts for producing sintered parts, has been expanding in automobile and other engineering industries. Powder metallurgy parts usually possess residual porosity in their microstructures deteriorating mechanical performance. There have been many solutions to increasing of strength in these parts such as applying different heat treatment or adding alloying elements. It is well known that Fe-Cu-C is the one of main alloying system for both increasing the strength and decreasing cost of them. In this study, the microstructure, mechanical properties (transverse rapture strength and hardness), crack behavior and fracture modes of a low alloy Fe-Cr powder (Astaloy CrA) with different amount of copper (0, 1 and 2. wt.%) and carbon, in form of graphite (0.45, 0.6 and 0.8. wt.%) sintered at conventional condition have been investigated. Microstructural evolution showed adding copper and graphite as alloying elements could generate widespread of strength (857-1380. MPa) and hardness (170-295 HV5). Developing different phases in microstructure was the main reason for various mechanical properties. Crack coalescence phenomenon leads to fracturing with ductile (at sinter-necks) and brittle morphology. Micro-mechanism of fracture related to transparticle and interparticle crack propagation. © 2013 Elsevier Ltd.
Open Access
Microstructural characterization of medical-grade stainless steel powders prepared by mechanical alloying and subsequent annealing
(Elsevier, 2013) Salahinejad, E.; Hadianfard, M. J.; Ghaffari, M.; Amini, R.; Mashhadi, S. B.; Okyay, Ali Kemal
The harmful effect of nickel ions released from conventional stainless steel implants has provided a high level of motivation for the further development of nickel-free stainless steels. In this paper, the microstructure of medical-grade nickel-free stainless steel powders, with the chemical composition of ASTM F2581, is studied during mechanical alloying and subsequent annealing. Rietveld X-ray diffraction and transmission electron microscopy evaluations reflect nanocrystallization, austenitization and amorphization of the powders due to mechanical activation. It is also realized that annealing of the as-milled powder can develop a single austenitic structure with nanometric crystallite sizes, implying a considerable inherent resistance to grain growth. This study demonstrates the merit of mechanical alloying and subsequent annealing in the development of nanostructured medical-grade stainless steels.
Open Access
Organization of bridging organics in periodic mesoporous organosilicas (PMOs)-polarization micro-raman spectroscopy
(Wiley, 2001) Dag, Ö.; Ozin, G. A.
The organization of bridging organics in oriented periodic mesoporous organosilica film (OPMOF) was demonstrated using the polarization micro-Raman spectroscopy (PMRS) in conjunction with powder x-ray diffraction (PXRD) and polarization optical microscopy (POM). The synthesis and the structural characterization of hexagonal symmetry OPMOF containing bridge-bonded ethane, ethene inside the silica channel walls were described. The mesoscale channels were found to run parallel to the surface of the underlying glass substrates as demonstrated by the PXRD measurements. A hexagonal array of channels with glassy silica organosilica walls was the best description of the structure shown by the PMRS measurements of OPMOF.
Open Access
Phase transformation during mechano-synthesis of nanocrystalline/amorphous Fe–32Mn–6Si alloys
(Elsevier, 2013) Amini, R.; Shamsipoor, A.; Ghaffari, M.; Alizadeh, M.; Okyay, Ali Kemal
Mechano-synthesis of Fe-32Mn-6Si alloy by mechanical alloying of the elemental powder mixtures was evaluated by running the ball milling process under an inert argon gas atmosphere. In order to characterize the as-milled powders, powder sampling was performed at predetermined intervals from 0.5 to 192 h. X-ray florescence analyzer, X-ray diffraction, scanning electron microscope, and high resolution transmission electron microscope were utilized to investigate the chemical composition, structural evolution, morphological changes, and microstructure of the as-milled powders, respectively. According to the results, the nanocrystalline Fe-Mn-Si alloys were completely synthesized after 48 h of milling. Moreover, the formation of a considerable amount of amorphous phase during the milling process was indicated by quantitative X-ray diffraction analysis as well as high resolution transmission electron microscopy image and its selected area diffraction pattern. It was found that the α-to-γ and subsequently the amorphous-to-crystalline (especially martensite) phase transformation occurred by milling development.
Open Access
Structural and microstructural phase evolution during mechano-synthesis of nanocrystalline/amorphous CuAlMn alloy powders
(Elsevier, 2013-11) Amini, R.; Mousavizad, S. M. M.; Abdollahpour, H.; Ghaffari, M.; Alizadeh, M.; Okyay, Ali Kemal
The formation mechanism of Cu-11.5Al-4Mn alloys by mechanical alloying (MA) of pure elemental powders was investigated. During milling, the powder sampling was conducted at predetermined intervals from 1 h to 96 h. The quantitative phase analyses were done by X-ray diffraction and the particles size and morphology were studied by scanning electron microscopy. Furthermore, the microstructure investigation and phase identification were done by transmission electron microscopy. Concerning the results, the nanocrystalline Cu solid solution were formed at short milling times and, by milling evolution, the austenite-to-martensite (2H) phase transformation occurred. Moreover, the formation of considerable amount of amorphous phase and its partial transformation to crystalline phases during the milling process were revealed. It was also found that, by milling development, the powder morphology changes from lamellar to semi-spherical and their size initially increases, then reduces and afterward re-increases.
Open Access
Structural, optical and electrical characteristics BaSrTiOx thin films: Effect of deposition pressure and annealing
(Elsevier BV * North-Holland, 2017) Bayrak, T.; Ozgit-Akgun, C.; Goldenberg, E.
Among perovskite oxide materials, BaSrTiOx (BST) has attracted great attention due to its potential applications in oxide-based electronics. However, reliability and efficiency of BST thin films strongly depend on the precise knowledge of the film microstructure, as well as optical and electrical properties. In the present work, BST films were deposited at room temperature using radio frequency magnetron sputtering technique. The impact of deposition pressure, partial oxygen flow, and post-deposition annealing treatment on film microstructure, surface morphology, refractive index, and dielectric constants were studied by X-ray diffraction, scanning electron microscopy, spectrophotometry, ellipsometry, photoluminescence, as well as capacitance-voltage measurements. Well-adhered and uniform amorphous films were obtained at room temperature. For all as-deposited films, the average optical transmission was ~ 85% in the VIS-NIR spectrum. The refractive indices of BST films were in the range of 1.90–2.07 (λ = 550 nm). Post-deposition annealing at 800 °C for 1 h resulted in polycrystalline thin films with increased refractive indices and dielectric constants, however reduced optical transmission values. Frequency dependent dielectric constants were found to be in the range of 46–72. However, the observed leakage current was relatively small, about 1 μA. The highest FOM values were obtained for films deposited at 0.67 Pa pressures, while charge storage capacity values increased with increased deposition pressure. Results show that room-temperature grown BST films have potential for device applications.
Open Access
Theoretical limits of the multistacked 1-D and 2-D microstructured inorganic solar cells
(SPIE, 2015-08) Yengel, Emre; Karaağaç, H.; Logeeswaran, V. J.; İslam, M. S.
Recent studies in monocrystalline semiconductor solar cells are focused on mechanically stacking multiple cells from different materials to increase the power conversion efficiency. Although, the results show promising increase in the device performance, the cost remains as the main drawback. In this study, we calculated the theoretical limits of multistacked 1D and 2D microstructered inorganic monocrstalline solar cells. This system is studied for Si and Ge material pair. The results show promising improvements in the surface reflection due to enhanced light trapping caused by photon-microstructures interactions. The theoretical results are also supported with surface reflection and angular dependent power conversion efficiency measurements of 2D axial microwall solar cells. We address the challenge of cost reduction by proposing to use our recently reported mass-manufacturable fracture-transfer- printing method which enables the use of a monocrystalline substrate wafer for repeated fabrication of devices by consuming only few microns of materials in each layer of devices. We calculated thickness dependent power conversion efficiencies of multistacked Si/Ge microstructured solar cells and found the power conversion efficiency to saturate at %26 with a combined device thickness of 30 μm. Besides having benefits of fabricating low-cost, light weight, flexible, semi-transparent, and highly efficient devices, the proposed fabrication method is applicable for other III-V materials and compounds to further increase the power conversion efficiency above 35% range. © 2015 SPIE.
Open Access
Transferring the structure of paper for mechanically durable superhydrophobic surfaces
(Elsevier, 2020-10-24) Torun, İ.; Celik, N.; Ruzi, M.; Önses, Mustafa Serdar
Solution-phase deposition of nanomaterials represents a highly promising technology with strong industrial application potential for the fabrication of superhydrophobic surfaces. An important barrier towards the adaptation of such materials and processes in a broad range of applications is the limited mechanical durability of the nanostructures. Herein, we present a universal solution to this challenge by benefiting from the unique micro-structure of paper. Our approach is based on transferring the structure of paper into a target material, to form a mechanical protection layer for nanomaterials that were deposited from solution-phase, i.e. spray-coating. We demonstrate this concept through the transfer of the structure of paper to a free-standing PDMS film using a simple molding process. Spraying a dispersion of alkyl-silane functionalized silica nanoparticles on the structured free-standing film results in a hierarchically structured superhydrophobic surface with a water contact angle of 175° ± 2° and a sliding angle <2° ± 1°. The fabricated superhydrophobic surface displays high levels of mechanical, chemical and thermal stability. The robust, inexpensive, scalable, flexible, and environmentally friendly nature of the presented approach may be a key enabler in superhydrophobic coating applications.