Browsing by Subject "Fiber diameter"

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    Antibacterial electrospun nanofibers from triclosan/cyclodextrin inclusion complexes
    (Elsevier, 2014) Celebioglu A.; Umu, O. C. O.; Tekinay, T.; Uyar, Tamer
    The electrospinning of nanofibers (NF) from cyclodextrin inclusion complexes (CD-IC) with an antibacterial agent (triclosan) was achieved without using any carrier polymeric matrix. Polymer-free triclosan/CD-IC NF were electrospun from highly concentrated (160% CD, w/w) aqueous triclosan/CD-IC suspension by using two types of chemically modified CD; hydroxypropyl-beta-cyclodextrin (HPβCD) and hydroxypropyl-gamma-cyclodextrin (HPγCD). The morphological characterization of the electrospun triclosan/CD-IC NF by SEM elucidated that the triclosan/HPβCD-IC NF and triclosan/HPγCD-IC NF were bead-free having average fiber diameter of 520±250nm and 1100±660nm, respectively. The presence of triclosan and the formation of triclosan/CD-IC within the fiber structure were confirmed by 1H-NMR, FTIR, XRD, DSC, and TGA studies. The initial 1:1molar ratio of the triclosan:CD was kept for triclosan/HPβCD-IC NF after the electrospinning and whereas 0.7:1molar ratio was observed for triclosan/HPγCD-IC NF and some uncomplexed triclosan was detected suggesting that the complexation efficiency of triclosan with HPγCD was lower than that of HPβCD. The antibacterial properties of triclosan/CD-IC NF were tested against Gram-negative (Escherichia coli) and Gram-positive (Staphylococcus aureus) bacteria. It was observed that triclosan/HPβCD-IC NF and triclosan/HPγCD-IC NF showed better antibacterial activity against both bacteria compared to uncomplexed pure triclosan.
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    Studies of polymer microring lasers subject to uniaxial stress
    (2007) Tulek, A.; Vardeny, Z.V.
    The emission spectra of microring lasers fabricated from π -conjugated polymer films casted on nylon microfibers with diameters in the range of 35-90 μm were studied upon application of uniaxial stress with strain up to ∼12%. The laser emission spectra substantially change with the applied stress, showing enhanced sensitivity to stress over changes induced in the fiber diameter alone. This is explained as due to the induced change in the polymer refractive index spectrum upon stress, causing an unexpected increase in the refractive index dispersion and, consequently, also in the effective refraction index for lasing at emission wavelengths. © 2007 American Institute of Physics.