Browsing by Subject "Conductive materials"
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Item Open Access Electrochemically obtained insulating and conducting polymers and composites of acrylonitrile(1998) Yilmaz, B.Y.; Akbulut, U.; Toppare L.Electrochemically obtained polyacrylonitrile and a commercial polyacrylonitrile were heat treated to improve their conductivities. The parameters chosen for heat treatment conditions were the temperature, treatment medium (vacuum or air) and, doping agent. The conductivity of all heat treated polymers was measured. The characterization of the heat treated polymers was made by IR analysis. The composite films of polyacrylonitrile with polypyyrole and polythiophene were electrochemically prepared at different compositions. The change in the conductivity of composites was analyzed as a function of the percent composition of the insulating component. IR, DSC, TGA and SEM analyses were used to characterize the polymer composites.Item Open Access On the possibility of grafting conducting polymers into insulating ones(Elsevier, 1996) Bahçeci, S.; Toppare, L.; Yurtsever, E.The possibility of grafting between conducting polymers, like polypyrrole (PPy) and polyaniline (PAn), and insulating polymers, such as polybisphenol A carbonate (PC) and polyamide (PA), is studied via semi-empirical methods using the AM1 parametrization. Several experimental studies on the issue have previously revealed that a chemical interaction exists between the couples (PAn-PC, PPy-PC and PPy-PA) during the electrochemical synthesis of PAn and PPy in the insulating host matrices. Here we present additional theoretical evidence indicating that such grafting is possible, at least for small oligomers.Item Open Access Paraxial space-domain formulation for surface fields on dielectric coated circular cylinder(IEEE, 2002-11) Ertürk, V. B.; Rojas, R. G.A new method to evaluate the surface fields excited within the paraxial (nearly axial) region of an electrically large dielectric coated circular cylinder is presented. This representation is obtained by performing the Watson’s transformation in the standard eigenfunction solution and using the fact that the circumferentially propagating series representation of the appropriate Green’s function is periodic in one of its two variables. Therefore, it can be approximated by a Fourier series where the two leading terms of the expansion yield engineering accuracy in most cases. This work can be used in conjunction with a method of moments solution for the design/analysis of conformal microstrip antennas and arrays. Numerical results are presented and compared with a standard eigenfunction expansion.Item Open Access Protein-releasing conductive anodized alumina membranes for nerve-interface materials(Elsevier Ltd, 2016) Altuntas, S.; Buyukserin, F.; Haider, A.; Altinok, B.; Bıyıklı, Necmi; Aslim, B.Nanoporous anodized alumina membranes (AAMs) have numerous biomedical applications spanning from biosensors to controlled drug delivery and implant coatings. Although the use of AAM as an alternative bone implant surface has been successful, its potential as a neural implant coating remains unclear. Here, we introduce conductive and nerve growth factor-releasing AAM substrates that not only provide the native nanoporous morphology for cell adhesion, but also induce neural differentiation. We recently reported the fabrication of such conductive membranes by coating AAMs with a thin C layer. In this study, we investigated the influence of electrical stimulus, surface topography, and chemistry on cell adhesion, neurite extension, and density by using PC 12 pheochromocytoma cells in a custom-made glass microwell setup. The conductive AAMs showed enhanced neurite extension and generation with the electrical stimulus, but cell adhesion on these substrates was poorer compared to the naked AAMs. The latter nanoporous material presents chemical and topographical features for superior neuronal cell adhesion, but, more importantly, when loaded with nerve growth factor, it can provide neurite extension similar to an electrically stimulated CAAM counterpart.Item Open Access Scanning Hall probe microscopy (SHPM) using quartz crystal AFM feedback(American Scientific Publishers, 2007) Dede, Münir; Ürkmen, Koray; Girişen, Ö.; Atabak, Mehrdad; Oral, Ahmet; Farrer, I.; Ritchie, D.Scanning Hall Probe Microscopy (SHPM) is a quantitative and non-invasive technique for imaging localized surface magnetic field fluctuations such as ferromagnetic domains with high spatial and magnetic field resolution of ∼50 nm and 7 mG/Hz 1/2 at room temperature. In the SHPM technique, scanning tunneling microscope (STM) or atomic force microscope (AFM) feedback is used to keep the Hall sensor in close proximity of the sample surface. However, STM tracking SHPM requires conductive samples; therefore the insulating substrates have to be coated with a thin layer of gold. This constraint can be eliminated with the AFM feedback using sophisticated Hall probes that are integrated with AFM cantilevers. However it is very difficult to micro fabricate these sensors. In this work, we have eliminated the difficulty in the cantilever-Hall probe integration process, just by gluing a Hall Probe chip to a quartz crystal tuning fork force sensor. The Hall sensor chip is simply glued at the end of a 32.768 kHz or 100 kHz Quartz crystal, which is used as force sensor. An LT-SHPM system is used to scan the samples. The sensor assembly is dithered at the resonance frequency using a digital Phase Locked Loop circuit and frequency shifts are used for AFM tracking. SHPM electronics is modified to detect AFM topography and the frequency shift, along with the magnetic field image. Magnetic domains and topography of an Iron Garnet thin film crystal, NdFeB demagnetised magnet and hard disk samples are presented at room temperature. The performance is found to be comparable with the SHPM using STM feedback.Item Open Access X-ray photoelectron spectroscopic investigation of conducting polymer blends(Springer, 1996) Süzer, Ş.; Toppare, L.; Hallam, K. R.; Allen, G. C.Electrochemically prepared films of conducting polymers of polypyrrole and polythiophene and their blends with polyamide have been investigated by X-ray photoelectron spectroscopy. In the N1s region of the spectra of films containing polypyrrole the peak corresponding to N+ at 402.0 eV is separated from that of neutral N. The intensity of the N+ peak can be correlated with the electrical conductivity of the films and the spectroscopically derived ratio of F/N+ is close to 4 indicating that one BF4 - dopant ion is incorporated for every oxidized nitrogen center. In the spectra of films of polythiophene and its blends peaks corresponding to S and S+ can not be resolved but again the F/C ratio correlates with the electrical conductivity. © Springer-Verlag 1996.