Browsing by Subject "Composite materials"
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Item Open Access The almost magical world of metamaterials(IEEE, 2008-11) Özbay, EkmelIn recent years, there has been a burgeoning interest in rapidly growing field of metamaterials due to their unprecedented properties unattainable from ordinary materials. Veselago pointed out that a material exhibiting negative values of dielectric permittivity (epsiv) and magnetic permeability (mu) would have a negative refractive index [1]. Generally speaking, the dielectric permittivity (epsiv) and the magnetic permeability (mu) are both positive for natural materials. In fact, it is possible to obtain negative values for epsiv and mu by utilizing proper designs of metamaterials. Left-handed electromagnetism and negative refraction are achievable with artificially structured metamaterials exhibiting negative values of permittivity and permeability simultaneously at a certain frequency region. The first steps to realize these novel type of materials were taken by Smith et al., where they were able to observe a left-handed propagation band at frequencies where both dielectric permittivity and magnetic permeability of the composite metamaterial are negative [2]. Soon after, left-handed metamaterials with an effective negative index of refraction are successfully demonstrated by various groups.Item Open Access Bacteria-immobilized electrospun fibrous polymeric webs for hexavalent chromium remediation in water(Springer Berlin Heidelberg, 2016) Sarioglu, O.F.; Celebioglu A.; Tekinay, T.; Uyar, TamerThe development of hexavalent chromium remediating fibrous biocomposite mats through the immobilization of a hexavalent chromium reducing bacterial strain, Morganella morganiiSTB5, on the surfaces of electrospun polystyrene and polysulfone webs is described. The bacteria-immobilized biocomposite webs have shown removal yields of 93.60 and 93.79 % for 10 mg/L, 99.47 and 90.78 % for 15 mg/L and 70.41 and 68.27 % for 25 mg/L of initial hexavalent chromium within 72 h, respectively, and could be reused for at least five cycles. Storage test results indicate that the biocomposite mats can be stored without losing their bioremoval capacities. Scanning electron microscopy images of the biocomposite webs demonstrate that biofilms of M. morganii STB5 adhere strongly to the fibrous polymeric surfaces and are retained after repeated cycles of use. Overall, the results suggest that reusable bacteria-immobilized fibrous biocomposite webs might be applicable for continuous hexavalent chromium remediation in water systems.Item Open Access Conducting polymer composites of polypyrrole and a poly(arylene ether ketone)(1998) Selampinar F.; Akbulut, U.; Toppare L.Electrically conducting composites of polypyrrole and a poly(arylene ether ketone) were synthesized by electroinitiated polymerization of pyrrole on a poly(arylene ether ketone)-coated platinum electrode. The electrolysis medium was water and p-toluene sulfonic acid. The conductivities of the composites were in the range 1-10 S/cm. The composites were characterized by scanning electron microscopy, Fourier transform infrared, and thermal analyses. The composites were found to be composed of bilayers which can be peeled into two free-standing polymer films. The solution side of the polypyrrole layer of the alloy film contains globular structures, whereas the other side is smoother.Item Open Access Conducting polymer composites of polypyrrole and polyindene(Elsevier, 1996) Bozkurt, A.; Akbulut, U.; Toppare, L.Polypyrrole-polyindene composites were prepared via electrochemical methods. Two different approaches were utilized. In the first, the electro-initiated polymerization of indene on a platinum electrode was achieved at 2.0 V versus Ag/Ag+ in acetonitrile. Then the polyindene-coated electrode was used for the electrochemical polymerization of pyrrole at 1.0 V versus Ag/Ag+. In the second case, electrochemical coating of platinum electrode with polypyrrole at 1.0 V versus Ag/Ag+ was carried out and indene was polymerized on the conducting polymer at 2.0 V versus Ag/Ag+ in acetonitrile medium. The characterizations of these composites were done by FT-IR, scanning electron microscopy (SEM) and thermal gravimetric analysis (TGA). Electrical conductivities were evaluated by two-probe and four-probe methods.Item Open Access Conducting polymer composites of polythiophene with natural and synthetic rubbers(Elsevier, 1996) Yigit, S.; Hacaloglu, J.; Akbulut, U.; Toppare, L.Electrochemical synthesis of conducting polymer composites of polythiophene was achieved. Synthetic and natural rubbers were used as the insulating polymer matrices. FT-IR, differential scanning calorimetry (DSC), scanning electron microscopy (SEM) and mass spectrometry (MS) were utilized to characterize the composite blends. The conductivity measurements were done by using a standard four-probe technique. The above-mentioned methods show that the resultant composites have different properties compared to polythiophene due to interaction of the rubbers with electrochemical polymerization of thiophene, whereas the same argument is not valid for the polypyrrole synthesis via the same procedure.Item Open Access Development of an innovative sandwich composite material for protection of lower limb against landmine explosion: mechanical leg test results(SAGE Publications Ltd, 2017) Karahan, M.; Karahan, E. A.This paper includes results of the blast tests which were performed with the aim of comparing the energy absorption and protection efficiency of protective boots with different sole configurations. Tests were performed on a mechanical leg model vestured with protective boots. Load and three axis acceleration values were measured during the blast tests to determine the protection efficiency of boot samples. Herewith, it was understood that merely a monolithic composite layer used in a sole does not provide protection, whereas compressible metallic honeycomb material-based sandwich composites demonstrate better energy absorption. With the innovative sandwich composite material developed in this study, energy absorption was increased by 209% in comparison to monolithic composites. © 2016, © The Author(s) 2016.Item Open Access Development of left-handed composite materials and negative refracting photonic crystals with subwavelength focusing(SPIE, 2005) Özbay, EkmelWe review the studies conducted in our group concerning electromagnetic properties of metamaterials and photonic crystals with negative effective index of refraction. In particular, we demonstate the true left handed behavior of a 2D composite metamaterial, by analyzing the electric and magnetic response of the material components systematically. The negative refraction, subwavelength focusing, and flat lens phenomena using 2D dielectric photonic crystals are also presented.Item Open Access Differentiation of domains in composite surface structures by charge-contrast x-ray photoelectron spectroscopy(2007) Süzer, Şefik; Dâna, A.; Ertas, G.An external bias is applied to two samples containing composite surface structures, while recording an XPS spectrum. Altering the polarity of the bias affects the extent of differential charging in domains that are chemically or electronically different to create a charge contrast. By utilizing this charge contrast, we show that two distinct silicon nitride and silicon oxynitride domains are present in one of the composite samples. Similarly, we use this technique to show that titanium oxide and silicon oxide domains exist as separate chemical entities in another composite sample. © 2007 American Chemical Society.Item Open Access Effect of disorder on magnetic resonance band gap of split-ring resonator structures(Optical Society of American (OSA), 2004) Aydın, K.; Güven, K.; Katsarakis, N.; Soukoulis, C. M.; Özbay, EkmelWe investigated the influence of periodicity, misalignment, and disorder on the magnetic resonance gap of split-ring resonators (SRRs) which are essential components of left handed-metamaterials (LHMs). The resonance of a single SRR which is induced by the split is experimentally demonstrated by comparing transmission spectra of SRR and closed ring resonator. Misaligning the SRR boards do not affect the magnetic resonance gap, while destroying the periodicity results in a narrower band gap. The disorder in SRR layers cause narrower left-handed pass band and decrease the transmission level of composite metamaterials (CMMs), which may significantly affect the performance of these LHMs. © 2004 Optical Society of America.Item Open Access Electrochemically obtained insulating and conducting polymers and composites of acrylonitrile(1998) Yilmaz, B.Y.; Akbulut, U.; Toppare L.Electrochemically obtained polyacrylonitrile and a commercial polyacrylonitrile were heat treated to improve their conductivities. The parameters chosen for heat treatment conditions were the temperature, treatment medium (vacuum or air) and, doping agent. The conductivity of all heat treated polymers was measured. The characterization of the heat treated polymers was made by IR analysis. The composite films of polyacrylonitrile with polypyyrole and polythiophene were electrochemically prepared at different compositions. The change in the conductivity of composites was analyzed as a function of the percent composition of the insulating component. IR, DSC, TGA and SEM analyses were used to characterize the polymer composites.Item Open Access Electrospun polymeric nanofibrous composites containing TiO2 short nanofibers(2011) Deniz, A. E.; Celebioglu A.; Kayaci, F.; Uyar, TamerIn this study, polymeric nanofibrous composites containing anatase TiO 2 short nanofibers (TiO2-SNF) were successfully produced via electrospinning. The fabrication of the nanofibrous composite structure includes two steps. First, anatase TiO2 nanofibers were obtained by calcination of electrospun PVP/TiO2 nanofibers and then crushed into short nanofibers ranging from few microns in length. Second, these TiO 2-SNF were dispersed into polymer solutions and then electrospun into nanofibrous composites. We obtained nanofibers containing TiO2-SNF from different polymer types including PMMA, PAN, PET and PC. The SEM and TEM imaging indicated that some of the TiO2-SNF were fully covered by the polymeric matrix whereas some TiO2-SNF were partially covered and/or stick on the surface of the fibers. The photocatalytic activity of nanofibrous composites containing TiO2-SNF was evaluated by monitoring the photocatalytic decomposition of a model dye (rhodamine-6G) under UV irradiation. © 2011 Elsevier B.V. All rights reserved.Item Open Access Experimental analysis of true left-handed behaviour and transmission properties of composite metamaterials(Elsevier, 2005-12) Güven, Kaan; Aydın, Koray; Özbay, EkmelWe report the true left-handed transmission of a composite metamaterial (CMM) consisting of periodically stacked split-ring resonator (SRR) and wire elements. The negative permeability (μ < 0) gap is demonstrated explicitly by comparing SRR and closed-ring resonator structures. We confirm experimentally that the plasma cut-off frequency of the CMM is determined by the combined dielectric response of SRR and wire elements, and it is much lower than that of the wire-only medium. This is crucial to identify the left-handed transmission bands of the CMM. We further investigate the effect of intralayer and interlayer disorder on the transmission spectrum of CMM arising from misaligned fabrication and stacking of the SRR layers. We found that the intralayer disorder affects the μ < 0 gap of SRRs and the left-handed transmission band of CMM significantly, whereas the SRR transmission is rather immune to interlayer disorder.Item Open Access Experimental demonstration of negative refraction and subwavelength imaging by left-handed composite metamaterials(Cambridge University Press, 2006) Özbay, Ekmel; Aydın, Koray; Özkan, Gonca; Bulu, İrfanWe report a true left-handed (LH) behavior and focusing in a composite metamaterial consisting of periodically arranged split ring resonator (SRR) and wire structures. The magnetic resonance of the SRR structure is demonstrated by comparing the transmission spectra of SRRs with that of closed SRRs. We confirmed experimentally that the effective plasma frequency of the LH material composed of SRRs and wires is lower than the plasma frequency of the wires. A well-defined left-handed transmission band with a peak value of -1.2 dB (-0.3 dB/cm) is obtained. We also report the transmission characteristics of a 2D composite metamaterial (CMM) structure in free space. At the frequencies where left-handed transmission takes place, we experimentally confirmed that the CMM structure has effective negative refractive index. Phase shift between consecutive numbers of layers of CMM is measured and phase velocity is shown to be negative at the relevant frequency range. Refractive index values obtained from the refraction experiments and the phase measurements are in good agreement and the experimental results agree extremely well with the theoretical calculations. By measuring the refracted electromagnetic (EM) waves from a LHM slab, we found an effective refractive index of -1.86. A 2D scanning transmission measurement technique was used to measure the intensity distribution of the electromagnetic (EM) waves that radiate from the point source. The flat lens behavior of a 2D CMM slab was demonstrated for two different point source distances of ds = 0.5λ and λ. The full width at half maximum of the focused beams is 0.36λ and 0.4λ, respectively, which are both below the diffraction limit. © 2006 Materials Research Society.Item Open Access Experimental demonstration of sub-wavelength imaging by left handed metamaterials(SPIE, 2007) Özbay, EkmelWe review the studies conducted in our group concerning electromagnetic properties of metamaterials and photonic crystals with negative effective index of refraction. In particular, we demonstate the true left handed behavior of a 2D composite metamaterial, by analyzing the electric and magnetic response of the material components systematically. The negative refraction, subwavelength focusing, and flat lens phenomena using left handed metamaterials and photonic crystals are also presented.Item Open Access Experimental observation of true left-handed metamaterial(IEEE, 2005) Aydın, Koray; Güven, Kaan; Özbay, EkmelWe report a true left-handed (LH) behavior in composite metamaterials. The magnetic resonance of the SRR structure is demonstrated. Plasma frequency of the LH material is shown to be lower than that of the wires.Item Open Access Implementation of high-quality warm-white light-emitting diodes by a model-experimental feedback approach using quantum dot-salt mixed crystals(American Chemical Society, 2015) Adam, M.; Erdem, T.; Stachowski, G.M.; Soran-Erdem Z.; Lox, J. F. L.; Bauer, C.; Poppe, J.; Demir, Hilmi Volkan; Gaponik N.; Eychmüller A.In this work, a model-experimental feedback approach is developed and applied to fabricate high-quality, warm-white light-emitting diodes based on quantum dots (QDs) as color-conversion materials. Owing to their unique chemical and physical properties, QDs offer huge potential for lighting applications. Nevertheless, both emission stability and processability of the QDs are limited upon usage from solution. Incorporating them into a solid ionic matrix overcomes both of these drawbacks, while preserving the initial optical properties. Here borax (Na2B4O7·10H2O) is used as a host matrix because of its lower solubility and thereby reduced ionic strength in water in comparison with NaCl. This guarantees the stability of high-quality CdSe/ZnS QDs in the aqueous phase during crystallization and results in a 3.4 times higher loading amount of QDs within the borax crystals compared to NaCl. All steps from the synthesis via mixed crystal preparation to the warm-white LED preparation are verified by applying the model-experimental feedback, in which experimental data and numerical results provide feedback to each other recursively. These measures are taken to ensure a high luminous efficacy of optical radiation (LER) and a high color rendering index (CRI) of the final device as well as a correlated color temperature (CCT) comparable to an incandescent bulb. By doing so, a warm-white LED with a LER of 341 lm/Wopt, a CCT of 2720 K and a CRI of 91.1 is produced. Finally, we show that the emission stability of the QDs within the borax crystals on LEDs driven at high currents is significantly improved. These findings indicate that the proposed warm-white light-emitting diodes based on QDs-in-borax hold great promise for quality lighting. © 2015 American Chemical Society.Item Open Access Microwave transmission through metamaterials in free space(2002) Aydın, Koray; Bayındır, Mehmet; Özbay, EkmelTo investigate properties of metamaterials, composite structures which consists of periodical arrangement of thin copper wires and SRRs on a circuit board was constructed. Through this, the transmission properties of composite metamaterials at microwave frequencies were investigated. It was observed that a pass-band was formed within the forbidden transmission bands of thin wire and SRR structures.Item Open Access Milling force modelling of multidirectional carbon fiber reinforced polymer laminates(Elsevier, 2012) Karpat, Yiğit; Bahtiyar, O.; Deger, B.Carbon fiber reinforced polymer (CFRP) usage in the aerospace industry has been steadily increasing due to its superior material properties such as high strength, low weight, high resistance to corrosion, and a low thermal expansion coefficient. In addition, CFRP parts are produced near-net-shape, a process that eliminates rough machining operations. However, machining operations such as drilling, side milling, and slotting are still necessary to give the CFRP parts their final shape. A majority of the studies on machining of CFRP laminates are on drilling. The number of studies on milling of CFRPs is quite limited. In this study, a mechanistic cutting force model for milling CFRPs is proposed based on experimentally collected cutting force data during slot milling of unidirectional CFRP laminates using a polycrystalline diamond cutter. Cutting force coefficients in radial and tangential directions are calculated as a function of fiber cutting angle. The mechanistic model is shown to be capable of predicting cutting forces during milling of multidirectional CFRP laminates and capable of investigating stability of machining. © 2012 The Authors.Item Open Access Modulation of electronic properties in laterally and commensurately repeating graphene and boron nitride composite nanostructures(American Chemical Society, 2015) Özçelik, V. O.; Durgun, Engin; Çıracı, SalimGraphene and hexagonal boron nitride (h-BN) nanoribbons of diverse widths and edge geometries are laterally repeated to form commensurate, single-layer, hybrid honeycomb structures. The resulting composite materials appear as continuous, one atom thick stripes of graphene and BN having the average mechanical properties of constituent structures. However, depending on the widths of constituent stripes they can be metal or semiconductor with band gaps in the energy range of the visible light. These two-dimensional (2D) composite materials allow strong dimensionality in electrical conductivity and undergo transition from 2D to one-dimensional (1D) metal in a 2D medium, resulting in multichannel narrow conductors. As for the composite ribbons, such as one dielectric BN stripe placed between two graphene stripes with bare zigzag edges, charge separation of opposite polarity is possible under applied electric field and they exhibit resonant tunneling effects at nanoscale. Graphene/BN composite materials also form stable single-wall nanotubes with zigzag or armchair geometries.Item Open Access Negative refraction and subwavelength focusing using left-handed composite metamaterials(SPIE, 2008-01) Özbay, Ekmel; Aydın, KorayWe review experimental studies performed on left-handed metamaterials (LHM) at microwave frequencies. The metamaterial structure is composed of periodic arrays of split-ring resonators and wire meshes and exhibits a left-handed propagation band at frequencies of negative permittivity and negative permeability. Negative refraction is verified using prism shaped LHM and also by beam-shifting method. Subwavelength focusing of a point source is achieved with a resolution of 0.13λ, through a flat LHM superlens.