Browsing by Author "Fardindoost, S."
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Item Open Access Evidence for Nonradiative Energy Transfer in Graphene-Oxide-Based Hybrid Structures(American Chemical Society, 2013-11-13) Yeltik, A.; Kucukayan-Dogu, G.; Guzelturk, B.; Fardindoost, S.; Kelestemur, Y.; Demir, Hilmi VolkanSolution processed graphene variants including graphene oxide (GO) and reduced graphene oxide (RGO) are promising materials for potential optoelectronic applications. To date, efficiency of the excitation energy transfer into GO and RGO thin layers has not been investigated in terms of donor-acceptor separation distance. In the present work, we study nonradiative energy transfer (NRET) from CdSe/CdS quantum dots into single and/or double layer GO or RGO using time-resolved fluorescence spectroscopy. We observe shorter lifetimes as the separation distance between the QDs and GO or RGO decreases. In accordance with these lifetimes, the rates reveal the presence of two different mechanisms dominating the NRET. Here we show that excitonic NRET is predominant at longer intervals while both excitonic and nonexcitonic NRET exist at shorter distances. In addition, we find the NRET rate behavior to be strongly dependent on the reduction degree of the GO-based layers. We obtain high NRET efficiency levels of similar to 97 and similar to 89% for the closest separation of the QD-RGO pair and the QD-GO pair, respectively. These results indicate that strong NRET from QDs into thin layer GO and RGO makes these solution-processable thin films promising candidates for light harvesting and detection systems.Item Open Access Flexible strain sensors based on electrostatically actuated graphene flakes(Institute of Physics Publishing, 2015) Fardindoost, S.; Alipour, A.; Mohammadi, S.; Gökyar, S.; Sarvari, R.; Iraji Zad, A.; Demir, Hilmi VolkanIn this paper we present flexible strain sensors made of graphene flakes fabricated, characterized, and analyzed for the electrical actuation and readout of their mechanical vibratory response in strain-sensing applications. For a typical suspended graphene membrane fabricated with an approximate length of 10 μm, a mechanical resonance frequency around 136 MHz with a quality factor (Q) of ∼60 in air under ambient conditions was observed. The applied strain can shift the resonance frequency substantially, which is found to be related to the alteration of physical dimension and the built-in strain in the graphene flake. Strain sensing was performed using both planar and nonplanar surfaces (bending with different radii of curvature) as well as by stretching with different elongations. © 2015 IOP Publishing Ltd.Item Open Access High-efficiency CdTe/CdS core/shell nanocrystals in water enabled by photo-induced colloidal hetero-epitaxy of CdS shelling at room temperature(Tsinghua University Press, 2015) Zare, H.; Marandi, M.; Fardindoost, S.; Sharma, V.K.; Yeltik A.; Akhavan, O.; Demir, Hilmi Volkan; Taghavinia, N.We report high-efficiency CdTe/CdS core/shell nanocrystals synthesized in water by epitaxially growing CdS shells on aqueous CdTe cores at room temperature, enabled by the controlled release of S species under low-intensity ultraviolet (UV) light illumination. The resulting photo-induced dissociation of S2O32− ions conveniently triggers the formation of critical two-dimensional CdS epitaxy on the CdTe surface at room temperature, as opposed to initiating the growth of individual CdS core-only nanocrystals. This controlled colloidal hetero-epitaxy leads to a substantial increase in the photoluminescence (PL) quantum yield (QY) of the shelled nanocrystals in water (reaching 64%). With a systematic set of studies, the maximum PL QY is found to be almost independent of the illuminating UV intensity, while the shell formation kinetics required for reaching the maximum QY linearly depends on the illuminating UV intensity. A stability study of the QD films in air at various temperatures shows highly improved thermal stability of the shelled QDs (up to 120 °C in ambient air). These results indicate that the proposed aqueous CdTe/CdS core/shell nanocrystals hold great promise for applications requiring efficiency and stability. [Figure not available: see fulltext.] © 2015, Tsinghua University Press and Springer-Verlag Berlin Heidelberg.