Browsing by Author "Arslan, O."
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Item Open Access A Benders decomposition approach for the charging station location problem with plug-in hybrid electric vehicles(Elsevier, 2016) Arslan, O.; Karaşan, O. E.The flow refueling location problem (FRLP) locates p stations in order to maximize the flow volume that can be accommodated in a road network respecting the range limitations of the vehicles. This paper introduces the charging station location problem with plug-in hybrid electric vehicles (CSLP-PHEV) as a generalization of the FRLP. We consider not only the electric vehicles but also the plug-in hybrid electric vehicles when locating the stations. Furthermore, we accommodate multiple types of these vehicles with different ranges. Our objective is to maximize the vehicle-miles-traveled using electricity and thereby minimize the total cost of transportation under the existing cost structure between electricity and gasoline. This is also indirectly equivalent to maximizing the environmental benefits. We present an arc-cover formulation and a Benders decomposition algorithm as exact solution methodologies to solve the CSLP-PHEV. The decomposition algorithm is accelerated using Pareto-optimal cut generation schemes. The structure of the formulation allows us to construct the subproblem solutions, dual solutions and nondominated Pareto-optimal cuts as closed form expressions without having to solve any linear programs. This increases the efficiency of the decomposition algorithm by orders of magnitude and the results of the computational studies show that the proposed algorithm both accelerates the solution process and effectively handles instances of realistic size for both CSLP-PHEV and FRLP.Item Open Access A branch and price approach for routing and refueling station location model(Elsevier, 2016) Yıldız, B.; Arslan, O.; Karaşan, O. E.The deviation flow refueling location problem is to locate p refueling stations in order to maximize the flow volume that can be refueled respecting the range limitations of the alternative fuel vehicles and the shortest path deviation tolerances of the drivers. We first provide an enhanced compact model based on a combination of existing models in the literature for this relatively new operations research problem. We then extend this problem and introduce the refueling station location problem which adds the routing aspect of the individual drivers. Our proposed branch and price algorithm relaxes the simple path assumption generally adopted in the existing studies and implicitly takes into account deviation tolerances without the pregeneration of the routes. Therefore, the decrease in solution times with respect to existing models is significant and our algorithm scales very efficiently to more realistic network dimensions.Item Open Access A branch-and-cut algorithm for the alternative fuel refueling station location problem with routing(INFORMS, 2019) Arslan, O.; Karaşan, Oya Ekin; Mahjoub, A. R.; Yaman, HandeBecause of the limited range of alternative fuel vehicles (AFVs) and the sparsity of the available alternative refueling stations (AFSs), AFV drivers cooperatively deviate from their paths to refuel. This deviation is bounded by the drivers’ tolerance. Taking this behavior into account, the refueling station location problem with routing (RSLP-R) is defined as maximizing the AFV flow that can be accommodated in a road network by locating a given number of AFSs while respecting the range limitation of the vehicles and the deviation tolerance of the drivers. In this study, we develop a natural model for the RSLP-R based on the notion of length-bounded cuts, analyze the polyhedral properties of this model, and develop a branch-and-cut algorithm as an exact solution approach. Extensive computational experiments show that the algorithm significantly improves the solution times with respect to previously developed exact solution methods and extends the size of the instances solved to optimality. Using our methodology, we investigate the tradeoffs between covered vehicle flow and deviation tolerance of the drivers and present insights on deviation characteristics of drivers in a case study in California.Item Open Access Controlled modulation of 1D ZnO nano/micro structures: Evaluation of the various effects on the photocatalytic activity(Elsevier Ltd, 2017) Arslan, O.; Abalı, Y.Effects of the concentration, temperature and precursor type on the fabrication of the elongated ZnO nano/micro structures were comprehensively investigated. Analytical investigations such as SEM and statistical analysis of the elongated ZnO nano/micro structures provided wide information about the growth behavior and final geometries. Different temperatures for the 1 D ZnO formation clearly revealed that hexagonally grown ZnO nanorods were obtained. Especially low crystal diffraction characteristics at low temperature (55 °C) implied that ZnO nano/micro rod formation requires some minimum conditions for the formation of an efficient photocatalyst. All XRD investigations together with SEM and TEM supported the ligand ordered elongation conducted by diverse beginning concentrations. Since temperature found as a highly dominant actor for morphology and surface sequence as manifested in crystallinity, morphology and photocatalytic results, we have systematically summarized the growth conditions of the ZnO nano/micro rods from same precursor. © 2017 Elsevier LtdItem Open Access Cost and emission impacts of virtual power plant formation in plug-in hybrid electric vehicle penetrated networks(2013) Arslan, O.; Karasan, O. E.With increasing interest in alternative energy resources and technologies, mass penetration of PHEVs (plug-in hybrid vehicles) into the electricity grid and widespread utilization of DERs (distributed energy resources) are anticipated in the near future. As an aggregation unit, the VPP (virtual power plant) is introduced for load management and resource scheduling. In this article, we develop an energy management model for VPPs and analyze the cost and emission impacts of VPP formation and PHEV penetration. We conduct a case study for the state of California using real-world data from official resources. An average of 29.5% cost reduction and 79% CO2 and 83% NOx emission reductions are attained as shared benefits of consumers in the case study. Results are illustrative of opportunities that VPP formation can provide for the community. Sensitivity of the results to the DER costs and capacities, battery and gasoline prices are also analyzed. In addition, we prove that charging and discharging do not simultaneously occur in the solutions, which leads to a simplification in traditional energy management models.Item Open Access Fiber optical network design problems: a case for Turkey(Elsevier, 2016-09) Yazar, B.; Arslan, O.; Karaşan, O. E.; Kara, B. Y.In this paper, we consider problems originating from one of the largest Internet service providers operating in Turkey. The company mainly faces two different design problems: the green field design (area with no Internet access) and the copper field re-design (area with limited access over copper networks). In the green field design problem, the aim is to design a least cost fiber optical network that will provide high bandwidth Internet access from a given central station to a set of aggregated demand nodes. Such an access can be provided either directly by installing fibers or indirectly by utilizing passive splitters. Insertion loss, bandwidth level and distance limitations should simultaneously be considered in order to provide a least cost design to enable the required service level. In the re-design of the copper field application, the aim is to improve the current service level by augmenting the network with fiber optical wires, specifically by adding cabinets to copper rings in the existing infrastructure and by constructing direct fiber links from cabinets to distant demand nodes. Mathematical models are constructed for both problem specifications. Extensive computational results based on realistic data from Kartal (45 nodes) and Bakırköy (74 nodes) districts in Istanbul show that the proposed models are viable exact solution methodologies for moderate dimensions.Item Open Access Fluorescent Si QD decoration onto a flexible polymeric electrospun nanofibrous mat for the colorimetric sensing of TNT(Royal Society of Chemistry, 2017) Arslan, O.; Aytac Z.; Uyar, TamerUV range light was used for the facile, effective and large-scale synthesis of visible light emitting, surface-protected silicon quantum dots (Si QDs) starting from an amine-functionalized alkoxy silane precursor. Within mild and easy hydrolysis/condensation environments, the use of an amine-functionalized precursor together with a reducing agent resulted in a bright visible green light that could be used for fluorescent analytical detection systems. Visible light emitting Si QDs were investigated and it was found that their emission character depends on the illumination time, hydrolysis/condensation conditions and pretreatments for the silane coupling agents. A Nylon 6,6 electrospun nanofibrous mat was selected as a substrate for decoration by the Si QDs in order to fabricate a flexible and free-standing polymeric nanofibrous mat posessing a visible light emitting character so that it could act as a visible colorimetric sensor. The visible light emitting Si QDs were decorated onto the Nylon 6,6 nanofibrous mats via covering the surfaces as a ‘nanodress’ by a simple impregnation/dip-coating and heat-curing methods. The analytical results revealed that the Si QDs decorated flexible polymeric nanofibrous mats could be utilized for colorimetric trinitrotoluene (TNT) detection in low concentrations.Item Open Access Impacts of battery characteristics, driver preferences and road network features on travel costs of a plug-in hybrid electric vehicle (PHEV) for long-distance trips(Elsevier, 2014-11) Arslan, O.; Yıldız, B.; Karaşan, O. E.In a road network with refueling and fast charging stations, the minimum-cost driving path of a plug-in hybrid electric vehicle (PHEV) depends on factors such as location and availability of refueling/fast charging stations, capacity and cost of PHEV batteries, and driver tolerance towards extra mileage or additional stopping. In this paper, our focus is long-distance trips of PHEVs. We analyze the impacts of battery characteristics, often-overlooked driver preferences and road network features on PHEV travel costs for long-distance trips and compare the results with hybrid electric and conventional vehicles. We investigate the significance of these factors and derive critical managerial insights for shaping the future investment decisions about PHEVs and their infrastructure. In particular, our findings suggest that with a certain level of deployment of fast charging stations, well established cost and emission benefits of PHEVs for the short range trips can be extended to long distance. Drivers׳ stopping intolerance may hamper these benefits; however, increasing battery capacity may help overcome the adverse effects of this intolerance.Item Open Access The location and location-routing problem for the refugee camp network design(Elsevier Ltd, 2021-01) Arslan, O.; Culhan Kumcu, G.; Yetiş Kara, Bahar; Laporte, G.The refugee crisis is one of the major challenges of modern society. The influxes of refugees are usually sudden and the refugees are in sheer need of services such as health care, education and safety. Planning public services under an imminent humanitarian crisis re quires simultaneous strategic and operational decisions. Inspired by a real-world problem that Red Crescent is facing in Southeast Turkey, we study the problem of locating refugee camps and planning transportation of public service providers from their institutions to the located camps. Our modeling approach brings a new facet to the location and routing problem by considering the location of beneficiaries as variables. We develop a branch price-and-cut algorithm for the problem. To solve the pricing problem, we introduce a cycle-eliminating algorithm using nested recursion to generate elementary hop constrained shortest paths. The best version of our algorithm efficiently solves 244-node real-world in stances optimallItem Open Access Multifunctional electrospun polymeric nanofibrous mats for catalytic reduction, photocatalysis and sensing(Royal Society of Chemistry, 2017) Arslan, O.; Uyar, TamerFabrication and decoration of flexible Nylon 6,6 polymeric nanofibrous mats for production of multifunctional electrospun material was accomplished via visible light-emitting surface-protected silicon quantum dots (Si QD), ZnO nanoparticles (ZnO NP) and Pd nanocubes (Pd NC). UV-range light was utilized for Si QD production and, after hydrolysis/condensation together with nucleation and growth reactions, amine-modified, fluorescent Si QD were obtained. Additionally, available molecular groups on the Si QD coated onto the polymeric nanofibrous mats provided further attachment of metal oxide and metal NP for various catalytic purposes. Analytical investigations showed that visible-light emission could be maintained on the Nylon 6,6 mats for trinitrotoluene (TNT) sensing. Also, due to consecutive NP decoration, multifunctional, polymeric, flexible nanofibrous mats were obtained. Experiments revealed that fabricated multifunctional mats could reduce molecules such as paranitrophenol effectively or decompose waste dyes such as methylene blue via photocatalytic experiments, and sense the pollutant TNT in aqueous solutions as an all-in-one concept.Item Open Access Nanocomposite glass coatings containing hexagonal boron nitride nanoparticles(Pergamon Press, 2016) Çamurlu, H. E.; Akarsu, E.; Arslan, O.; Mathur, S.Glass coatings composed of SiO2-K2O-Li2O, containing non-modified and fluorosilane modified hexagonal boron nitride (hBN) nanoparticles, were prepared on stainless steel plates through sol-gel spin-coating method. Coatings were examined by scanning electron microscopy (SEM), Fourier transform infrared (FTIR) spectroscopy, x-ray diffraction (XRD), atomic force microscopy (AFM) and thermo-gravimetric analysis (TGA). 1.3-2.5 μm thick uniform coatings were obtained after curing at 500 °C for 1 h. The coatings adhered well to the steel substrates. It was determined by salt spray tests that the coatings enhance corrosion resistance. The aim of hydrophobic fluorosilane modification of hBN nanoparticles was to enrich hBN quantity on the top surface of the coatings. Coatings containing fluorosilane modified hBN nanoparticles presented slightly lower friction coefficient values than the other coatings.Item Open Access Pd nanocube decoration onto flexible nanofibrous mats of core-shell polymer-ZnO nanofibers for visible light photocatalysis(Royal Society of Chemistry, 2017) Arslan, O.; Topuz, F.; Eren, H.; Bıyıklı, Necmi; Uyar, TamerPlasmonic enhancement for electron-hole separation efficiency and visible light photocatalysis was achieved by Pd nanocube decoration on a ZnO nanolayer coated onto electrospun polymeric (polyacrylonitrile (PAN)) nanofibers. Since exciton formation and sustainable electron-hole separation have a vital importance for realizing better solar energy in photovoltaic and photocatalytic devices, we achieved visible light photocatalysis by Pd nanocube decoration onto well designed core-shell nanofibers of ZnO@PAN-NF. By controlling the cubic Pd nanoparticle size and the thickness of the crystalline ZnO nanolayer deposited onto electrospun PAN nanofibers via atomic layer deposition (ALD), defect mediated visible light photocatalysis efficiency can be increased. By utilizing nanofabrication techniques such as thermal decomposition, electrospinning and ALD, this fabricated template became an efficient, defect mediated, Pd nanocube plasmon enhanced photocatalytic system. Due to the enhanced contact features of the Pd nanocubes, an increase was observed for the visible light photocatalytic activity of the flexible and nanofibrous mat of Pd@ZnO@PAN-NF.Item Open Access Reusable and flexible heterogeneous catalyst for reduction of TNT by Pd nanocube decorated ZnO nanolayers onto electrospun polymeric nanofibers(Wiley-Blackwell, 2017-10) Arslan, O.; Eren, H.; Bıyıklı, Necmi; Uyar, TamerAn effective method for the fabrication of well designed nanocomposite for the catalytic reduction of 2,4,6-trinitrotoluene (TNT) was developed. Here, cubic palladium (Pd) nanoparticles were utilized for enhancing the interface properties, attachment quality, catalytic yield and stability after the catalysis reactions. Ligand controlled facet growth by the Br- anions during thermal decomposition of the palladium-precursor resulted with cubic shaped average ∼13 nm palladium nanocubes (Pd NC). The anisotropic Pd NC were utilized to decorate the surface of the zinc oxide (ZnO) nanolayers deposited by atomic layer deposition (ALD) technique on the electrospun polyacrylonitrile (PAN) nanofibers. Due to the polymeric nature of the electrospun PAN nanofibers, Pd NC decorated nanoweb is highly flexible and has a high surface area. For the sustainable Pd NC decoration on the ZnO surfaces coated on PAN nanofibers, anchor points were formed by the functional thiol groups which can facilitate the Pd NC attachment and stability on the ZnO surface. The -OH and alkyl thiol groups obtained via sol-gel reactions positioned on the ZnO layer providing a better interface between ZnO and Pd NC which cannot be obtained by pristine PAN nanofibers. Additionally, due to the increased surface interaction, geometrical positioning on fibers for a better intermediate complex formation and stability via soft-soft interaction, Pd NC decorated flexible polymeric electrospun nanoweb provided enhanced catalytic reduction of TNT in aqueous medium.Item Open Access Superhydrophobic, hybrid, electrospun cellulose acetate nanofibrous mats for oil/water separation by tailored surface modification(American Chemical Society, 2016) Arslan, O.; Aytac Z.; Uyar, TamerElectrospun cellulose acetate nanofibers (CA-NF) have been modified with perfluoro alkoxysilanes (FS/CA-NF) for tailoring their chemical and physical features aiming oil-water separation purposes. Strikingly, hybrid FS/CA-NF showed that perfluoro groups are rigidly positioned on the outer surface of the nanofibers providing superhydrophobic characteristic with a water contact angle of ∼155°. Detailed analysis showed that hydrolysis/condensation reactions led to the modification of the acetylated β(1 → 4) linked d-glucose chains of CA transforming it into a superhydrophobic nanofibrous mat. Analytical data have revealed that CA-NF surfaces can be selectively controlled for fabricating the durable, robust and water resistant hybrid electrospun nanofibrous mat. The -OH groups available on the CA structure allowed the basic sol-gel reactions started by the reactive FS hybrid precursor system which can be monitored by spectroscopic analysis. Since alkoxysilane groups on the perfluoro silane compound are capable of reacting for condensation together with the CA, superhydrophobic nanofibrous mat is obtained via electrospinning. This structural modification led to the facile fabrication of the novel oil/water nanofibrous separator which functions effectively demonstrated by hexane/oil and water separation experiments. Perfluoro groups consequently modified the hydrophilic CA nanofibers into superhydrophobic character and therefore FS/CA-NF could be quite practical for future applications like water/oil separators, as well as self-cleaning or water resistant nanofibrous structures.