Direct evidence for the instability and deactivation of mixed-oxide systems: influence of surface segregation and subsurface diffusion
dc.citation.epage | 22443 | en_US |
dc.citation.issueNumber | 45 | en_US |
dc.citation.spage | 22438 | en_US |
dc.citation.volumeNumber | 115 | en_US |
dc.contributor.author | Emmez, E. | en_US |
dc.contributor.author | Vovk, E. I. | en_US |
dc.contributor.author | Bukhtiyarov V. I. | en_US |
dc.contributor.author | Ozensoy, E. | en_US |
dc.date.accessioned | 2016-02-08T09:50:09Z | |
dc.date.available | 2016-02-08T09:50:09Z | |
dc.date.issued | 2011 | en_US |
dc.department | Department of Chemistry | en_US |
dc.description.abstract | In the current contribution, we provide a direct demonstration of the thermally induced surface structural transformations of an alkaline-earth oxide/transition metal oxide interface that is detrimental to the essential catalytic functionality of such mixed-oxide systems toward particular reactants. The BaOx/TiO2/Pt(111) surface was chosen as a model interfacial system where the enrichment of the surface elemental composition with Ti atoms and the facile diffusion of Ba atoms into the underlying TiO2 matrix within 523 873 K leads to the formation of perovskite type surface species (BaTiO3/Ba2TiO4/BaxTiyOz). At elevated temperatures (T > 973 K), excessive surface segregation of Ti atoms results in an exclusively TiO2/TiOx-terminated surface which is almost free of Ba species. Although the freshly prepared BaOx/TiO2/Pt(111) surface can strongly adsorb ubiquitous catalytic adsorbates such as NO2 and CO2, a thermally deactivated surface at T > 973 K practically loses all of its NO2/CO2 adsorption capacity due to the deficiency of surface BaOx domains. | en_US |
dc.description.provenance | Made available in DSpace on 2016-02-08T09:50:09Z (GMT). No. of bitstreams: 1 bilkent-research-paper.pdf: 70227 bytes, checksum: 26e812c6f5156f83f0e77b261a471b5a (MD5) Previous issue date: 2011 | en |
dc.identifier.doi | 10.1021/jp206969h | en_US |
dc.identifier.eissn | 1932-7455 | |
dc.identifier.issn | 1932-7447 | |
dc.identifier.uri | http://hdl.handle.net/11693/21715 | |
dc.language.iso | English | en_US |
dc.relation.isversionof | http://dx.doi.org/10.1021/jp206969h | en_US |
dc.source.title | Journal of Physical Chemistry C | en_US |
dc.subject | Adsorption capacities | en_US |
dc.subject | Alkaline earth | en_US |
dc.subject | Catalytic functionalities | en_US |
dc.subject | Elemental compositions | en_US |
dc.subject | Elevated temperature | en_US |
dc.subject | Interfacial systems | en_US |
dc.subject | Matrix | en_US |
dc.subject | Metal oxide interface | en_US |
dc.subject | Perovskite type | en_US |
dc.subject | Structural transformation | en_US |
dc.subject | Surface species | en_US |
dc.subject | Thermally induced | en_US |
dc.subject | Ti atoms | en_US |
dc.subject | TiO | en_US |
dc.subject | Adsorption | en_US |
dc.subject | Atoms | en_US |
dc.subject | Barium | en_US |
dc.subject | Barium compounds | en_US |
dc.subject | Carbon dioxide | en_US |
dc.subject | Metallic compounds | en_US |
dc.subject | Nitrogen oxides | en_US |
dc.subject | Perovskite | en_US |
dc.subject | Platinum | en_US |
dc.subject | Titanium dioxide | en_US |
dc.subject | Surface segregation | en_US |
dc.title | Direct evidence for the instability and deactivation of mixed-oxide systems: influence of surface segregation and subsurface diffusion | en_US |
dc.type | Article | en_US |
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