Variation of stability constants of thorium citrate complexes with ionic strength

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dc.citation.epage127en_US
dc.citation.issueNumber1en_US
dc.citation.spage123en_US
dc.citation.volumeNumber74en_US
dc.contributor.authorChoppin, G. R.en_US
dc.contributor.authorErten, H. N.en_US
dc.contributor.authorXia, Yuan-Xiaen_US
dc.date.accessioned2016-02-08T10:49:20Z
dc.date.available2016-02-08T10:49:20Z
dc.date.issued1996en_US
dc.departmentDepartment of Chemistryen_US
dc.description.abstractCitrate is among the organic anions which are expected to be present in the wastes planned for deposition in the WIPP repository. In this study, a solvent extraction method has been used to measure the stability constants of Th(IV) with citrate anions in aqueous solutions with (a) NaClO4 and (b) NaCI as the back-ground electrolytes. The ionic strengths were varied up to 5 m (NaCl) and 14 m (NaClO4). The data from the NaClO4 solutions at varying pH values were used to calculate thermodynamic stability constants through the use of Specific Ion Interaction Theory (SIT).en_US
dc.identifier.doi10.1524/ract.1996.74.special-issue.123en_US
dc.identifier.issn0033-8230
dc.identifier.urihttp://hdl.handle.net/11693/25704
dc.language.isoEnglishen_US
dc.publisherDe Gruyter Oldenbourgen_US
dc.relation.isversionofhttp://doi.org/10.1524/ract.1996.74.special-issue.123en_US
dc.source.titleRadiochimica Actaen_US
dc.subjectCitrateen_US
dc.subjectComplexationen_US
dc.subjectSolvent extractionen_US
dc.subjectStability constantsen_US
dc.subjectThoriumen_US
dc.titleVariation of stability constants of thorium citrate complexes with ionic strengthen_US
dc.typeArticleen_US

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