Variation of stability constants of thorium citrate complexes with ionic strength
dc.citation.epage | 127 | en_US |
dc.citation.issueNumber | 1 | en_US |
dc.citation.spage | 123 | en_US |
dc.citation.volumeNumber | 74 | en_US |
dc.contributor.author | Choppin, G. R. | en_US |
dc.contributor.author | Erten, H. N. | en_US |
dc.contributor.author | Xia, Yuan-Xia | en_US |
dc.date.accessioned | 2016-02-08T10:49:20Z | |
dc.date.available | 2016-02-08T10:49:20Z | |
dc.date.issued | 1996 | en_US |
dc.department | Department of Chemistry | en_US |
dc.description.abstract | Citrate is among the organic anions which are expected to be present in the wastes planned for deposition in the WIPP repository. In this study, a solvent extraction method has been used to measure the stability constants of Th(IV) with citrate anions in aqueous solutions with (a) NaClO4 and (b) NaCI as the back-ground electrolytes. The ionic strengths were varied up to 5 m (NaCl) and 14 m (NaClO4). The data from the NaClO4 solutions at varying pH values were used to calculate thermodynamic stability constants through the use of Specific Ion Interaction Theory (SIT). | en_US |
dc.description.provenance | Made available in DSpace on 2016-02-08T10:49:20Z (GMT). No. of bitstreams: 1 bilkent-research-paper.pdf: 70227 bytes, checksum: 26e812c6f5156f83f0e77b261a471b5a (MD5) Previous issue date: 1996 | en |
dc.identifier.doi | 10.1524/ract.1996.74.special-issue.123 | en_US |
dc.identifier.issn | 0033-8230 | |
dc.identifier.uri | http://hdl.handle.net/11693/25704 | |
dc.language.iso | English | en_US |
dc.publisher | De Gruyter Oldenbourg | en_US |
dc.relation.isversionof | http://doi.org/10.1524/ract.1996.74.special-issue.123 | en_US |
dc.source.title | Radiochimica Acta | en_US |
dc.subject | Citrate | en_US |
dc.subject | Complexation | en_US |
dc.subject | Solvent extraction | en_US |
dc.subject | Stability constants | en_US |
dc.subject | Thorium | en_US |
dc.title | Variation of stability constants of thorium citrate complexes with ionic strength | en_US |
dc.type | Article | en_US |
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