Solid state emissive bodipy dyes with bulky substituents as spacers and a sensitive and selective ratiometric near IR fluorescent probe for zinc ions based on the distyryl-bodipy fluorophore

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buir.advisorAkkaya, Engin U.
dc.contributor.authorÖzdemir, Tuğba
dc.date.accessioned2016-01-08T18:13:15Z
dc.date.available2016-01-08T18:13:15Z
dc.date.issued2010
dc.departmentGraduate Program in Materials Science and Nanotechnologyen_US
dc.descriptionAnkara : The Graduate Program of Materials Science and Nanotechnology and the Institute of Engineering and Sciences of Bilkent University, 2010.en_US
dc.descriptionThesis (Master's) -- Bilkent University, 2010.en_US
dc.descriptionIncludes bibliographical references leaves 74-77.en_US
dc.description.abstractDyes having solid state fluorescence are playing an important role for organic light emitting devices (OLED), optoelectronic devices and photoelectric conversion. However, emissive solids are not common because of the quenching resulting from the packing. With these considerations, we have synthesized and characterized novel boradiazaindacene BODIPY-based dye with bulky substituents (3,5-di-tert-butylphenyl) to prevent π-π stacking of the chromophore. We have succesfully demonstrated that by simple modulation of BODIPY core with very bulky groups lead us to have a bright emissive compounds in solid state. In the second part of this research, we developed BODIPY based near-IR dye as a selective, ratiometric and water-soluble fluorophore for Zn (II) cation. We functionalized the versatile BODIPY from its 3 and 5 positions for long wavelength emission the zinc selective chemosensor.en_US
dc.description.degreeM.S.en_US
dc.description.statementofresponsibilityÖzdemir, Tuğbaen_US
dc.format.extentxv, 116 leaves, illustrationsen_US
dc.identifier.itemidB122588
dc.identifier.urihttp://hdl.handle.net/11693/15096
dc.language.isoEnglishen_US
dc.publisherBilkent Universityen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subjectSolid state fluorescenceen_US
dc.subjectChemosensoren_US
dc.subjectBoradiazaindaceneen_US
dc.subjectNear-IR dyesen_US
dc.subjectπ-π stackingen_US
dc.subjectStokes’ shiften_US
dc.subject.lccQP519.9.F56 O93 2010en_US
dc.subject.lcshFluorescent probes.en_US
dc.subject.lcshFluorescence spectroscopy.en_US
dc.subject.lcshFluorescent Dyes.en_US
dc.subject.lcshNanostructured materials.en_US
dc.subject.lcshLight emitting diodes.en_US
dc.titleSolid state emissive bodipy dyes with bulky substituents as spacers and a sensitive and selective ratiometric near IR fluorescent probe for zinc ions based on the distyryl-bodipy fluorophoreen_US
dc.typeThesisen_US

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