Spectroscopic characterization of VOx/ZrO2 catalysts prepared using vanadium(V) oxo complexes

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dc.citation.epage492en_US
dc.citation.spage487en_US
dc.citation.volumeNumber141-142en_US
dc.contributor.authorKantcheva, M.en_US
dc.date.accessioned2016-02-08T11:57:48Z
dc.date.available2016-02-08T11:57:48Z
dc.date.issued2001en_US
dc.departmentDepartment of Chemistryen_US
dc.description.abstractA method for deposition of vanadium(V) oxo species on zirconia using different vanadium(V) precursor ions is described. The samples are synthesized by suspension of the support (powder) in solutions containing: (i) the dioxovanadium(V) ion, VO2+; (ii) the yellow diperoxo anion, [VO(O-O)2]- and (iii) the red monoperoxo cation, [VO(O-O)]+. The application of vanadium(V) peroxo complexes significantly increases the uptake of vanadium by zirconia. The state and localization of the VOx species on the surface of zirconia have been studied by FTIR, UV-Vis and XP spectroscopies. © 2001 Elsevier Science B.V.en_US
dc.identifier.doi10.1016/S0167-2738(01)00793-7en_US
dc.identifier.issn0167-2738
dc.identifier.urihttp://hdl.handle.net/11693/27612
dc.language.isoEnglishen_US
dc.publisherElsevieren_US
dc.relation.isversionofhttp://dx.doi.org/10.1016/S0167-2738(01)00793-7en_US
dc.source.titleSolid State Ionicsen_US
dc.subjectFTIRen_US
dc.subjectIon exchangeen_US
dc.subjectSynthesis from vanadium(V) oxo complexesen_US
dc.subjectUV-Visen_US
dc.subjectVOx/ZrO2en_US
dc.subjectXPSen_US
dc.titleSpectroscopic characterization of VOx/ZrO2 catalysts prepared using vanadium(V) oxo complexesen_US
dc.typeArticleen_US

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