Investigation of the hydrogen bond donating ability of 1,8-naphthalenediol by NMR spectroscopy and its use as a hydrogen bonding catalyst

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buir.contributor.authorTürkmen, Yunus Emre
dc.citation.epage1407en_US
dc.citation.issueNumber5en_US
dc.citation.spage1398en_US
dc.citation.volumeNumber42en_US
dc.contributor.authorTürkmen, Yunus Emreen_US
dc.date.accessioned2019-02-21T16:09:07Zen_US
dc.date.available2019-02-21T16:09:07Zen_US
dc.date.issued2018en_US
dc.departmentDepartment of Chemistryen_US
dc.departmentNanotechnology Research Center (NANOTAM)en_US
dc.departmentInstitute of Materials Science and Nanotechnology (UNAM)en_US
dc.description.abstractThe hydrogen bond donating ability of 1,8-naphthalenediol was investigated via a series of 1H, 13C, and 31P NMR experiments. Complexation studies using triphenylphosphine oxide and cyclohexanone as hydrogen bond acceptors revealed that 1,8-naphthalenediol is a more effective hydrogen bond donor compared to 1-naphthol and 8-methoxy-1-naphthol. Afterwards, its effectiveness as a hydrogen bonding catalyst was demonstrated in the Friedel-Crafts-type addition reaction of indole to trans-β-nitrostyrene.en_US
dc.description.provenanceMade available in DSpace on 2019-02-21T16:09:07Z (GMT). No. of bitstreams: 1 Bilkent-research-paper.pdf: 222869 bytes, checksum: 842af2b9bd649e7f548593affdbafbb3 (MD5) Previous issue date: 2018en_US
dc.identifier.doi10.3906/kim-1806-68en_US
dc.identifier.issn1300-0527en_US
dc.identifier.urihttp://hdl.handle.net/11693/50446en_US
dc.language.isoEnglishen_US
dc.publisherTUBITAKen_US
dc.relation.isversionofhttps://doi.org/10.3906/kim-1806-68en_US
dc.source.titleTurkish Journal of Chemistryen_US
dc.subject1,8-Naphthalenediolen_US
dc.subjectHydrogen bondingen_US
dc.subjectOrganocatalysisen_US
dc.subjectPhenolsen_US
dc.titleInvestigation of the hydrogen bond donating ability of 1,8-naphthalenediol by NMR spectroscopy and its use as a hydrogen bonding catalysten_US
dc.typeArticleen_US

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