NaCl-promoted CuO–RuO2/SiO2 catalysts for propylene epoxidation with O2 at atmospheric pressures: a combinatorial micro-reactor study

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dc.citation.epage605en_US
dc.citation.issueNumber2en_US
dc.citation.spage596en_US
dc.citation.volumeNumber145en_US
dc.contributor.authorKalyoncu, Ş.en_US
dc.contributor.authorDüzenli, D.en_US
dc.contributor.authorOnal, I.en_US
dc.contributor.authorSeubsai, A.en_US
dc.contributor.authorNoon, D.en_US
dc.contributor.authorSenkan, S.en_US
dc.contributor.authorSay, Z.en_US
dc.contributor.authorVovk, E. I.en_US
dc.contributor.authorOzensoy, E.en_US
dc.date.accessioned2016-02-08T10:01:06Z
dc.date.available2016-02-08T10:01:06Z
dc.date.issued2015en_US
dc.departmentDepartment of Chemistryen_US
dc.description.abstractA combinatorial approach is used to investigate several alkali metals promoted Cu–Ru binary oxide catalysts with improved catalytic performance in the propylene partial oxidation. 2 %Cu/5 %Ru/c–SiO2 catalyst had the best yield with high propylene conversion and propylene oxide (PO) selectivity. Among the promoters screening in the study, NaCl promotion significantly increased the PO selectivity accompanied by some attenuation in the total propylene conversion. It was proposed that binary oxide catalysts revealed a greater number of exposed catalytically active adsorption sites as compared to monometallic oxide counterparts according to XPS and FTIR results. Besides NaCl addition alters the structure, yielding a significantly improved PO selectivity without any change in the particle size of Cu and Ru oxide according to XRD analysis.en_US
dc.description.provenanceMade available in DSpace on 2016-02-08T10:01:06Z (GMT). No. of bitstreams: 1 bilkent-research-paper.pdf: 70227 bytes, checksum: 26e812c6f5156f83f0e77b261a471b5a (MD5) Previous issue date: 2015en
dc.identifier.doi10.1007/s10562-014-1454-7en_US
dc.identifier.eissn1572-879X
dc.identifier.issn1011-372X
dc.identifier.urihttp://hdl.handle.net/11693/22514
dc.language.isoEnglishen_US
dc.publisherSpringeren_US
dc.relation.isversionofhttp://dx.doi.org/10.1007/s10562-014-1454-7en_US
dc.source.titleCatalysis Lettersen_US
dc.subjectCuen_US
dc.subjectEpoxidationen_US
dc.subjectPropyleneen_US
dc.subjectRuen_US
dc.subjectSiO2en_US
dc.titleNaCl-promoted CuO–RuO2/SiO2 catalysts for propylene epoxidation with O2 at atmospheric pressures: a combinatorial micro-reactor studyen_US
dc.typeArticleen_US

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