Crystal structure of rac-3-hydroxy-2-(p-tolyl)-2,3,3a,4,7,7a-hexahydro-1H-4,7-methanoisoindol-1-one

Date

2015

Authors

Aslantaş, M.
Çelik, C.
Çelik Ö.
Karayel, A.
Stoeckli-Evans H.

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Source Title

Acta Crystallographica Section E: Structure Reports Online

Print ISSN

16005368

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International Union of Crystallography

Volume

71

Issue

3

Pages

o143 - o144

Language

English

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Abstract

In the title compound, C16H17NO2, the cyclohexene ring adopts a boat conformation, and the five-membered rings have envelope conformations with the bridging atom as the flap. Their mean planes are oriented at a dihedral angle of 86.51 (7)°. The molecular structure is stabilized by a short intramolecular C - H⋯O contact. In the crystal, molecules are linked by O - H⋯O hydrogen bonds forming chains propagating along [100]. The chains are linked by C - H⋯π interactions, forming slabs parallel to (001).

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