Electroinitiated polymerization of 2-chloroethylvinyl ether
Date
1998
Authors
Kalaycioglu, E.
Toppare L.
Yagci, Y.
Editor(s)
Advisor
Supervisor
Co-Advisor
Co-Supervisor
Instructor
Source Title
Designed Monomers and Polymers
Print ISSN
1385772X
Electronic ISSN
Publisher
Volume
1
Issue
2
Pages
245 - 250
Language
English
Type
Journal Title
Journal ISSN
Volume Title
Series
Abstract
The electroinitiated polymerization of 2-chloroethylvinyl ether via controlled potential conditions has been achieved. The kinetics of the polymerization were determined by cyclic voltammetry at different temperatures in dichloromethane (DM) and acetonitrile (AN). The post-polymerization kinetics were followed with a similar technique. It was found that polymerization was twice as fast in DM as in AN. In DM, both the polymerization and the post-polymerization rates increased with decreasing temperature, whereas in AN the reverse behavior was observed.