Characterization of different electrolyte composition Lithium Thionyl Chloride reserve battery by Electrochemical Impedance Spectroscopy

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buir.contributor.authorZabara, Mohammed Ahmed
buir.contributor.authorÜlgüt, Burak
buir.contributor.orcidZabara, Mohammed Ahmed|0000-0002-4195-6258
buir.contributor.orcidÜlgüt, Burak|0000-0002-4402-0033
dc.citation.epage7en_US
dc.citation.issueNumber5en_US
dc.citation.spage1en_US
dc.citation.volumeNumber168en_US
dc.contributor.authorZabara, Mohammed Ahmed
dc.contributor.authorGöçmez, Hasan
dc.contributor.authorKarabatak, Akın
dc.contributor.authorÜlgüt, Burak
dc.date.accessioned2022-02-07T12:02:01Z
dc.date.available2022-02-07T12:02:01Z
dc.date.issued2021-05-19
dc.departmentDepartment of Chemistryen_US
dc.description.abstractElectrochemical Impedance Spectroscopy (EIS) characterization for electrochemical processes in Lithium Thionyl Chloride reserve primary battery is shown. Two different electrolyte compositions are used to distinguish the changes in the EIS response. Galvanostatic EIS at discharge technique is used to obtain Kramers-Kronig compatible data for the reserve primary battery. The EIS data is analyzed by means of Equivalent Circuit models. The analysis shows the presence of five time-constants belonging to the electrochemical processes at Lithium anode, Solid Electrolyte Interface and the porous Carbon cathode. The change in the electrolyte composition causes the variation in the Solid Electrolyte Interface configuration and the kinetics of the Li anode processes. No variation in the cathode electrochemical processes observed by changing the electrolyte. The obtained results show the power of the non-destructive and in situ EIS technique to reveal the parameters for the electrochemical processes inside energy storage systems.en_US
dc.description.provenanceSubmitted by Türkan Cesur (cturkan@bilkent.edu.tr) on 2022-02-07T12:02:01Z No. of bitstreams: 1 Characterization_of_different_electrolyte_composition_Lithium_Thionyl_Chloride_reserve_battery_by_Electrochemical_Impedance_Spectroscopy.pdf: 1262831 bytes, checksum: ceaac4ebd942c45586127ac09211a95d (MD5)en
dc.description.provenanceMade available in DSpace on 2022-02-07T12:02:01Z (GMT). No. of bitstreams: 1 Characterization_of_different_electrolyte_composition_Lithium_Thionyl_Chloride_reserve_battery_by_Electrochemical_Impedance_Spectroscopy.pdf: 1262831 bytes, checksum: ceaac4ebd942c45586127ac09211a95d (MD5) Previous issue date: 2021-05-19en
dc.identifier.doi10.1149/1945-7111/abff61en_US
dc.identifier.eissn1945-7111
dc.identifier.issn0013-4651
dc.identifier.urihttp://hdl.handle.net/11693/77118
dc.language.isoEnglishen_US
dc.publisherElectrochemical Society, Inc.en_US
dc.relation.isversionofhttps://doi.org/10.1149/1945-7111/abff61en_US
dc.source.titleJournal of The Electrochemical Societyen_US
dc.titleCharacterization of different electrolyte composition Lithium Thionyl Chloride reserve battery by Electrochemical Impedance Spectroscopyen_US
dc.typeArticleen_US

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