Colloidal quantum dot light-emitting diodes employing phosphorescent small organic molecules as efficient exciton harvesters
Date
2014
Advisor
Instructor
Source Title
Journal of Physical Chemistry Letters
Print ISSN
1948-7185
Electronic ISSN
1948-7185
Publisher
American Chemical Society
Volume
5
Issue
16
Pages
2802 - 2807
Language
English
Type
Article
Journal Title
Journal ISSN
Volume Title
Abstract
Nonradiative energy transfer (NRET) is an alternative excitation mechanism in colloidal quantum dot (QD) based electroluminescent devices (QLEDs). Here, we develop hybrid highly spectrally pure QLEDs that facilitate energy transfer pumping via NRET from a phosphorescent small organic molecule-codoped charge transport layer to the adjacent QDs. A partially codoped exciton funnelling electron transport layer is proposed and optimized for enhanced QLED performance while exhibiting very high color purity of 99%. These energy transfer pumped hybrid QLEDs demonstrate a 6-fold enhancement factor in the external quantum efficiency over the conventional QLED structure, in which energy transfer pumping is intrinsically weak.
Course
Other identifiers
Book Title
Keywords
Electroluminescence, Excitons, Light emission, Light emitting diodes, Molecules, Optoelectronic devices, Phosphorescence, Semiconductor quantum dots, Colloidal quantum dots, Hybrid light-emitting diodes, Nonradiative energy transfer, Phosphorescent molecules, Triplet state, Energy transfer