Covalent self-assembly of an energy cascade in one step

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buir.advisorAkkaya, Engin U.
dc.contributor.authorÇamur, Ceren
dc.date.accessioned2016-05-02T10:25:51Z
dc.date.available2016-05-02T10:25:51Z
dc.date.copyright2015-08
dc.date.issued2015-08
dc.date.submitted15-09-2015
dc.descriptionCataloged from PDF version of thesis.en_US
dc.descriptionIncludes bibliographical references (leaves 52-61).en_US
dc.descriptionThesis (Master's): Bilkent University, Department of Chemistry, İhsan Doğramacı Bilkent University, 2015.en_US
dc.description.abstractLight harvesting mechanisms include absorption of energy by donor and transfer of the absorbed energy to acceptor. The aim of this process is the channeling of the light at certain wavelength. In this study, energy transfer process was sustained by BODIPY based Förster type light harvesting cascade. The donor and acceptor units of the cascade were synthesized to be combined by self-assembly. Passerini reaction was used in the assembly of the three units. Designed molecule consists of three moieties: BODIPY, monostyryl- BODIPY and distyryl-BODIPY. The expected process of energy transfer starts with the absorption of light at around 502 nm and ends with the emission at around 674 nm. The spectral overlap between donors and acceptors were shown. Under the light of the results, the designed molecule is promising to work as an effective energy transfer cascade.en_US
dc.description.provenanceSubmitted by Betül Özen (ozen@bilkent.edu.tr) on 2016-05-02T10:25:51Z No. of bitstreams: 1 CerenCamurTez.pdf: 3984711 bytes, checksum: bc8d933ef04f6a15d6ce3306f026df86 (MD5)en
dc.description.provenanceMade available in DSpace on 2016-05-02T10:25:51Z (GMT). No. of bitstreams: 1 CerenCamurTez.pdf: 3984711 bytes, checksum: bc8d933ef04f6a15d6ce3306f026df86 (MD5) Previous issue date: 2015-08en
dc.description.statementofresponsibilityby Ceren Çamur.en_US
dc.embargo.release2017-09-14
dc.format.extentxii, 89 leaves : illustrations, charts.en_US
dc.identifier.itemidB151300
dc.identifier.urihttp://hdl.handle.net/11693/29029
dc.language.isoEnglishen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subjectBoradiazaindaceneen_US
dc.subjectFörster type energy transferen_US
dc.subjectEnergy transfer cascadeen_US
dc.subjectStyryl BODIPYen_US
dc.subjectPasserini reactionen_US
dc.titleCovalent self-assembly of an energy cascade in one stepen_US
dc.title.alternativeTek adımda kovalent bağlarla kendiliğinden bir araya gelen enerji transferi sistemien_US
dc.typeThesisen_US
thesis.degree.disciplineChemistry
thesis.degree.grantorBilkent University
thesis.degree.levelMaster's
thesis.degree.nameMS (Master of Science)

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