A new lyotropic liquid crystalline system: oligo(ethylene oxide) surfactants with [M(H2O)n]Xm transition metal complexes

dc.citation.epage3803en_US
dc.citation.issueNumber20en_US
dc.citation.spage3800en_US
dc.citation.volumeNumber40en_US
dc.contributor.authorÇelik, Ö.en_US
dc.contributor.authorDag, Ö.en_US
dc.date.accessioned2016-02-08T10:34:29Z
dc.date.available2016-02-08T10:34:29Z
dc.date.issued2001en_US
dc.departmentDepartment of Chemistryen_US
dc.description.abstractCoordinated water molecules induce the aggregation and self-assembly of the lyotropic liquid crystalline phase formed from non-ionic surfactants CnH2n+1(CH2CH2O)mOH and transition metal aqua complexes ([Ni(H2O)6](NO3)2, [Co(H2O)6](NO3)2, [Cd(H2O)4](NO3)2, and [Co(H2O)6]Cl2) into hexagonal (see schematic representation) and/or cubic structures. While the NiII and CoII complexes undergo recrystallization and phase separation at high complex concentrations, the ZnII and CdII complexes form cubic phases above metal/surfactant molar ratios of 3.2/1 at room temperature.en_US
dc.description.provenanceMade available in DSpace on 2016-02-08T10:34:29Z (GMT). No. of bitstreams: 1 bilkent-research-paper.pdf: 70227 bytes, checksum: 26e812c6f5156f83f0e77b261a471b5a (MD5) Previous issue date: 2001en
dc.identifier.doi10.1002/1521-3773(20011015)40:20<3799::AID-ANIE3799>3.0.CO;2-Ien_US
dc.identifier.issn1433-7851
dc.identifier.urihttp://hdl.handle.net/11693/24798
dc.language.isoEnglishen_US
dc.publisherWileyen_US
dc.relation.isversionofhttps://doi.org/10.1002/1521-3773(20011015)40:20<3799::AID-ANIE3799>3.0.CO;2-Ien_US
dc.source.titleAngewandte Chemie - International Editionen_US
dc.subjectLiquid crystalsen_US
dc.subjectMesophasesen_US
dc.subjectNanostructuresen_US
dc.subjectSurfactantsen_US
dc.subjectTransition metalsen_US
dc.subjectAgglomerationen_US
dc.subjectCrystallizationen_US
dc.subjectMoleculesen_US
dc.subjectPhase separationen_US
dc.subjectSelf assemblyen_US
dc.subjectSurface active agentsen_US
dc.subjectWater moleculesen_US
dc.titleA new lyotropic liquid crystalline system: oligo(ethylene oxide) surfactants with [M(H2O)n]Xm transition metal complexesen_US
dc.typeArticleen_US

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