A new lyotropic liquid crystalline system: oligo(ethylene oxide) surfactants with [M(H2O)n]Xm transition metal complexes
dc.citation.epage | 3803 | en_US |
dc.citation.issueNumber | 20 | en_US |
dc.citation.spage | 3800 | en_US |
dc.citation.volumeNumber | 40 | en_US |
dc.contributor.author | Çelik, Ö. | en_US |
dc.contributor.author | Dag, Ö. | en_US |
dc.date.accessioned | 2016-02-08T10:34:29Z | |
dc.date.available | 2016-02-08T10:34:29Z | |
dc.date.issued | 2001 | en_US |
dc.department | Department of Chemistry | en_US |
dc.description.abstract | Coordinated water molecules induce the aggregation and self-assembly of the lyotropic liquid crystalline phase formed from non-ionic surfactants CnH2n+1(CH2CH2O)mOH and transition metal aqua complexes ([Ni(H2O)6](NO3)2, [Co(H2O)6](NO3)2, [Cd(H2O)4](NO3)2, and [Co(H2O)6]Cl2) into hexagonal (see schematic representation) and/or cubic structures. While the NiII and CoII complexes undergo recrystallization and phase separation at high complex concentrations, the ZnII and CdII complexes form cubic phases above metal/surfactant molar ratios of 3.2/1 at room temperature. | en_US |
dc.description.provenance | Made available in DSpace on 2016-02-08T10:34:29Z (GMT). No. of bitstreams: 1 bilkent-research-paper.pdf: 70227 bytes, checksum: 26e812c6f5156f83f0e77b261a471b5a (MD5) Previous issue date: 2001 | en |
dc.identifier.doi | 10.1002/1521-3773(20011015)40:20<3799::AID-ANIE3799>3.0.CO;2-I | en_US |
dc.identifier.issn | 1433-7851 | |
dc.identifier.uri | http://hdl.handle.net/11693/24798 | |
dc.language.iso | English | en_US |
dc.publisher | Wiley | en_US |
dc.relation.isversionof | https://doi.org/10.1002/1521-3773(20011015)40:20<3799::AID-ANIE3799>3.0.CO;2-I | en_US |
dc.source.title | Angewandte Chemie - International Edition | en_US |
dc.subject | Liquid crystals | en_US |
dc.subject | Mesophases | en_US |
dc.subject | Nanostructures | en_US |
dc.subject | Surfactants | en_US |
dc.subject | Transition metals | en_US |
dc.subject | Agglomeration | en_US |
dc.subject | Crystallization | en_US |
dc.subject | Molecules | en_US |
dc.subject | Phase separation | en_US |
dc.subject | Self assembly | en_US |
dc.subject | Surface active agents | en_US |
dc.subject | Water molecules | en_US |
dc.title | A new lyotropic liquid crystalline system: oligo(ethylene oxide) surfactants with [M(H2O)n]Xm transition metal complexes | en_US |
dc.type | Article | en_US |
Files
Original bundle
1 - 1 of 1
Loading...
- Name:
- A new lyotropic liquid crystalline system Oligo(ethylene oxide) surfactants with [M(H2O)n]Xm transition metal complexes.pdf
- Size:
- 412.21 KB
- Format:
- Adobe Portable Document Format
- Description:
- Full printable version