Browsing by Subject "Solar Cell"

Now showing 1 - 3 of 3

Open Access
Investigation of lithium salt-nonionic surfactant mesophases and their applications in solar cells as gel electrolyte
(2013) Barım, Gözde
Some salts and some nonionic surfactants self-assemble together into lyotropic liquid crystalline (LLC) mesophases. The salt can be either in aqueous solution phase or in its molten phase in the self-assembly process. Concentrated aqueous solutions of lithium salts (LiCl, LiBr, or LiI) and pluronics (triblock copolymers, such as P65, P85, P103, or P123) or 10-lauryl ether (C12H25(CH2CH2O)10OH, denoted as C12EO10) type nonionic surfactant mesophases were investigated in this thesis work. The LLC mesophases are well ordered between 5.0 and 25.0 salt/pluronics and 2.0 and 10.0 salt/C12EO10 mole ratios, and remain stable for months under the ambient conditions. The water molecules remain as the hydrates under open atmosphere in the LLC mesophases of lithium salts-nonionic surfactants. The lithium salt-pluronic LLC mesophases are birefringent and have a hexagonal mesophase in a broad range of salt concentrations. The unit cell of the mesophases increases and a transition from the hexagonal to a cubic mesophases occurs upon increasing the salt content of the media. Moreover the LLC mesophases are ordered and stable up to 25.0 salt to pluronic mole ratio. At higher salt content, one can observe either a disordered phase or co-existence of salt crystals and mesophase. There is a big demand on the gel electrolytes for dye sensitized solar cells (DSSC) in order to overcome solvent problems caused by liquid electrolytes. The LLC mesophases of LiI, LiCl and LiBr salts with 10-lauryl ether (C12EO10) has been considered as gel-electrolyte for the DSSC. We demonstrate that the LiI/I2 couple can be incorporated into above LLC mesophases of various lithium salt-nonionic surfactant systems. Those LLC phases, with LiI/I2 couple have been characterized by means of diffraction, microscopy, spectroscopy and conductivity measurements. The LLC mesophases diffract at small angles and do not show any phase segregation upon incorporating the LiI/I2 redox couple. The LLC mesophases of these systems are 2D hexagonal, and they remain stable under ambient conditions for months. In the LLC media, the iodide ion and iodine molecule react to produce triodide ion in the media. The iodide/triodide (I- /I3 - ) redox couples containing gel electrolytes were formed and their solar performance was investigated by using a solar simulator and a cell consisting of a dye sensitized anode (FTO-dye modified TiO2), gel-electrolyte, and a cathode (FTO-Pt nanoparticles). The LLC mesophases of various lithium saltnonionic surfactant systems with the I- /I3 - redox couple were characterized using POM (Polarized Optical Microscope), XRD (X-ray Diffraction), FT-IR (Fourier Transform Infrared Spectroscopy) and Raman techniques. These new LLC mesophases can be used as gel electrolytes in solar cells after incorporation of redox couple into the media and display responses as good as commonly used liquid electrolytes.
Open Access
The left hand of electromagnetism : metamaterials
(2010) Alıcı, Kamil Boratay
Metamaterials are artificial periodic structures whose electromagnetic response is solely dependent on the constituting unit cells. In the present thesis, we studied unit cell characteristics of metamaterials that has negative permeability and permittivity. We investigated negative permeability medium elements, especially in terms of their electrical size and resonance strength. Experimental and numerical study of µ-negative (MNG) materials: multi split ring resonators (MSRRs), spiral resonators (SRs) and multi-spiral resonators are presented. The resonance frequency of the structures is determined by the transmission measurements and minimum electrical size of λ0/17 for the MSRRs and of λ0/82 for the SRs observed. We explain a method for tuning the resonance frequency of the multi-split structures. We investigated scalability of MNG materials and designed a low loss double negative composite metamaterial that operates at the millimeter wave regime. A negative pass-band with a peak transmission value of -2.7 dB was obtained experimentally at 100 GHz. We performed transmission based qualitative effective medium theory analysis numerically and experimentally, in order to prove the double negative nature of the metamaterial. These results were supported by the standard retrieval analysis method. We confirmed that the effective index of the metamaterial was indeed negative by performing far field angular scanning measurements for a metamaterial prism. Moreover, we illuminated the split-ring resonator based metamaterial flat lens with oblique incidence and observed from the scanning experiments, the shifting of the beam to the negative side. The first device was a horn antenna and metamaterial lens composite whose behavior was similar to Yagi-Uda antenna. We numerically and experimentally investigated planar fishnet metamaterials operating at around 20 GHz and 100 GHz and demonstrated that their effective index is negative. The study is extended to include the response of the metamaterial layer when the metamaterial plane normal and the propagation vector are not parallel. We also experimentally studied the transmission response of a one dimensional rectangle prism shaped metamaterial slab for oblique incidence angles and confirmed the insensitivity of split-ring resonator based metamaterials to the angle of incidence. After the demonstration of complete transmission enhancement by using deep subwavelength resonators into periodically arranged subwavelength apertures, we designed and implemented a metamaterial with controllable bandwidth. The metamaterial based devices can be listed under the categories of antennas absorbers and transmission enhancement. We studied electrically small resonant antennas composed of split ring resonators (SRR) and monopoles. The electrical size, gain and efficiency of the antenna were λ0/10, 2.38 and 43.6%, respectively. When we increased the number of SRRs in one dimension, we observed beam steerability property. These achievements provide a way to create rather small steerable resonant antennas. We also demonstrated an electrically small antenna that operates at two modes for two perpendicular polarizations. The antenna was single fed and composed of perpendicularly placed metamaterial elements and a monopole. One of the metamaterial elements was a multi split ring resonator and the other one was a split ring resonator. When the antenna operates for the MSRR mode at 4.72 GHz for one polarization, it simultaneously operates for the SRR mode at 5.76 GHz, but for the perpendicular polarization. The efficiencies of the modes were 15% and 40% with electrical sizes of λ/11.2 and λ/9.5. Finally, we experimentally verified a miniaturization method of circular patch antennas. By loading the space between the patch and ground plane with metamaterial media composed of multi-split ring resonators and spiral resonators, we manufactured two electrically small patch antennas of electrical sizes λ/3.69 and λ/8.26. The antenna efficiency was 40% for the first mode of the multi-split ring resonator antenna with broad far field radiation patterns similar to regular patch antennas. We designed, implemented, and experimentally characterized electrically thin microwave absorbers by using the metamaterial concept. The absorbers consist of i) a metal back plate and an artificial magnetic material layer; ii) metamaterial back plate and a resistive sheet layer. We investigated absorber performance in terms of absorbance, fractional bandwidth and electrical thickness, all of which depend on the dimensions of the metamaterial unit cell and the distance between the back plate and metamaterial layer. As a proof of concept, we demonstrated a λ/4.7 thick absorber of type i), with a 99.8% absorption peak along with a 8% fractional bandwidth. We have also demonstrated experimentally a λ/4.7 and a λ/4.2 thick absorbers of type ii), based on SRR and MSRR magnetic metamaterial back plates, respectively. The absorption peak of the SRR layout is 97.4%, while for the MSRR one the absorption peak is 98.4%. We conveyed these concepts to optical frequencies and demonstrated a metamaterial inspired absorber for solar cell applications. We finalized the study by a detailed study of split ring resonators at the infrared and visible band. We studied i) frequency tuning, ii) effect of resonator density, iii) shifting magnetic resonance frequency by changing the resonator shape, iv) effect of metal loss and plasma frequency and designed a configuration for transmission enhancement at the optical regime. By using subwavelength optical split ring resonator antennas and couplers we achieved a 400-fold enhanced transmission from a subwavelength aperture area of the electrical size λ2 /25. The power was transmitted to the far field with 3.9 dBi directivity at 300 THz.
Open Access
Molten-Salt-Asisted self-Assembly (MASA)-synthesis of mesoporous metal titanate-titania, metal sulfi de-titania, and metal selenide-titania thin films
(Wiley Online Library, 2013) Karakaya, C.; Turker, Y.; Dag, Ö.
New synthetic strategies are needed for the assembly of porous metal titanates and metal chalcogenite-titania thin films for various energy applications. Here, a new synthetic approach is introduced in which two solvents and two surfactants are used. Both surfactants are necessary to accommodate the desired amount of salt species in the hydrophilic domains of the mesophase. The process is called a molten-salt-assisted self-assembly (MASA) because the salt species are in the molten phase and act as a solvent to assemble the ingredients into a mesostructure and they react with titania to form mesoporous metal titanates during the annealing step. The mesoporous metal titanate (meso-Zn2TiO4 and meso-CdTiO3) thin films are reacted under H2S or H2Se gas at room temperature to yield high quality transparent mesoporous metal chalcogenides. The H2Se reaction produces rutile and brookite titania phases together with nanocrystalline metal selenides and H2S reaction of meso-CdTiO3 yields nanocrystalline anatase and CdS in the spatially confined pore walls. Two different metal salts (zinc nitrate hexahydrate and cadmium nitrate tetrahydrate) are tested to demonstrate the generality of the new assembly process. The meso-TiO2-CdSe film shows photoactivity under sunlight.