Browsing by Subject "Phase-change materials"
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Item Open Access Adaptive thermal camouflage using sub-wavelength phase-change metasurfaces(Institute of Physics Publishing Ltd., 2022-12-09) Omam, Zahra Rahimian; Ghobadi, Amir; Özbay, Ekmel; Khalichi, BahramSub-wavelength metasurface designs can be used to artificially engineer the spectral thermal signature of an object. The real-time control of this emission can provide the opportunity to switch between radiative cooling (RC) and thermal camouflage functionalities. This performance could be achieved by using phase-change materials (PCMs). This paper presents a sub-wavelength dynamic metasurface design with the adaptive property. The proposed metasurface is made of vanadium dioxide (VO2) nanogratings on a silver (Ag) substrate. The design geometries are optimized in a way that both narrowband and broadband mid-infrared (MIR) emitters can be realized. At low temperatures, insulating VO2 nanogratings trigger the excitation of Fabry–Perot mode inside the grating and surface plasmon polaritons at the metal–dielectric interface with an emission peak located in the MIR region to maximize the RC performance of the design. As temperature rises, the PCM transforms into a metallic phase material and supports excitation of Wood's anomaly and localized surface plasmon resonance modes. Accordingly, the thermal signature is adaptively suppressed.Item Open Access Thermal conductivity and phase-change properties of boron nitride–lead oxide nanoparticle-doped polymer nanocomposites(MDPI AG, 2023-05-16) Ortaç, Bülend; Mutlu, Saliha; Baskan, T.; Savaşkan Yılmaz, Sevil; Yilmaz, A. H.; Erol, B.Thermally conductive phase-change materials (PCMs) were produced using the crosslinked Poly (Styrene-block-Ethylene Glycol Di Methyl Methacrylate) (PS-PEG DM) copolymer by employing boron nitride (BN)/lead oxide (PbO) nanoparticles. Differential Scanning Calorimetry (DSC) and Thermogravimetric Analysis (TGA) methods were used to research the phase transition temperatures, the phase-change enthalpies (melting enthalpy (ΔHm), and crystallization enthalpies (ΔHc)). The thermal conductivities (λ) of the PS-PEG/BN/PbO PCM nanocomposites were investigated. The λ value of PS-PEG/BN/PbO PCM nanocomposite containing BN 13 wt%, PbO 60.90 wt%, and PS-PEG 26.10 wt% was determined to be 18.874 W/(mK). The crystallization fraction (Fc) values of PS-PEG (1000), PS-PEG (1500), and PS-PEG (10,000) copolymers were 0.032, 0.034, and 0.063, respectively. XRD results of the PCM nanocomposites showed that the sharp diffraction peaks at 17.00 and 25.28 °C of the PS-PEG copolymer belonged to the PEG part. Since the PS-PEG/PbO and the PS-PEG/PbO/BN nanocomposites show remarkable thermal conductivity performance, they can be used as conductive polymer nanocomposites for effective heat dissipation in heat exchangers, power electronics, electric motors, generators, communication, and lighting equipment. At the same time, according to our results, PCM nanocomposites can be considered as heat storage materials in energy storage systems.