Browsing by Subject "Organic lasers"

Now showing 1 - 5 of 5

Open Access
Bio-insprired optoelectronic digital nose for breath analysis
(2011) Bayındır, Mehmet; Yıldırım, Adem; Yaman, Mecit; Vural, Mert
A novel electronic nose device is presented that can be used in disease diagnostics by exhaled breath analysis. Exhaled breath contains more than a thousand organic compounds that can be analysed to insect various diseases and metabolic activity. The novel device is an electronic nose, based on photonic bandgap fibers that can selectively guide infrared radition inside a hollow core plastic fiber. Instead of a laser line source, a broadband balackbody source is used that exploits the filtering/ guiding properties of the fibers to scan the whole mid-infrared region, making it high selectivity of volatile organic compounds possible. In addition waveguiding inside the fiber enhances the electromagnetic radiation intensity, resulting in improved infrared absorption cross-section. The fiber electronic nose can be integrated and deployed as a portable electronics device to point-of-care institutes.
Open Access
Generation of ultra-small InN nanocrystals by pulsed laser ablation of suspension in organic solution
(Springer Verlag, 2017-03) Kurşungöz, C.; U. Şimşek, E.; Tuzaklı, R.; Ortaç, B.
Nanostructures of InN have been extensively investigated since nano-size provides a number of advantages allowing applications in nanoscale electronic and optoelectronic devices. It is quite important to obtain pure InN nanocrystals (InN-NCs) to reveal the characteristic features, which gain interest in the literature. Here, we proposed a new approach for the synthesis of ultra-small hexagonal InN-NCs by using suspension of micron-sized InN powder in ethanol with pulsed laser ablation method. The liquid environment, laser energy and ablation time were optimized and a post-synthesis treatment, centrifugation, was performed to achieve InN-NCs with the smallest size. Besides, the micron-sized InN powder suspension, as a starting material, enabled us to obtain InN-NCs having diameters smaller than 5 nm. We also presented a detailed characterization of InN-NCs and demonstrated that the formation mechanism mainly depends on the fragmentation due to laser irradiation of the suspension.
Open Access
Synthesis of blue-shifted luminescent colloidal GaN nanocrystals through femtosecond pulsed laser ablation in organic solution
(Springer Netherlands, 2016-05) Demirel, A.; Öztaş T.; Kurşungöz, C.; Yılmaz, İ.; Ortaç, B.
We demonstrate the synthesis of GaN nanocrystals (NCs) with the sizes of less than the doubled exciton Bohr radius leading quantum confinement effects via a single-step technique. The generation of colloidal GaN nanoparticles (NPs) in organic solution through nanosecond (ns) and femtosecond (fs) pulsed laser ablation (PLA) of GaN powder was carried out. Ns PLA in ethanol and polymer matrix resulted in amorphous GaN-NPs with the size distribution of 12.4 ± 7.0 and 6.4 ± 2.3 nm, respectively, whereas fs PLA in ethanol produced colloidal GaN-NCs with spherical shape within 4.2 ± 1.9 nm particle size distribution. XRD and selected area electron diffraction analysis of the product via fs PLA revealed that GaN-NCs are in wurtzite structure. Moreover, X-ray photoelectron spectroscopy measurements also confirm the presence of GaN nanomaterials. The colloidal GaN-NCs solution exhibits strong blue shift in the absorption spectrum compared to that of the GaN-NPs via ns PLA in ethanol. Furthermore, the photoluminescence emission behavior of fs PLA-generated GaN-NCs in the 295–400 nm wavelength range is observed with a peak position located at 305 nm showing a strong blue shift with respect to the bulk GaN.
Open Access
Terahertz time-domain study of silver nanoparticles synthesized by laser ablation in organic liquid
(IEEE Microwave Theory and Techniques Society, 2016-07) Koral, C.; Ortaç, B.; Altan, H.
We report the investigation of laser-synthesized Ag nanoparticles (Ag-NPs) in an organic liquid environment by using terahertz time-domain spectroscopy (THz-TDS) technique. Colloidal Ag-NPs with an average diameter of 10 nm in two-propanol solution through nanosecond pulsed laser ablation were synthesized. THz-TDS measurements were performed on different volumetric concentration of Ag-NPs suspensions placed in 2-mm path length quartz cuvette. Due to the dispersive and highly absorptive nature of the nano liquids, an approach based on extracting the optical properties through the changes in amplitude and phase solely around the main peak of THz waveform is developed. This approach allowed for an accurate estimation of the complex refractive index of the Metallic-NPs suspension for the different prepared volumetric concentrations. In addition, using Maxwell-Garnett theory, the NP concentration is also extracted. This method shows that the time-domain nature of the THz pulse measurement technique is extremely useful in instances where slight variations in highly dispersive samples need to be investigated.
Open Access
Ultralow-threshold up-converted lasing in oligofluorenes with tailored strong nonlinear absorption
(Royal Society of Chemistry, 2015) Guzelturk, B.; Kanibolotsky, A.L.; Orofino-Pena, C.; Laurand, N.; Dawson, M.D.; Skabara P.J.; Demir, Hilmi Volkan
Nonlinear optical response in organic semiconductors has been an attractive property for many practical applications. For frequency up-converted lasers, to date, conjugated polymers, fluorescent dyes and small organic molecules have been proposed but their performances have been severely limited due to the difficulty in simultaneously achieving strong nonlinear optical response and high performance optical gain. In this work, we show that structurally designed truxene-based star-shaped oligofluorenes exhibit strong structure-property relationships enabling enhanced nonlinear optical response with favorable optical gain performance. As the number of fluorene repeat units in each arm is increased from 3 to 6, these molecules demonstrate a two-photon absorption cross-section as high as 2200 GM, which is comparable to that of linear conjugated polymers. Tailored truxene oligomers with six fluorene units in each arm (T6) show two-photon absorption pumped amplified spontaneous emission with a threshold as low as 2.43 mJ cm-2, which is better than that of the lowest reported threshold in organic semiconductors. Furthermore, we show a frequency up-converted laser using the newly designed and synthesized star-shaped oligomer T6 with a threshold as low as 3.1 mJ cm-2, which is more than an order of magnitude lower than that of any conjugated polymer. Thus, these oligomers with enhanced nonlinear optical properties are highly attractive for bio-integrated applications such as photodynamic therapy and in vivo bio-sensing. © The Royal Society of Chemistry 2015.