Browsing by Subject "Experimental conditions"

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Open Access
Experimental conditions for the excitation of thin disk whispering-gallery-mode resonators
(Electromagnetics Academy, 2013) Yurchenko, V. B.; Altintas, A.; Ciydem, M.; Koc, S.
Measurements of mm-wave excitation spectra of highorder whispering gallery modes in free-space cylindrical disk resonators as functions of resonator thickness have been made. Resonators in the form of tight stacks of thin dielectric disks excited via dielectric waveguides have been used in the experiment. Experimental conditions for the excitation of thin-disk resonators have been found. A simple approach for the modeling of resonator spectra and recovery of dielectric parameters has been proposed.
Open Access
A microfluidic erythrocyte sedimentation rate analyzer using rouleaux formation kinetics
(Springer Verlag, 2017-03) Isiksacan, Z.; Asghari, M.; Elbuken, C.
Red blood cell aggregation is an intrinsic property of red blood cells that form reversible stacked structures, also called rouleaux, under low shear rates. Erythrocyte sedimentation rate (ESR), commonly performed in clinics, is an indirect inflammation screener and a prognostic test for diseases. We have recently developed a microfluidic system for rapid measurement of ESR from 40 µl whole blood employing the aggregation dynamics. In this work, we propose the use of an aggregation inducer, dextran polyglucose, for the preparation of multiple blood samples with differing aggregation dynamics. Using these samples, we characterized the performance of the system with three aggregation indices and under varying experimental conditions. Additionally, using the same underlying principle, we improved the system for ESR measurement using both venipuncture and fingerprick whole blood samples depending on the user needs. The results demonstrate that the system performs equally well with both samples, which validates the compatibility of the system for both laboratory and point-of-care applications where venous and capillary blood are the primary samples, respectively. The detailed characterization presented in this study legitimates the feasibility of the system for ultrafast and facile measurement of ESR in clinics and diverse off-laboratory settings.
Open Access
Selective catalytic ammonia oxidation to nitrogen by atomic oxygen species on Ag (111)
(American Chemical Society, 2017) Karatok, M.; Vovk, E. I.; Koc, A. V.; Ozensoy, E.
Ammonia-selective catalytic oxidation was studied on the planar Ag(111) single-crystal model catalyst surface under ultra-high-vacuum (UHV) conditions. A variety of oxygen species were prepared via ozone decomposition on pristine Ag(111). Surface coverages of oxygen species were quantified by temperature-programmed desorption (TPD) and X-ray photoemission spectroscopy techniques. Exposure of ozone on Ag(111) at 140 K led to a surface atomic oxygen (Oa) overlayer. Low-energy electron diffraction experiments revealed that annealing of this atomic oxygen-covered Ag(111) surface at 473 K in UHV resulted in the formation of ordered oxide surfaces (Oox) with p(5×1) or c(4×8) surface structures. Ammonia interactions with O/Ag(111) surfaces monitored by temperature-programmed reaction spectroscopy indicated that disordered surface atomic oxygen selectively catalyzed N-H bond cleavage, yielding mostly N2 along with minor amounts of NO and N2O. Higher coverage O/Ag(111) surfaces, whose structure was tentatively assigned to a bulklike amorphous silver oxide (Obulk), showed high selectivity toward N2O formation (rather than N2) due to its augmented oxygen density. In contrast, ordered surface oxide overlayers on Ag(111) (where the order was achieved by annealing the oxygen adlayer to 473 K) showed only very limited reactivity toward ammonia. The nature of the adsorbed NH3 species on a clean Ag(111) surface and its desorption characteristics were also investigated via infrared reflection absorption spectroscopy and TPD techniques. Current findings demonstrate that the Ag(111) surface can selectively oxidize NH3 to N2 under well-defined experimental conditions without generating significant quantities of environmentally toxic species such as NO2, NO, or N2O.