Browsing by Subject "Energy gradients"
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Item Open Access Förster resonance energy transfer enhanced color-conversion using colloidal semiconductor quantum dots for solid state lighting(American Institute of Physics, 2009-10-15) Nizamoglu, S.; Demir, Hilmi VolkanIn this paper, we present Förster resonance energy transfer (FRET)-enhanced color-conversion using colloidal semiconductor quantum dot nanocrystals (NCs) to make reddish-orange light-emitting diodes for use in ultraefficient solid state lighting. To achieve FRET enhancement at 614 nm, we use an energy gradient hybrid structure made of cyan- and orange-emitting CdSe/ZnS NCs (λPL =492 and 588 nm in solution, respectively). This enables recycling of trapped excitons using FRET and achieves a relative quantum efficiency enhancement of 15.1% in reddish-orange full color-conversion for the integrated hybrid cyan-orange NC layer with respect to the case of full color-conversion using only orange NCs without FRET.Item Open Access Towards unimolecular luminescent solar concentrators: bodipy-based dendritic energy-transfer cascade with panchromatic absorption and monochromatized emission(2011) Bozdemir, O. A.; Erbas-Cakmak, S.; Ekiz, O. O.; Dana, A.; Akkaya, E. U.A polymer-embedded dendritic, bodipy-based panchromatic absorber with a built-in energy gradient concentrates incident solar radiation at a terminal chromophore, resulting in a monochromatized emission directed to the sides of the polymer waveguide (see picture). This particular design minimizes self-absorption losses from the peripheral antenna units with an impressive S factor of 10 000.