Browsing by Subject "Core/shell"

Now showing 1 - 5 of 5

Open Access
Blue-and red-shifting amplified spontaneous emission of CdSe/CdS core/shell colloidal quantum dots
(IEEE, 2013) Kelestemur, Yusuf; Cihan, Ahmet Fatih; Güzeltürk, Burak; Yerli, Ozan; Kurum, U.; Yaglioglu H.G.; Elmali, A.; Demir, Hilmi Volkan
We report blue- and red-shifting amplified spontaneous emission of CdSe/CdS quantum dots, controlled by varying core/shell dimensions and modifying exciton-exciton interactions, with low optical gain threshold of two-photon absorption pumping. © 2013 The Optical Society.
Open Access
High-efficiency CdTe/CdS core/shell nanocrystals in water enabled by photo-induced colloidal hetero-epitaxy of CdS shelling at room temperature
(Tsinghua University Press, 2015) Zare, H.; Marandi, M.; Fardindoost, S.; Sharma, V.K.; Yeltik A.; Akhavan, O.; Demir, Hilmi Volkan; Taghavinia, N.
We report high-efficiency CdTe/CdS core/shell nanocrystals synthesized in water by epitaxially growing CdS shells on aqueous CdTe cores at room temperature, enabled by the controlled release of S species under low-intensity ultraviolet (UV) light illumination. The resulting photo-induced dissociation of S2O32− ions conveniently triggers the formation of critical two-dimensional CdS epitaxy on the CdTe surface at room temperature, as opposed to initiating the growth of individual CdS core-only nanocrystals. This controlled colloidal hetero-epitaxy leads to a substantial increase in the photoluminescence (PL) quantum yield (QY) of the shelled nanocrystals in water (reaching 64%). With a systematic set of studies, the maximum PL QY is found to be almost independent of the illuminating UV intensity, while the shell formation kinetics required for reaching the maximum QY linearly depends on the illuminating UV intensity. A stability study of the QD films in air at various temperatures shows highly improved thermal stability of the shelled QDs (up to 120 °C in ambient air). These results indicate that the proposed aqueous CdTe/CdS core/shell nanocrystals hold great promise for applications requiring efficiency and stability. [Figure not available: see fulltext.] © 2015, Tsinghua University Press and Springer-Verlag Berlin Heidelberg.
Open Access
Magneto-optical studies of CdSe/CdMnS/CdS core/multi-shell colloidal nanoplatelets
(SPIE, 2016) Petrou, A.; Scrace, T. A.; Murphy, J. R.; Zhang, P.; Norden, T.; Zhang, T.; Thomay, T.; Cartwright, A. N.; Delikanlı, Savaş; Akgül, Mehmet Zafer; Demir, Hilmi Volkan
We studied the photoluminescence (PL)) from CdSe/CdMnS/CdS core/multi-shell colloidal nanoplatelets, a versatile platform to study the interplay of optical properties and nanomagnetism. The photoluminescence (PL) exhibits σ+ polarization in the applied magnetic field. Our measurement detects the presence of even a single magnetic monolayer shell. The PLL consists of a higher and a lower energy component; the latter exhibits a circular polarization peak. The time-resolved PL (trPL) shows a red shift as function of time delay. At early (later) times the trPL spectra coincide with the high (low) energy PL component. A model is proposed to interpret these results.
Open Access
Mn2+-doped CdSe/CdS core/multishell colloidal quantum wells enabling tunable carrier-dopant exchange interactions
(American Chemical Society, 2015) Delikanlı, S.; Akgül, M. Z.; Murphy, J. R.; Barman, B.; Tsai, Y.; Scrace, T.; Zhang, P.; Bozok, B.; Hernández-Martínez, P.L.; Christodoulides, J.; Cartwright, A. N.; Petrou, A.; Demir, Hilmi Volkan
In this work, we report the manifestations of carrier-dopant exchange interactions in colloidal Mn2+-doped CdSe/CdS core/multishell quantum wells. The carrier-magnetic ion exchange interaction effects are tunable through wave function engineering. In our quantum well heterostructures, manganese was incorporated by growing a Cd0.985Mn0.015S monolayer shell on undoped CdSe nanoplatelets using the colloidal atomic layer deposition technique. Unlike previously synthesized Mn2+-doped colloidal nanostructures, the location of the Mn ions was controlled with atomic layer precision in our heterostructures. This is realized by controlling the spatial overlap between the carrier wave functions with the manganese ions by adjusting the location, composition, and number of the CdSe, Cd1-xMnxS, and CdS layers. The photoluminescence quantum yield of our magnetic heterostructures was found to be as high as 20% at room temperature with a narrow photoluminescence bandwidth of ∼22 nm. Our colloidal quantum wells, which exhibit magneto-optical properties analogous to those of epitaxially grown quantum wells, offer new opportunities for solution-processed spin-based semiconductor devices. © 2015 American Chemical Society.
Open Access
Semiconductor nanoplatelet heterostructures enhanced via combinations of colloidal atomic layer deposition and hot injection shell growths
(2019-07) Quliyeva, Ulviyya
One of the most promising families of semiconductor nanocrystals in colloidal optoelectronics and nanophotonics is considered to be colloidal quantum wells, also commonly referred to as nanoplatelets (NPLs). Possessing an atomically flat structure, NPLs feature unique properties including spectrally-resolved and tunable light-holeand heavy-hole transitions accompanied by their respective giant oscillator strengths. CdSe, CdS and CdTe, making the first colloidal NPLs synthesized in core-only structure, portray distinct qualities necessary for light-harvesting and -generating applications. However, going beyond the core structure, there are many properties that are highly enhanced by growing crown and/or shell layers around core NPLs. While the crown growth takes place anisotropically in lateral directions, the shell layer covers the entire NPL surface, combinations of which enable NPL heterostructures in new architectures. Depending on the electronic alignment of parts of the NPL heterostructure and the resulting confinement of electron-hole wave functions, these hetero-NPLs can be type-I or type-II. In type-I electron-hole pairs are confined in the core-NPL and recombination occurs in a direct pathway. In type-II electron-hole wave function is separated into different semiconductor layers, resulting in spatially indirect recombination. In this thesis, we synthesized and showed thin- and thick-shell grown heterostructures of type-I CdSe/ZnS NPLs using hot-injection (HI) for the first time particularly for these semiconductor NPLs. Unlike the typical colloidal atomic layer deposition (c-ALD) technique, which produces NPL heterostructures with low quantum yield (QY) and low chemical and optical stability, our approach yields CdSe/ZnS NPLs of almost unity (100%) quantum yield (QY) and improved chemical stability, tested by washing the same samples rigorously up to 6 times with ethanol with little change observed in the QY. Additionally, unparalleled thermal and optical aging endurances is achieved in aging tests. These tests experimentally demonstrated that, elevated to 400 K, HI thick-shelled NPLs can retain up to 65% of their emission intensity in the colloidal form and 52% of that in the film. This level of high stability creates a great opportunity for employing these NPLs for high-temperature applications. Also, in the thesis, we synthesized and studied CdS/CdSe core/crown, CdS/CdZnS core/c-ALD shell-grown and CdS/CdSe/CdZnS core/crown/c-ALD shell-grown heterostructures of NPLs. Here the starting-template CdS NPLs are considered to be unique in terms of their emission in the blue region, which may open up new opportunities for NPL lasing in this spectral region. Nominally CdS NPLs are folded due to great lateral sizes. However, in this research work, when coated with crown and shell layer, these particles unfold. The unrolled CdS/CdSe core/crown NPLs are found to exhibit relatively higher QY up to 15-20% in its class of CdS core-seeded NPLs. The findings of this thesis reveal that such heterostructures of the NPLs are very rich in terms of variety of the quantum architectures one can achieve using them as working model systems.