Browsing by Subject "Carrier transport"
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Item Open Access Influence of gold-silica nanoparticles on the performance of small-molecule bulk heterojunction solar cells(Elsevier BV * North-Holland, 2015) Xu, X.; Kyaw, A. K. K.; Peng, B.; Xiong, Q.; Demir, Hilmi Volkan; Wang Y.; Wong, T. K. S.; Sun, X. W.Light trapping by gold (Au)-silica nanospheres and nanorods embedded in the active layer of small-molecule (SM) organic solar cell has been systematically compared. Nanorod significantly outperforms nanosphere because of more light scattering and higher quality factor for localized surface plasmon resonance (LSPR) triggered by nanorods. The optimum concentration of nanorod was characterized by charge carrier transport and morphology of the active layers. At optimum nanorod concentration, almost no change in the morphology of the active layer reveals that LSPR and scattering effects rather than the morphology are mainly responsible for the enhanced power conversion efficiency. In addition, the preliminary lifetime studies of the SM solar cells with and without Au-silica nanorods were conducted by measuring the current density-voltage characteristics over 20 days. The results show that plasmonic device with nanorods has no adverse impact on the device stabilityItem Open Access Strongly Scale-Dependent Charge Transport From Interconnections of Silicon Quantum Dots and Nanowires(Cambridge University Press, 2017) Ilday, S.We present the first characterization of strongly scale-dependent charge transport of a unique, hierarchical complex topology: an interconnected random network of silicon quantum dots (QDs) and nanowires. We show that this specific topology has different charge transport characteristics on the nanoscale and the microscale: photogenerated charge carriers tend to be confined inside the QDs and externally injected charge carriers flow preferably along the nanowires. The former enables expression of quantum confinement properties, and the latter mainly contributes to the good electrical conduction on the microscale. Our findings strongly suggest that this multifunctionality can be controlled and used in photovoltaic device applications.