Browsing by Subject "Batch method"

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    Adsorption behavior of radionuclides, 137Cs and 140Ba, onto solid humic acid
    (Springer, 2011) Çelebi, O.; Erten, Hasan N.
    In this research, the adsorption behaviors of two important fission product radionuclides (137Cs and 133Ba) onto sodium form of insolubilized humic acid (INaA) were investigated as a function of time, cation concentration and temperature, utilizing radiotracer method. The resulting data was fitted well to the Freundlich and Dubinin-Radushkevich (D-R) isotherms. Thermodynamic constants such as; free energy (ΔGads), enthalpy (ΔHads), entropy (ΔSads) of adsorption were determined. Temperature change didn't effect sorption processes significantly. Best fitting kinetic models were found for a better understanding of adsorption mechanisms. It was found that Ba2+ was adsorbed five times more than Cs+ onto structurally modified humic acid and kinetic studies indicated that adsorption behaviors of both ions obey the pseudo second order rate law. The effect of pH changes on adsorption was also examined and optimum pH range was found in the range of pH 6-8. FTIR and solid state carbon nmr (13CNMR) spectroscopic techniques were used to understand the structural changes during insolubilization process. Quantitative determination of adsorption sites was carried out using potentiometric titration method and the resulting data was treated by using appropriate Gran functions.
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    Migration behaviour of Barium and Strontium in Granite
    (De Gruyter Oldenbourg, 1994-12-01) Hatipoğlu, S.; Göktürk, H.; Erten, H. N.
    The sorption behaviour of Ba2+ and Sr2+ cations on granite have been studied under flowing and static conditions in column and batch experiments. 133Ba, 90Sr and 3H were used as radio tracers. The retardation factors, R1, and distribution ratios, Rd, of barium and strontium in column experiments were found to be smaller than those from batch experiments. In both techniques barium was sorbed more strongly on granite than strontium. Sorption energies were found to be in good agreement with literature val-ues.
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    ItemOpen Access
    Migration behaviour of barium and strontium through colemanite
    (De Gruyter Oldenbourg, 1996) Hatipoǧlu, S.; Göktürk, H.; Erten, H. N.
    Column and batch experiments were performed to study the migration behaviour of Ba and Sr in colemanite matrix. 133Ba. 90Sr and 3H were used as tracers. The retardation factors and the distribution ratios of Ba and Sr in column experiments were found to be smaller than those obtained in batch experiments. Sorption Ra values of Ba were higher than those of Sr determined by both techniques. Sorption energies calculated from batch experiments are in good agreement with the literature values.
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    Sorption behavior of radioiodine on organic rich soil, alumina and clay minerals
    (1992) Assemi, Shoeleh
    Sorption behavior of radioiodine on organic rich soil, alumina, chlorite- illite clay mixture, kaolinite and bentonite have bc;en studied using the batch method. was used as tracer. Characterization of samples were done by FTIR, X-ray diffraction spectrometry and particle size distribution by Andreason pipette method. The grain size of the samples used were all below 38/xm and the experiments were performed at room temperature. The aqxreos phase used in all experiments were synthetic ground water with a composition similar to the underground waters of the regions where the samples were obtained. Stock solutions containing tracer, were prepared using synthetic ground- water. Initial concentration of inactive iodide ion in the solutions ranged from 10~®to 10“^ mmole/ml. The influence of contact time, solution/solid ratio, pH of synthetic ground- water, biomass of soil and I~ ion concentration on the sorption of radioiodine on the organic rich soil were investigated. The effect of I~ ion concentration and complexing agents on the sorption behavior of radioiodine on alumina and clay minerals were also studied. A rather slow kinetics was observed for tlie adsor])tion of radioiodine on the organic rich soil, tending saturation within 14 da.ys. It was observed that distribution ratio increased with increasing ratio of the volume of solution to the mass of soil(V/m ratio) and reached a platee.u after V/m=50. Distribution ratio did not change very much by changing the pH of the solution. Comparison of Eh-pH behavior of the solutions with the standard Eh-pH graph of iodine-water system indicated that in the whole pH rcinge, iodine is mostly preseirt in I~ form. To observe the effect of soil biomass soil samples were sterilized by heat and gamma-ray source and the results were found to be much lower than the control sample. Increasing the concentration of iodide ion in the .solution, caused a decrease in Rd. values. Desorption Wcvs ol)served only for low initial iodine concentrations < 1 X I0~^7nmol/ml), for organic rich soil which suggests that at least two sites and/or mechanisms are involved in the sorption. The sorption data were fitted to Freundlich and Dubinin-Radushkevich isotherms. The slope of Freundlich isotherm was found to be less than 1 which indicates the non-linearity of the isotherm. The mean free energy of adsorption was calculated from the slope of Dubinin-Radushkevich isotherm and was found as about 11 k.J/mol. The distribution of sites on organic rich soil was calculated using the Freundlich and Dubinin-Radushkevich constants, considering Cl~ as the competing ion with I~ in the solution. The affinities of sites were found to be about three times higher for Cl~ than I~. Among the clay minerals, the highest Rd value was found for chlorite-illite cla}^ mixture but tlie Rd values found for alumina and the other sanrples were well below those found for the organic rich soil. The sorption data were fitted to Freundlich and Dubinin-Radushkevich isotherms. All the Freundlich isotherms were non-linear (slope
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    ItemOpen Access
    Sorption of barium on kaolinite, montmorillonite and chlorite
    (Royal Society of Chemistry, 1989) Eylem, C.; Erten, H. N.; Göktürk, H.
    The sorption characteristics of the Ba2+ ion on kaolinite, montmorillonite and chloritetype clays were studied using the batch method. Barium-133 was used as a tracer. The Ba2+ ion concentrations ranged from 10-8 to 10-5 mol l-1; synthetic groundwater was used and the grain size of all the solid particles was <40 μm. About 6, 8 and 12 d of shaking were necessary to reach equilibrium for chlorite, kaolinite and montmorillonite, respectively. The sorption isotherms were described best by Freundlich and Dubinin - Radushkevich type isotherms. Sorption was predominantly reversible for kaolinite and partly reversible for montmorillonite and chlorite.
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    Sorption of cesium and strontium on montmorillonite and kaolinite
    (De Gruyter Oldenbourg, 1988) Erten, H. N.; Aksoyoglu, S.; Hatipoglu, S.; Göktürk, H.
    Sorption characteristics of Cs+ and Sr++on montmorillonite and kaolinite type clays and soil fractions from various regions of Turkey were studied using the batch method. 137Cs and 90Sr were used as tracers. Concentrations of Cs+ and Sr++ ions ranged from 10-8to 10-2 mol/1; natural groundwater was used and the grain size of the solid particles was < 20 yμm. Equilibrium was reached in 4 - 7 days for Cs+and 7 - 11 days for Sr++. The distribution coefficient, RD, increased with decreasing grain size, suggesting mainly a surface phenomenon. The sorption isotherms were non-linear suggesting at least two different sorption processes. The sorption was found to be predominantly reversible. Cs+ was sorbed much stronger than Sr++in all samples. © 1988, Walter de Gruyter. All rights reserved.